Soil water residence times and solute uptake on a dolomite bedrock—preliminary results

Calcium and magnesium levels have been monitored in slope foot drainage waters on a dolomite bedrock. Both calcium and magnesium rich pulses occur. Short term dissolution experiments demonstrate high calcium levels in solution while other authors have suggested that long residence time groundwater has relatively high levels of magnesium due to calcite precipitation. Patterns of field fluctuations in Ca: Mg ratios can thus be tentatively interpreted in terms of short residence time water of high calcium content mixing with long residence time water of high magnesium content. Fluorometric dye tracing has been used to indicate the orders of magnitude of soil water residence times, suggesting that quickflow components are resident in the system for a few hours to a few days. Further work is in progress.     

A scree slope rockfall model

Certain observed characteristics of scree slopes; namely concavity of profile, straight slope angle less than the angle of repose, and good size sorting of particles, are not consistent with an angle of repose model for accumulation. An alternative model is proposed based upon rockfall and surface stone movement and is tested against experimental data of particle movement in the field. It is found that the mechanical model of stone movement generated adequately explains the motion of particles on scree slopes and that it is in keeping with the characteristics of many screes. The static features of some Isle of Skye screes were also measured and the straight-concave slope form with good downslope sorting of material, characteristic of the rockfall process, was found to be present.     

Alkali-feldspars: Which solvus?

Variation in published alkali-feldspar solvus curves is discussed in the light of the concept of complete (crystal-crystal) and exchange (crystal-fluid-crystal) equilibrium. Exchange equilibrium may lead to very regular solvus-like two-phase curves differing substantially from the true binodal solvus; certain experimental strategies tend to favour the attainment and persistence of the exchange equilibrium condition. New long duration experiments under “alkali excess” and “alkali+silica excess” conditions did not yield fledspar pairs significantly off the bracketed binodal obtained by Smith and Parsons (1974) but exchange equilibrium behaviour is shown to influence the course of equilibration in peralkaline experiments. Agreement in solvus curves obtained by bracketing experiments by several workers is excellent (±2 mol. % Or) with a straight linear relationship between T _crit and P such that dT _crit/dP≈16°/Kbar. These curves do not exhibit breaks or sensitivity to chemical environment, and there is no evidence that the solvus changes shape with increasing P.     

Growth defects in metamorphic biotite

Metamorphic biotites examined by transmission electron microscopy contain planar defects on the (001) plane, superlattices, twins and a microstructure causing streaking of k≠3n rows. Analysis of the fringe contrast shows that the fault vectors associated with the planar defects are either R ₁=±1/3 [010], R ₂=±1/6 [310] or R ₃=±1/6 [3 \(\bar 1\) 0]. Structural considerations indicate that a stacking fault R ₁, R ₂ or R ₃ is most likely to exist in the octahedral layer rather than the potassium layer. The result of such a fault on a unit layer of mica is effectively to rotate it through ±120° about c* (equivalent to the common mica twin law). These stacking faults can provide the mechanism for producing the ±120° rotations associated with the common mica polytypes. Furthermore, many of the observed microstructures can be generated by these stacking faults.     

Armalcolite stability as a function of pressure and oxygen fugacity

The stability of synthetic armalcolite of composition (Fe_0.5Mg_0.5Ti₂O₅ was studied as a function of total pressure up to 15 kbar and 1200°C and also as a function of oxygen fugacity (?O₂) at 1200°C and 1 atm total pressure. The high pressure experiments were carried out in a piston-cylinder apparatus using silver-palladium containers. At 1200°C, armalcolite is stable as a single phase at 10 kbar. With increasing pressure, it breaks down ($\text{dT}\text{dP}\text{= 20°C/}\text{kbar}$), to rutile, a more magnesian armalcolite, and ilmenite solid solution. At 14 kbar, this three-phase assemblage gives way ($\text{dT}\text{dP}\text{= 30°C/}\text{kbar}$) to a two-phase assemblage of rutile plus ilmenite solid solution.A zirconian-armalcolite was synthesized and analyzed; 4 wt % ZrO₂ appears to saturate armalcolite at 1200°C and 1 atm. The breakdown of Zr-armalcolite occurs at pressures of 1–2 kbar less than those required for the breakdown of Zr-free armalcolite. The zirconium partitions approximately equally between rutile and ilmenite phases.The stability of armalcolite as a function of ?O₂ was determined thermogravimetrically at 1200°C and 1 atm by weighing sintered pellets in a controlled atmosphere furnace. Armalcolite, (Fe_0.5Mg_0.5)-Ti₂O₅, is stable over a range ?O₂ from about 10^?9.5to 10^?10.5 atm. Below this range to at least 10^?12.8 atm, ilmenite plus a reduced armalcolite are formed. These products were observed optically and by Mössbauer spectroscopy, and no metallic iron was detected; therefore, some of the titanium must have been reduced to Ti³⁺. This reduction may provide yet another mechanism to explain the common association of ilmenite rims around lunar armalcolites.     

Volcanic ash clouds affecting Northern Europe: the long view

The volcanic ash or ‘tephra’ cloud resulting from the relatively small (volume and VEI) eruption of the Icelandic volcano Eyjafjallajökull in 2010 caused major air travel disruption, at substantial global economic cost. On several occasions in the past few centuries, Icelandic eruptions have created ash and/or sulphur dioxide clouds which were detected over Europe (e.g. Hekla in 1947, Askja in 1875, and Laki in 1783). However, these historical observations do not represent a complete record of events serious enough to disrupt aviation in Europe. The only feasible evidence for this is within the geological tephra record. Ash layers are preserved in bogs and lakes where tephra deposited from the atmosphere is incorporated in the peat/mud. In this article we: 1, introduce the analysis of the Northern European sedimentary tephra record; 2, discuss our findings and modelling results; 3, highlight how these were misinterpreted by the popular media; and 4, use this experience to outline several existing problems with current tephra studies and suggest agendas for future research.     

Geochemistry of the Early Miocene volcanic succession of Northland,New Zealand,and implications for the evolution of subduction in the Southwest Pacific

Latest Oligocene and Early Miocene volcanic rocks occur on the Northland Peninsula, New Zealand, and record the inception of Cenozoic subduction-related volcanism in the North Island that eventually evolved to its present manifestation in the Taupo Volcanic Zone. This NW-striking Northland Arc is continuous with the Reinga Ridge and comprises two parallel belts of volcanic centres ca. 60 km apart. A plethora of tectonic models have been proposed for its origins. We acquired new trace element and Sr–Nd isotope data to better constrain such models. All Northland Arc rocks carry an arc-type trace element signature, however distinct differences exist between rocks of the eastern and western belt. Eastern belt rocks are typically andesites and dacites and have relatively evolved isotope ratios indicating assimilated crustal material, and commonly contain hornblende. Additionally some eastern belt rocks with highly evolved isotope compositions show fractionated REE compositions consistent with residual garnet, and some contain garnetiferous inclusions in addition to schistose crustal fragments. In contrast, western belt rocks are mostly basalts or basaltic andesites with relatively primitive Sr–Nd isotope compositions, do not contain hornblende and show no rare earth element evidence for cryptic amphibole fractionation. Eastern and western belt rocks contain comparable slab-derived fractions of fluid-mobile trace elements and invariably possess an arc signature. Therefore the difference between the belts may be best explained as due to variation in crustal thickness across the Northland Peninsula, where western belt centres erupted onto a thinner crustal section than eastern belt rocks.The consistent arc signature throughout the Northland arc favours an origin in response to an actual, if short-lived subduction event, rather than slab detachment as proposed in some models. No Northland Arc rocks possess a convincing adakite-like composition that might reflect the subduction of very young oceanic lithosphere such as that of the Oligocene South Fiji Basin. Therefore we favour a model in which subduction of old (Cretaceous) lithosphere drove subduction.     

Multi-segment earthquakes and tsunami potential of the Aleutian megathrust

Large to great earthquakes and related tsunamis generated on the Aleutian megathrust produce major hazards for both the area of rupture and heavily populated coastlines around much of the Pacific Ocean. Here we use paleoseismic records preserved in coastal sediments to investigate whether segment boundaries control the largest ruptures or whether in some seismic cycles segments combine to produce earthquakes greater than any observed since instrumented records began. Virtually the entire megathrust has ruptured since AD1900, with four different segments generating earthquakes >M8.0. The largest was the M9.2 great Alaska earthquake of March 1964 that ruptured ～800 km of the eastern segment of the megathrust. The tsunami generated caused fatalities in Alaska and along the coast as far south as California. East of the 1964 zone of deformation, the Yakutat microplate experienced two >M8.0 earthquakes, separated by a week, in September 1899. For the first time, we present evidence that earthquakes ～900 and ～1500 years ago simultaneously ruptured adjacent segments of the Aleutian megathrust and the Yakutat microplate, with a combined area ～15% greater than 1964, giving an earthquake of greater magnitude and increased tsunamigenic potential.