Zirconolite and xenotime U–Pb age constraints on the emplacement of the Golden Mile Dolerite sill and gold mineralization at the Mt Charlotte mine,Eastern Goldfields Province,Yilgarn Craton,Western Australia

In situ SHRIMP U–Pb dating of magmatic zirconolite (CaZrTi₂O₇) in the Golden Mile Dolerite from the Mt Charlotte gold deposit (Yilgarn Craton, Australia) has yielded the first robust emplacement age (2,680 ± 9 Ma) for the principle host-rock of gold mineralization in the Kalgoorlie district. In contrast, co-magmatic zircon gave ages from ~2.68 Ga to ~2.17 Ga, reflecting isotopic resetting of high-U and -Th crystals. In situ SHRIMP analysis of hydrothermal xenotime (YPO₄), which co-exists with gold in alteration pyrite, provided a Pb/Pb isochron age of 2,655 ± 13 Ma. This date indicates that the youngest deposit in the Kalgoorlie district (Mt Charlotte) formed at ~2.65 Ga, and provides a new minimum age for the structurally older Golden Mile deposit. Our results indicate that gold mineralization at Mt Charlotte is ~50 million years older than indicated by recent ⁴⁰Ar/³⁹Ar dating and places new constraints on the timing of late-stage regional faulting (D₄) in the province.     

Direct measurement of the Si–O bond length and orientational disorder in the high-temperature phase of cristobalite

Neutron total scattering measurements from powdered samples of cristobalite have been used to determine the local structure in both the tetragonal and cubic phases. The results for the cubic phase show directly that the Si–O bonds are tilted at an angle of around 17° to the unit cell [111] direction. It is striking that the structure of β-cristobalite over the range 5–10 Å is closer to that of silica glass than α-cristobalite, which suggests that the local structure of β-cristobalite is not likely to consist of domains with the structure of α-cristobalite. The measurements show a small thermal expansion of the Si–O bonds over the temperature range 570–950 K.     

Determination of Rare Earth Elements and Yttrium in Nine Geochemical Reference Samples Using a Novel Group Separation Procedure Involving Mixed-Acid Elution Ion-Exchange Chromatography

Rare earth data for nine well-known geochemical reference samples were obtained using a rapid and efficient cation exchange chromatographic separation procedure. It involves the use of a mixed-acid eluent (HCI and HNO3) on a 15 x 1 cm column of Bio-Rad AG50–X8 (200–400 mesh) to remove matrix and many trace elements from rock solutions. The rare earth elements are removed from the column using 60 ml 7M HNO3. The pre-concentration procedure described is routinely used in this laboratory for the determination of the rare earth elements by mass spectrometry-isotope dilution, and has been satisfactorily used for their determination using inductively-coupled plasma-source atomic emission spectrometry.     

Binary formation in stellar clusters

We consider how the tidal potential of a stellar cluster or a dense molecular cloud affects the fragmentation of gravitationally unstable molecular cloud cores. We find that molecular cloud cores which would collapse to form a single star in the absence of tidal shear, can be forced to fragment if they are subjected to tides. This may enhance the frequency of binaries in star-forming regions such as Ophiuchus and the frequency of binaries with separations ≲100 au in the Orion Trapezium Cluster. We also find that clouds which collapse to form binary systems in the absence of a tidal potential will form bound binary systems if exposed to weak tidal shear. However, if the tidal shear is sufficiently strong, even though the cloud still collapses to form two fragments, the fragments are pulled apart while they are forming by the tidal shear and two single stars are formed. This sets an upper limit for the separation of binaries that form near dense molecular clouds or in stellar clusters.     

Late Devensian and Holocene relative sealevel changes at Loch nan Eala,near Arisaig,northwest Scotland

Pollen, diatom, radiocarbon and lithostratigraphical data from isolation basins in northwest Scotland are used to quantify the reference water (tide) level, indicative range and age of differenty types of isolation and connection contacts. Tendencies of sea-level movement and relative sea-level changes from the mid-Lateglacial Interstadial (11.8 ka BP) to the late Holocene are constructed from these data. Relative sea-level fell continuously from + 17.8 m OD at 11.8 ka BP to ca. + 5.2 m OD at 10.1 ka BP. From an unkown minimum between 10 ka and 9 ka BP relative sea-level then rose to +6.3 m OD at 8.3 ka BP. The maximum Holocene sea-level occurred within the range +6.6 m OD to +9.3 m OD between 6.6 ka BP and 4.0 ka BP before falling to present. Isobase, age-altitude and quantitative rebound models for northwest Scotland are tested using these sealevel data, but none of the published models shows close agreement with the new results.