The stability of a remediated bed in Hamilton Harbour,Lake Ontario,Canada

ABSTRACT In situ measurements of lakebed sediment erodibility were made on three sites in Hamilton Harbour, Lake Ontario, using the benthic flume Sea Carousel. Three methods of estimating the surface erosion threshold (τ_c(0)) from a Carousel time series were evaluated: the first method fits measures of bed strength to eroded depth (the failure envelope) and evaluates threshold as the surface intercept; the second method regresses mean erosion rate (E_m) with bed shear stress and solves for the floc erosion rate (E_f) to derive the threshold for E_m = E_f = 1 × 10^?5 kg m^?2 s^?1; the third method extrapolates a regression of suspended sediment concentration (S) and fluid transmitted bed shear stress (τ₀) to ambient concentrations. The first field site was undisturbed (C) and acted as a control; the second (W) was disturbed through ploughing and water injection as part of lakebed treatment, whereas the third site (OIP) was disturbed and injected with an oxidant used for remediation of contaminated sediment. The main objectives of this study were: (1) to evaluate the three different methods of deriving erosion threshold; (2) to compare the physical behaviour of lacustrine sediments with their marine estuarine counterparts; and (3) to examine the effects of ploughing and chemical treatment of contaminated sediment on bed stability. Five deployments of Sea Carousel were carried out at the control site. Mean erosion thresholds for the three methods were: τ_c(0) = 0·5 (±0·06), 0·27 (±0·01) and 0·34 (±0·03) Pa respectively. Method 1 overpredicted bed strength as it was insensitive to effects in the surface 1–2 mm, and the fit of the failure envelope was also highly subjective. Method 2 exhibited a wide scatter in the data (low correlation coefficients), and definition of the baseline erosion rate (E_f) is largely arbitrary in the literature. Method 3 yielded stable (high correlation coefficients), reproducible and objective results and is thus recommended for evaluation of the erosion threshold. The results of this method correlated well with sediment bulk density and followed the same trend as marine counterparts from widely varying sites. Mass settling rates, expressed as a decay constant, k, of S(t), were strongly related to the maximum turbidity at the onset of settling (S_max) and were also in continuity with marine counterparts. Thus, it appears that differences in salinity had little effect on mass settling rates in the examples presented, and that biological activity dominated any effects normally attributable to changes in salinity. Bedload transport of eroded aggregates (2–4 mm in diameter) took place by rolling below a mean tangential flow velocity (U_y) of 0·32 ms^?1 and by saltation at higher velocities. Mass transport as bedload was a maximum at U_y = 0·4 ms^?1, although bedload never exceeded 1% of the suspended load. The proportion of material moving as bedload was greatest at the onset of erosion but decreased as flow competence increased. Given the low bulk density and strength of the lakebed sediment, the presence of a bedload component is notable. Bedload transport over eroding cohesive substrates should be greater in estuaries, where both sediment density and strength are usually higher. Significant differences between the ploughed and control sites were apparent in both the erosion rate and the friction coefficient (φ), and suggest that bed recovery after disruption is rapid (< 24 h). τ_c(0) increased linearly with time after ploughing and recovered to the control mean value within 3 days. The friction coefficient was reduced to zero by ploughing (diagnostic of fluidization), but increased linearly with time, regaining control values within 6 days. No long‐term reduction in bed strength due to remediation was apparent.     

Mass-independent fractionation of oxygen isotopes in the mesostasis of a chondrule from the Semarkona LL3.0 ordinary chondrite

A large chondrule from Semarkona, the most primitive ordinary chondrite known, has been discovered to contain a record of mass transport during its formation. In most respects, it is a normal Type I, group A1, low-FeO chondrule that was produced by reduction and mass-loss during the unidentified flash-heating event that produced the chondrules, the most abundant structural component in primitive meteorites. We have previously measured elemental abundances and abundance profiles in this chondrule. We here report oxygen isotope ratio abundances and ratio abundance profiles. We have found that the mesostasis is zoned in oxygen isotope ratio, with the center of the chondrule containing isotopically heavier oxygen than the outer regions, the outer regions being volatile rich from the diffusion of volatiles into the chondrule during cooling. The δ¹⁷O values range from −2.0‰ to 9.9‰, while δ¹⁸O range from −1.9‰ to 9.6‰. More importantly, a plot of δ¹⁷O against δ¹⁸O has a slope of 1.1 ± 0.2 (1σ) and 0.88 ± 0.10 (1σ) when measured by two independent methods. Co-variation of δ¹⁷O with δ¹⁸O that does not follow mass-dependent fractionation has often been seen in primitive solar system materials and is usually ascribed to the mixing of different oxygen reservoirs. We argue that petrographic and compositional data indicate that this chondrule was completely melted at the time of its formation so that relic grains could not have survived. Furthermore, there is petrographic and compositional evidence that there was no aqueous alteration of this chondrule subsequent to its formation. Although it is possible to formulate a series of exchanges between the chondrule and external ¹⁶O-rich and ¹⁶O-poor reservoirs that may explain the detailed oxygen isotope systematics of this chondrule, such a sequence of events looks very contrived. We therefore hypothesize that reduction, devolatilization, and crystallization of the chondrule melt may have produced ¹⁶O-rich olivines and ¹⁶O-poor mesostasis plotting on a slope-one line as part of the chondrule-forming process in an analogous fashion to known chemical mass-independent isotopic fractionation mechanisms. During cooling, volatiles and oxygen near the terrestrial line in oxygen isotope composition produced the outer zone of volatile rich and ¹⁶O-rich mesostasis. The chondrule therefore not only retains a record of considerable mass transport accompanying formation, but also may indicate that the isotopes of oxygen underwent mass-independent fractionation during the process.     

Rate of growth of the preserved North American continental crust: Evidence from Hf and O isotopes in Mississippi detrital zircons

Detrital zircons from the Mississippi River have been analyzed for U-Th-Pb, Lu-Hf and O isotopes to constrain the rate of growth of the preserved North American continental crust. One hundred and forty two concordant zircon U/Pb dates on grains mounted in epoxy, obtained by Excimer laser ablation ICP-MS method, resolved six major periods of zircon crystallization: 0-0.25, 0.3-0.6, 0.95-1.25, 1.3-1.5, 1.65-1.95 and 2.5-3.0 Ga. These age ranges match the ages of the recognized lithotectonic units of the North American continent in the hinterland of the Mississippi River. Ninety-six zircons mounted on tape, which show no age zonation and were within 7.5% of concordance, were selected to represent the six U/Pb age time intervals and analyzed for Lu-Hf and O isotope by laser ablation MC-ICP-MS and SHRIMP II, respectively. The δ¹⁸O values of the zircons show a small step increase in the maximum δ¹⁸O values at the Archean-Proterozoic boundary from 7.5‰ in the Archean to 9.5‰, and rarely 13‰, in the Proterozoic and Phanerozoic. However, the average value of δ¹⁸O in zircons changes little with time, showing that the increase in the maximum δ¹⁸O values between 2.5 and 2.0 Ga, which can be attributed to an increase in the sediment content of the source regions of younger granitoids, is largely balanced by an increase in zircons with anomalously low δ¹⁸O, which can be attributed to hydrothermally altered crust in the granitoid source region.εHf_i values for the zircons range from 13.1 to −26.9. Zircons derived from juvenile crust, which we define as having mantle δ¹⁸O (4.5-6.5‰) and lying within error of the Hf depleted mantle growth curve, are rare or absent in the Mississippi basin. The overwhelming majority of zircons crystallized from melted pre-existing continental crust, or mantle-derived magmas that were contaminated by continental crust. The average time difference between primitive crust formation and remelting for each of the recognized lithotectonic time intervals, which is defined as crustal incubation time in this study, is 890 ± 460 Myr. There is also a suggestion that the crustal incubation time increases with decreasing age in the Mississippi basin, which is consistent with the declining role of radioactive heat production in the lower crust with time.The average Hf model age (1.94 Ga), weighted by fraction of zircons in the river load is in reasonable agreement with the Nd model age (1.7 Ga) for the Mississippi River. However, if the zircons are weighted by the area of North America covered by the six recognized periods of zircon crystallization the average model age is 2.35 Ga, which compares favorably with an area weighted Nd model age of 2.36 Ga. Our preferred approach is to use the measured O isotope values to constrain variations in the ¹⁷⁶Lu/¹⁷⁷Hf ratio of the granitic source region from which the zircons crystallized, making the assumption that zircons with mantle-like O isotopic ratios have higher ¹⁷⁶Lu/¹⁷⁷Hf than zircons with higher O isotope values. This method gives an average Hf model age of 2.53 Ga, which is 180 Myr older than the constant ¹⁷⁶Lu/¹⁷⁷Hf calculation.The area weighted zircon Hf model ages show two distinct periods of crust formation for the North American continent, 1.6-2.2 and 2.9-3.4 Ga. At least 50% of the preserved North American continental crust was extracted from the mantle by 2.9 Ga and 90% by 1.6 Ga. Two similar periods of crustal growth are also recognized in Gondwana (Hawkesworth C. J. and Kemp A. I. S. (2006) Using hafnium and oxygen isotopes in zircons to unravel the record of crustal evolution. Chem. Geol.226, 144-162.), suggesting that these may be periods of global continental crustal growth. However, we stress that more data from other continents are required before the hypothesis of episodic global continental growth can be accepted with confidence.     

A morphological, sedimentological and geophysical investigation of the Woore Moraine, Shropshire, England

The Bar Hill-Whitchurch-Wrexham Morainic Complex is a large-scale glacial landform thought to represent either the maximum extent or the re-advance of the British-Irish Ice Sheet during the Late Devensian. The origin of the moraine remains uncertain as its key characteristics have not been studied in detail due to a lack of exposures from which its large-scale structure can be determined. The development of new technologies has enabled detailed examination of the topography and internal structure of such large-scale landforms. This paper describes a multi-disciplinary approach involving digital geomorphological mapping using enhanced resolution NextMAP™ digital surface models, geophysical imaging (electrical resistivity tomography) and conventional sedimentological analyses. This combination of techniques is useful for elucidating the origin of a large glacial landform in a region of poor exposure. Digital elevation models such as NextMAP™ offer an efficient and accurate method for landform-mapping, whilst electrical resistivity tomography was able to map the major constituent sediments of the moraine, which had in turn been identified in the single exposure available. Additional geophysical techniques should however be applied to provide further structural data and thereby enable a more detailed interpretation of the moraine's internal structure. Preliminary findings indicate that the moraine is a glaciotectonic landform composed of diamicton and glaciofluvial sediments, an origin consistent with recent suggestions that the Cheshire Plain contained an active ice lobe during the last glacial maximum.     

A TEM and EELS study of carbon in a melt fragment from the Gardnos impact structure

A carbon‐rich melt fragment from the Gardnos impact structure has been studied for a better understanding of the preservation and structural form(s) of carbon that have been processed by impact melting. The carbon was analyzed in situ in its original petrographic context within the melt fragment, using high‐resolution techniques including focused ion beam‐transmission electron microscopy and electron energy loss spectroscopy. Results show that the carbon is largely uniform and has a nanocrystalline grain size. The Gardnos carbon has a graphitic structure but with a large c/a ratio indicating disorder. The disorder could be a result of rapid heating to high temperatures during impact, followed by rapid cooling, with not enough time to crystallize into highly ordered graphite. However, temperature distribution during impact is extremely heterogenous, and the disordered Gardnos carbon could also represent material that avoided extreme temperatures, and thus, it was preserved. Understanding the structure of carbon during terrestrial impacts is important to help determine if the history of carbon within extraterrestrial samples is impact related. Furthermore, the degree of preservation of carbon during impact is key for locating and detecting organic compounds in extraterrestrial samples. This example from Gardnos, together with previous studies, shows that not all carbon is lost to oxidation during impact but that impact melting can encapsulate and preserve carbon where it is available.     

Annual to decadal morphodynamics of the foredune system at Greenwich Dunes,Prince Edward Island,Canada

The purpose of this study was to quantify relationships between season, sediment availability, sediment transport pathways, and beach/foredune morphology at Greenwich Dunes, PEI. This was done for periods ranging from a few days to multiple decades using erosion pins, bedframe measurements, annual surveys, and digital photogrammetry using historical aerial photographs. The relative significance of seasonal/annual processes versus response of the foredune system to broader geomorphic controls (e.g. relative sea level rise, storms, etc.) was also assessed. The data show that there are clear seasonal differences in the patterns of sand supply from the beach to the foredune at Greenwich and that there are differences in sediment supply to the foredune between the east and west reaches of the study area, resulting in ongoing differences in foredune morphology. They also demonstrate that models that incorporate wind climate alone, or even models that include other factors like beach moisture, would not be able to predict the amount of sediment movement from the beach to the foredune in this environment unless there were some way to parameterize system morphology, especially the presence or absence of a dune ramp. Finally, the data suggest that the foredune can migrate landward while maintaining its form via transfers of sediment from the stoss slope, over the crest, and onto the lee slope. Although the rate of foredune development or recovery after disturbance changes over time due to morphological feedback, the overall decadal evolution of the foredune system at Greenwich is consistent with, and supports, the Davidson‐Arnott (2005) conceptual model of dune transgression under rising sea level. Copyright © 2012 John Wiley & Sons, Ltd.     

Rapid adjustment of shoreline behavior to changing seasonality of storms: observations and modelling at an open‐coast beach

An 8‐year time series of weekly shoreline data collected at the Gold Coast, Australia, is used to examine the temporal evolution of a beach, focusing on the frequency response of the shoreline to time‐varying wave height and period. Intriguingly, during 2005 the movement of the shoreline at this site changed from a seasonally‐dominated mode (annual cycle) to a storm‐dominated (~monthly) mode. This unexpected observation provides the opportunity to explore the drivers of the observed shoreline response. Utilizing the calibration of an equilibrium shoreline model to explore the time‐scales of underlying beach behavior, the best‐fit frequency response (days^?1) is shown to be an order of magnitude higher post‐2004, suggesting that a relatively subtle change in wave forcing can drive a significant change in shoreline response. Analysis of available wave data reveals a statistically significant change in the seasonality of storms, from predominantly occurring at the start of the year pre‐2005 to being relatively consistent throughout the year after this time. The observed change from one mode of shoreline variability to another suggests that beaches can adapt relatively quickly to subtle changes in the intra‐annual distribution of wave energy. Copyright © 2016 John Wiley & Sons, Ltd.     

Using Diurnal Temperature Signals to Infer Vertical Groundwater‐Surface Water Exchange

Heat is a powerful tracer to quantify fluid exchange between surface water and groundwater. Temperature time series can be used to estimate pore water fluid flux, and techniques can be employed to extend these estimates to produce detailed plan‐view flux maps. Key advantages of heat tracing include cost‐effective sensors and ease of data collection and interpretation, without the need for expensive and time‐consuming laboratory analyses or induced tracers. While the collection of temperature data in saturated sediments is relatively straightforward, several factors influence the reliability of flux estimates that are based on time series analysis (diurnal signals) of recorded temperatures. Sensor resolution and deployment are particularly important in obtaining robust flux estimates in upwelling conditions. Also, processing temperature time series data involves a sequence of complex steps, including filtering temperature signals, selection of appropriate thermal parameters, and selection of the optimal analytical solution for modeling. This review provides a synthesis of heat tracing using diurnal temperature oscillations, including details on optimal sensor selection and deployment, data processing, model parameterization, and an overview of computing tools available. Recent advances in diurnal temperature methods also provide the opportunity to determine local saturated thermal diffusivity, which can improve the accuracy of fluid flux modeling and sensor spacing, which is related to streambed scour and deposition. These parameters can also be used to determine the reliability of flux estimates from the use of heat as a tracer.