Determining the main atmospheric factor on ozone concentrations

This paper presents techniques for studying the influence of the atmospheric variables for the explanation of ozone concentrations. A methodology is described for separating the different time scale components in time series of ozone, namely, the global-term component which describes the long and seasonal variations, and the synoptic-scale component. We prove that the decomposition of the time series of ozone and other atmospheric variables is essential for the analysis. The results indicate that solar radiation is the only main factor between all the atmospheric variables for the global and the synoptic-scale component of the ozone time series. Most of the total variance of ozone can be explained by the atmospheric variables, which makes possible the precise estimation of human effect on ozone. In case the solar radiation data are not available, lagged temperature can be used as a supplement of solar radiation.     

Geo–ecology and management of sensitive montane landscapes

Montane (alpine) areas are generally of high value for nature conservation. Such environments and the habitats they support are dynamic and often fragile. They are vulnerable to disturbance from a range of human activities and are responsive to climate changes over short and long timescales. Biodiversity and conservation values are closely linked to geological history, geomorphological processes and soils, and it is crucial that management systems are based on understanding these links.
There are many similarities between the Cairngorm Mountains (Scotland), the Giant Mountains (Czech Republic) and Abisko Mountains (Sweden) in terms of geology, geomorphology, ecology, links with biodiversity and high conservation importance. Comparable pressures and management issues involve, to varying degrees, a history of human use and impacts from deforestation, pasturing, grazing, recreation and atmospheric pollution. Landscape change therefore involves a complex interplay between natural and anthropogenic factors. Managing such change requires better understanding of the geo–ecological processes involved and the factors that determine landscape sensitivity. This is illustrated through a simple framework and examples from the three areas. Comparison of landscape sensitivity between similar montane areas, but in different geographic locations and climatic environments, should allow more informed management planning and a precautionary approach in advance of further changes in human activity and from predicted global warming scenarios.     

Current estimates of freshwater flux through Arctic and subarctic seas

As the world warms, the expectation is that the freshwater outflows from the Arctic Ocean to the North Atlantic will strengthen and may act to suppress the rate of the climatically-important Atlantic meridional overturning circulation. Hitherto, however, we have lacked the system of measurements required to estimate the totality of the freshwater flux through subarctic seas. Though observations remain patchy and rudimentary in places, we piece-together the results from recent large-scale observational programmes together with associated modelling, to establish preliminary maps of the rates and pathways of freshwater flux through subarctic seas. These fluxes are calculated according to two reference salinities, S = 34.8 to conform with the majority of estimates reported in the literature, and S = 35.2, the salinity of the inflowing Atlantic water, to calculate the freshwater balance of the ‘Arctic Mediterranean’. We find that 148 mSv of freshwater enters the Nordic Seas across its northern boundary. There it is supplemented by around 54 mSv of freshwater from Baltic runoff, Norwegian runoff, P − E and Greenland ice melt, so that the total freshwater contribution to the Nordic Seas from all sources is 202 mSv. Of this, around 51 mSv of freshwater is estimated to pass south to the deep Atlantic in the dense water overflows leaving an assumed balance of 151 mSv to leave the Nordic Seas in the upper water export through Denmark Strait. The corresponding estimate for the freshwater outflow west of Greenland is 103 mSv relative to 35.2 so that the total freshwater flux reaching the North Atlantic through subarctic seas is around 300 mSv.     

Finite element modeling of net panels using a consistent net element

A consistent finite element is proposed to model the hydrodynamic response of net panels to environmental loading. This equivalent net element is constructed to reproduce the drag, buoyancy, inertial and elastic forces exerted on the netting by current and waves. To evaluate the accuracy of the proposed finite element modeling, numerical predictions have been compared with the experimental observations and (simplified) analytical results of other authors. This new modeling technique has been applied to evaluate the performance of a tension leg fish cage in the open ocean environment.     

Effects of the Anticyclonic Eddies on Water Masses, Chemical Parameters and Chlorophyll Distributions in the Oyashio Current Region

Data from the R/V Mirai cruise (May–June 2000) have been examined to discover how mesoscale processes associated with eddy dynamics direct affect the water masses, the distributions and the vertical fluxes of the dissolved oxygen, nutrients and dissolved inorganic carbon in the western subarctic Pacific. Using maps of the temperature, salinity, dissolved oxygen, nutrients, chlorophyll and sea-air pCO₂ difference we show that the boundaries of the anticyclone eddies in the study region were composed of high productivity coastal Oyashio water. The coastal waters were wrapped around the anticyclone eddies (thus creating a high productivity belt) and intruded inside of them. Using SeaWifs data we demonstrate that temporal variations in the position and the strength of anticyclone eddies advected the Kuril island coastal high productivity waters to the pelagic part, resulting in temporal variations of the chlorophyll in the Oyashio region. Computed vertical fluxes of the dissolved oxygen (DO), inorganic carbon (DIC) and silicate show that the anticylonic eddies in the Kuroshio-Oyashio Zone are characterized by enhanced vertical fluxes of the DO and DIC between the upper (σ_θ = 26.7–27.0) and lower (σ_θ = 27.1–27.5) intermediate layer, probably due to the intrusions of the Oyashio waters into the eddies. This revised version was published online in August 2006 with corrections to the Cover Date.     

Modelling hydrographic changes in the Labrador sea over the past five decades

Inter-annual to inter-decadal changes of hydrographic structure and circulation in the subpolar North Atlantic are studied using a coarse resolution ocean circulation model. The study covers 1949 through 2001, inclusive. A “time-mean state nudging” method is applied to assimilate the observed hydrographic climatology into the model. The method significantly reduces model biases in the long-term mean distribution of temperature and salinity, which commonly exist in coarse-resolution ocean models. By reducing the time-mean biases we also significantly improve the model’s representation of inter-annual to inter-decadal variations. In the central Labrador Sea, the model broadly reproduces the heat and salt variations of the Labrador Sea Water (LSW) as revealed by hydrographic observations. Model sensitivity experiments confirm that the low-frequency hydrographic changes in the central Labrador Sea are closely related to changes in the intensity and depth of deep convection. Changes in surface heat flux associated with the winter North Atlantic Oscillation (NAO) index play a major role in driving the changes in T–S and sea surface height (SSH). Changes in wind stress play a secondary role in driving these changes but are important in driving the changes in the depth-integrated circulation. The total changes in both SSH and depth-integrated circulation are almost a linear combination of the separate influences of variable buoyancy and momentum fluxes.     

Geochronology of the Larderello geothermal field: new data and the “closure temperature” issue

The Larderello geothermal field is generally accepted to have been produced by a granite intrusion at 4–9 km depth. Hydrothermal parageneses and fluid inclusions always formed at temperatures greater than or equal to the current ones, which implies that the field has always undergone a roughly monotonic cooling history (fluctuations < 40 K) since intrusion of the granite at 4 Ma. The heat required to maintain the thermal anomaly over such a long period is supplied by a seismically anomalous body of 32000 km³ rooted in the mantle. Borehole minerals from Larderello are thus a unique well-calibrated natural example of thermally induced Ar and Sr loss under geological conditions and time spans. The observations (biotites retain Ar above 450°C) agree well with other, albeit less precise, geological determinations, but contrast with laboratory determinations of diffusivity from the literature. We therefore performed a hydrothermal experiment on two Larderello biotites and derived a diffusivity D _Lab(370°C)=5.3·10^-18 cm²s^-1, in agreement with published estimates of diffusivity in annite. From D _Lab and the rejuvenation of the K/Ar ages we calculate maximum survival times at the present in-hole temperatures. They trend smoothly over almost two orders of magnitude from 352 ka to 5.3 ka, anticorrelating with depth: laboratory diffusivities are inconsistent not only with geological facts, but also among themselves. From the geologically constrained lifetime of the thermal anomaly we derive a diffusivity D _G(370°C)=3.81·10²¹ cm²s^-1, 3±1 orders of magnitude lower than D _Lab. The cause of these discrepancies must be sought among various laboratory artefacts: overstepping of a critical temperature T ^*; enhanced diffusivities in wet experiments; presence of fast pathway (dislocation and pipe) diffusion, and of dissolution/reprecipitation reactions, which we imaged by scanning electron microscopy. These phenomena are minor in geological settings: in the absence of mineral transformation reactions, complete or near-complete resetting is achieved only by volume diffusion. Therefore, laboratory determinations will necessarily result in apparent diffusivities that are too high compared to those actually effecting the resetting of natural geochronometers.This word is dedicated to the memory of Aldo Valori (1958–1991)     

Management of karst aquifers in Serbia for water supply

Karst aquifers represent one of the main sources of water supply in Serbia. Wide distributions of karstic areas, abundant reserves, and excellent quality of karst groundwater have been the reasons for its extensive use in water supply systems throughout the country. In Serbia, 70 karstic sources have been tapped for centralized water supply, with the assessed minimal capacity exceeding 4.5 m³/s. Most of the large cities of Eastern and Western Serbia currently use karst groundwater for water supply; however, due to unstable flow regime when only natural springflow is tapped, numerous problems arise during the recession period (summer–autumn). During the last two decades, after favorable conditions had been confirmed through hydrogeological survey and feasibility studies, several newly constructed systems for artificial control of karst aquifers (mostly in Eastern Serbia) resulted in significantly improved water supply.     

3D non-hydrostatic modelling of bottom stability under impact of the turbulent ship propeller jet

New three-dimensional numerical non-hydrostatic model with a free surface that was designed for modelling the bottom and bank stability subjected by ship propeller jets is presented. Unlike all known models, it describes three-dimensional fields of velocities generated by ship propellers, turbulence intensity and length scale in the given domain of arbitrary bottom and coastal topography. Results of simulations are compared with the laboratory experiments.     

Recent changes of the thermohaline circulation in the subpolar North Atlantic

Time series of hydrographic sections in the northern North Atlantic from the period 1990 to 2004 are analyzed for changes in the characteristics and distribution of water masses that are involved in the thermohaline circulation (THC). During the 1990s, the North Atlantic Oscillation (NAO) alternates from a positive phase (strong westerlies) to a negative phase (weak westerlies). The reduced ocean heat loss confined the convection in the Labrador Sea to the upper 1,200 m, generating a new salinity minimum layer characterizing the Upper Labrador Sea Water (ULSW), and led to a warming and salinization of the older LSW below due to lateral mixing. The Lower LSW, formed in the first half of the 1990s, spread in the subpolar gyre and reached the Newfoundland and Irminger basins after about 1 to 2 years, where the associated isopycnal doming contributed to eastward frontal shifts in the upper layer. After 5 and 6 years, it arrived in the Iceland and West European basins, respectively. The collapse of the isopycnal dome in the Labrador Sea, associated with the drainage of the Lower LSW, resulted in a slowing of the cyclonic circulation of the subpolar gyre. This was accompanied in the upper layer by a westward shift of the southeastern extension of the gyre and a northward advection of warm and saline subtropical water in its eastern part, which finally reached the Labrador Sea after about 7 years. In the upper layer of the Labrador Sea, the advection of warm and saline water dominated over the heat loss to the atmosphere and the freshwater gain from melting ice and precipitation in the NAO-low period, so that no accumulation of freshwater but an increase of the heat and salt contents were observed, as in the whole eastern part of the subpolar gyre. Within 1 to 2 years after the drop of the NAO in the winter of 1995/1996, the Subarctic (Subpolar) Front shifted northward and westward north of about 50°N, favored by the retreat of the low-salinity tongue extending eastward from the southern Labrador Sea, and it shifted southward and eastward in the Newfoundland Basin. Therefore, the enhanced northward advection of subtropical waters in the northeastern North Atlantic is balanced by the enhanced southward advection of subarctic waters, including Lower LSW in the Newfoundland Basin, indicating a strong response of the gyre component of the THC.