MALDI analysis of presolar nanodiamonds: Mass spectrometric determination of the mass distribution of nanodiamonds from meteorites and a technique to manipulate individual nanodiamonds

Abstract— This paper describes the use of matrix‐assisted laser desorption and ionization (MALDI) to measure the mass distribution of nanodiamonds extracted from meteorites. The techniques used to prepare and mass analyze nanodiamond samples from the Murchison (CM2) and Allende (CV3) meteorites are described. The mass spectra of nanodiamonds (peaking at between 1 times 10⁴‐1.5 times 10⁴ Daltons) are compared with size distributions obtained by point‐counting transmission electron microscopy (TEM) images obtained elsewhere and reasonable agreement is found. The implications of the ability to produce and mass analyze a beam of nanodiamonds are explored.     

Rest-frame optical and far-infrared observations of extremely bright Lyman-break galaxy candidates at z∼ 2.5

We have investigated the rest-frame optical and far-infrared properties of a sample of extremely bright candidate Lyman-break galaxies (LBGs) identified in the Sloan Digital Sky Survey. Their high ultraviolet luminosities and lack of strong ultraviolet emission lines are suggestive of massive starbursts, although it is possible that they are more typical luminosity LBGs which have been highly magnified by strong gravitational lensing. Alternatively, they may be an unusual class of weak-lined quasars. If the ultraviolet and submillimetre (submm) properties of these objects mirror those of less luminous, starburst LBGs, then they should have detectable rest-frame far-infrared emission. However, our submm photometry fails to detect such emission, indicating that these systems are not merely scaled-up (either intrinsically or as a result of lensing) examples of typical LBGs. In addition we have searched for the morphological signatures of strong lensing, using high-resolution, near-infrared imaging, but we find none. Instead, near-infrared spectroscopy reveals that these systems are, in fact, a rare class of broad absorption line quasars.     

Architecture and evolution of a fjord‐head delta,western Vancouver Island,British Columbia

The architectural framework and Holocene evolution of the Zeballos fjord‐head delta on west‐central Vancouver Island was established through a multidisciplinary field‐based study. The Zeballos delta is a composite feature, consisting of an elevated, incised, late Pleistocene delta and an inset Holocene delta graded to present sea level. Both deltas have a classic Gilbert‐type tripartite architecture, with nearly flat topset and bottomset units and an inclined foreset unit. Time domain electromagnetic (TDEM) and ground‐penetrating radar (GPR) surveys, borehole data, and gravel pit exposures provided information on the internal form, lithologies and substrate of both deltas. Both sets of deltaic deposits coarsen upward from silt in the bottomset unit to gravel in the topset unit. The TDEM survey revealed a highly irregular, buried bedrock surface, ranging from 20 m to 190 m in depth, and it delineated saltwater intrusion into the deltaic sediments. Late Quaternary sea‐level change at Zeballos was inferred from delta morphology and the GPR survey. The elevated, late Pleistocene delta was constructed when the sea was about 21 m higher relative to the land than it is today. It was dissected when sea‐level fell rapidly as a result of glacio‐isostatic rebound. Relative sea‐level reached a position about 20 m below the present datum during the early Holocene. Foreset beds that overlap and progressively climb in a seaward direction and topset beds that thicken to 26 m landward imply that the delta aggraded and prograded into Zeballos Inlet during the middle and late Holocene transgression. Sea‐level may have risen above the present datum during the middle Holocene, creating a delta plain at about 4 m a.s.l. Remnants of this surface are preserved along the valley margins. Copyright © 2004 John Wiley & Sons, Ltd.