Products and Mechanism of the NO<Subscript>3</Subscript> Reaction with Thiophene

Products of the gas-phase reaction of the NO₃ radical with thiophene have been investigated using different experimental systems. On the one hand, experiments have been conducted in our laboratory using two different methods, a Teflon static reactor coupled to a gas chromatograph combined with mass-spectrometry (GC-MS) and a discharge flow tube with direct MS spectroscopic detection. A qualitative analysis in these cases indicates that possible products for the reaction of thiophene+NO₃ at room temperature include: sulphur dioxide, acetic and formic acids, a short-chain aldehyde, 2-nitrothiophene and 3-nitrothiophene. On the other hand, quantitative experiments have been performed in the European Photoreactor (EUPHORE) in Valencia, Spain. In this case, the major products were: HNO₃ (≈80%), nitrothiophenes (≈30%), SO₂ (≈20%), propanal (3%) and a fraction of particles (≈10%). The results obtained indicate that at least 70% of the reaction of NO₃ with thiophene proceeds by an H-abstraction process at room temperature. The mechanism of the reaction studied is proposed on the basis of experimental results.     

Apse Alignment of the Uranian Rings

An explanation of the dynamical mechanism for apse alignment of the eccentric uranian rings is necessary before observations can be used to determine properties such as ring masses, particle sizes, and elasticities. The leading model (P. Goldreich and S. Tremaine 1979, Astron J.84, 1638-1641) relies on the ring self-gravity to accomplish this task, yet it yields equilibrium masses which are not in accord with Voyager radio measurements. We explore possible solutions such that the self-gravity and the collisional terms are both involved in the process of apse alignment. We consider limits that correspond to a hot and a cold ring, and we show that pressure terms may play a significant role in the equilibrium conditions for the narrow uranian rings. In the cold ring case, where the scale height of the ring near periapse is comparable to the ring particle size, we introduce a new pressure correction pertaining to a region of the ring where the particles are locked in their relative positions and jammed against their neighbors and the velocity dispersion is so low that the collisions are nearly elastic. In this case, we find a solution such that the ring self-gravity maintains apse alignment against both differential precession (m=1 mode) and the fluid pressure. We apply this model to the uranian α ring and show that, compared to the previous self-gravity model, the mass estimate for this ring increases by an order of magnitude. In the case of a hot ring, where the scale height can reach a value as much as 50 times the particle size, we find velocity dispersion profiles that result in pressure forces which act in such a way as to alter the ring equilibrium conditions, again leading to a ring mass increase of an order of magnitude. We find that such a velocity dispersion profile would require a different mechanism than is currently envisioned for establishing a heating/cooling balance in a finite-sized, inelastic particle ring. Finally, we introduce an important correction to the model of E. I. Chiang and P. Goldreich (2000, Astrophys. J.540, 1084-1090.). These authors relied on collisional forces in the last ∼100 m of an ∼10 km wide ring to increase ring equilibrium masses by up to a factor of ∼100. However, their treatment of ring edges as one-sided surface density drops leads to a strong dependence of the ring mass on the adjustable parameter λ (the length scale over which the ring's optical depth drops from order unity to zero at the edge). A treatment of the ring edges that takes into account their ridgelike structure retains the increase of ring mass of the order of ∼100 for a 10 km wide ring, while exhibiting weak dependence on λ. We conclude that a modified Chiang-Goldreich model can likely account for the masses of narrow, eccentric planetary rings; however, the role of shepherd satellites both in forming ring edges and in altering the streamline precession conditions near them needs to be explored further. It is also unclear whether a fully self-consistent ring model allows for the possibility of rings with negative eccentricity gradients.     

Mineralogy and possible origin of an unusual Cr-rich inclusion in the Los Martinez (L6) chondrite

Abstract— During a petrological study of the previously unclassified ordinary chondrite Los Martínez, we discovered a highly unusual Cr-rich inclusion which we believe is unique in both extraterrestrial and terrestrial mineralogy. The inclusion is highly zoned both compositionally and optically, with a Ca-Al rich, cloudy core and an opaque, Cr-Na-rich rim (up to 24 wt.% Cr₂O₃). Detailed SEM and TEM studies show that the inclusion now consists of a highly zoned, single crystal of plagioclase intergrown with chromium-rich spinel. The spinel has a well-developed crystallographic orientation relationship with the host plagioclase, which indicates that it is the product of exsolution. Although superficially similar to a plagioclase feldspar in composition, in detail the inclusion is Si-deficient and Al-enriched relative to a stoichiometric feldspar. We have not been able to identify a viable precursor mineral phase to the plagioclase-chromite intergrowth and suggest that it may be an unknown metastable phase. The Cr-rich precursors of the inclusion probably have close affinities to the chromite-plagioclase chondrules observed by Ramdohr (1967) in several ordinary chondrites. Based on the zoning in the inclusion, we suggest that it is the product of fractional crystallization from a melt, which may have formed as a liquid condensate, or by melting of solid condensates, in the solar nebula. Subsequent cooling of this melt condensate resulted in crystallization of the, as yet, unidentified phase. After crystallization, the inclusion was probably incorporated into a parent body where it underwent metamorphism and was probably shocked to some degree. During this period of parent body metamorphism, exsolution and decomposition of the unknown precursor occurred to produce the observed intergrowth of plagioclase and chromite. Finally, we have classified Los Martínez as an L6 ordinary chondrite breccia.     

Lithological classification assisted by the joint inversion of electrical and seismic data at a control site in northeast Mexico

In this paper, evidence is presented that the combination of geospectral images and geophysical signatures (resistivity–velocity cross-plots) is a good tool to provide a natural visualization of the distribution and variations of lithological features in a test site. This was confirmed by the correlation between the electrical resistivity and seismic velocity values obtained after cross-gradient joint inversion at two profiles and geotechnical information provided by shallow boreholes in a site located in the Earth Sciences School grounds in Linares, Northeastern Mexico. The results obtained from this study show how the cross-gradient joint inversion facilitates the analysis of hydrological estimates and assists in lithological classification of subsurface materials.     

Reassessment of Prejanopterus curvirostris,a Basal Pterodactyloid Pterosaur from the Early Cretaceous of Spain

Prejanopterus curvirostra, from the Early Cretaceous of La Rioja province, was the first pterosaur genus and species described from Spain. The material comprises disarticulated cranial and postcranial remains from several individuals. The fossil-bearing bed is assigned to the lacustrine Leza Formation (eastern Cameros Basin, NW margin of the Iberian Range). This unit is regarded as either Berriasian-Valanginian or Barremian-Aptian. Prejanopterus curvirostris (specific name emended) was originally diagnosed on the basis of several characters of which the most significant was a lateral curvature of the rostrum. Re-examination of the holotype (rostrum) and paratype (partial rostrum with teeth) indicates that there is no genuine sideways bend of the preserved premaxilla-maxilla segments, but a slight dorsal curvature. Prejanopterus is characterized by a unique combination of characters: an emended diagnosis is provided. In contrast with previous estimates, the wing span of Prejanopterus was probably not much (if ever) in excess of 2 m. A phylogenetic analysis suggests that Prejanopterus is a basal pterodactyloid positioned between Pterodactylus and Cycnorhamphus-Gallodactylus. Prejanopterus represents the first evidence of Pterodactylidae in the Early Cretaceous of the Iberian Peninsula.     

THE DECLINE OF PARTY VOTING: A GEOGRAPHICAL ANALYSIS OF THE 1978 MASSACHUSETTS ELECTION

A factor analysis of the 1978 Massachusetts election is undertaken to investigate whether the alleged decline of political parties in the United States can be distinguished at the state scale. Four factors are identified, two of which relate to the voting patterns of state-wide candidates. The main factor is easily seen to represent a “party voting”pattern and the fourth factor suggests a nonparty pattern of support associated with the Democratic candidate for governor, Edward King. It is suggested that this separation of the voting pattern for Democratic candidates may possibly reflect party decomposition in Massachusetts.     

Pounding force assessment in performance‐based design of bridges

Bridges with deck supported on either sliding or elastomeric bearings are very common in mid‐seismicity regions. Their main seismic vulnerabilities are related to the pounding of the deck against abutments or between the different deck elements. A simplified model of the longitudinal behavior of those bridges will allow to characterize the reaction forces developed during pounding using the Pacific Earthquake Engineering Research Center framework formula. In order to ensure the general applicability of the results obtained, a large number of system parameter combinations will be considered. The heart of the formula is the identification of suitable intermediate variables. First, the pseudo acceleration spectral value for the fundamental period of the system (Sa(T_s)) will be used as an intensity measure (IM). This IM will result in a very large non‐explained variability of the engineering demand parameter. A portion of this variability will be proved to be related to the relative content of high‐frequency energy in the input motion. Two vector‐valued IMs including a second parameter taking this energy content into account will then be considered. For both of them, a suitable form for the conditional intensity dependence of the response will be obtained. The question of which one to choose will also be analyzed. Finally, additional issues related to the IM will be studied: its applicability to pulse‐type records, the validity of scaling records and the sufficiency of the IM. Copyright © 2009 John Wiley & Sons, Ltd.