Evidence for the trapped liquid shift effect in the Mount Ayliff Intrusion,South Africa

Postcumulus trapped liquid shift in layered complexes produces cumulate minerals with more fractionated compositions than the original primary phases. This effect is shown by olivine compositions from the base of the Mount Ayliff Intrusion, where varying proportions of olivine to interstitial liquid produce a suite of rocks which define a tight linear trend on a binary whole-rock plot of MgO versus FeO. Extrapolation of this trend constrains the composition of the primary cumulus olivine to the range Fo_84–86, whereas olivine actually present have compositions Fo_77–83. The magnitude of the discrepancy between the theoretical and observed olivine compositions correlates directly with the weight fraction of interstitial liquid. These observations are quantitatively predicted by the trapped liquid shift model. They also argue against significant migration of residual liquid. Trapped liquid shift is documented over a vertical interval of 60 m. It occurred in rocks lying only 1 m above the basal contact of the intrusion and hence must be a comparatively rapid process.     

Sea level,climate change and coastal evolution in Morar,northwest Scotland

Analyses of geomorphologically contrasting sites in Morar, NW Scotland, describe the forcing mechanisms of coastal change. Isolation basins (i.e. basins behind rock sills and now isolated from the sea following isostatic uplift) accumulated continuous marine and freshwater sediments from c.12 to 2 ka BP. Raised dune, marsh and wetland sites register breaching, migration and stability of dunes from c. 9 to 2 ka BP. High-resolution methods designed to address issues of macroscale and microscale sea-level changes and patterns of storminess include 1-mm sampling for pollen, dinocyst and diatom analyses, infra-red photography, X-ray photography and thin-section analysis. The data enhance the record of relative sea-level change for the area. Major phases of landward migration of the coast occurred during the period of low sea-level rise in the mid-Holocene as the rate of rise decreased from c. 3 to < 1 mm/year. Relative sea-level change controls the broad pattern of coastal evolution at each site; local site-specific factors contribute to short-term process change. There is no record of extreme events such as tsunami. Within a system of dynamic metastable equilibrium, the Holocene records show that site-specific factors determine the exact timing of system breakdown, e.g. dune breaching, superimposed on regional sea-level rise. The global average sea-level rise of 3 to 6 mm/yr by AD 2050 predicted by IPCC would only partly be offset in the Morar area by isostatic uplift of about 1 mm/yr. A change from relative sea-level fall to sea-level rise, in areas where the regional rate of uplift no longer offsets global processes, is a critical factor in the management of coastal resources.     

Advances in our understanding of the gem corundum deposits of the West Pacific continental margins intraplate basaltic fields

Recent discoveries over the last decade of new gemfields, exploitation of new and existing deposits, and application of relatively new techniques have greatly increased our knowledge of the basalt-derived gem sapphire–ruby–zircon deposits. In this paper we focus on the Late Mesozoic to Cenozoic intraplate basaltic fields of the West Pacific continental margins. We review advances made in understanding the genesis of these deposits, based on the application of newer techniques. We also critically review existing data on the gem corundum deposits, in order to further refine a model for their origin.In some of the intraplate basaltic fields, corundum-bearing xenoliths have been found showing a range of PT formation conditions from 790 °C at 0.85 GPa to as much as 1100 to 1200 °C at 1.0 to 2.5 GPa. Although most magmatic sapphires contain syngenetic inclusions of columbite-group phases, zircon, spinel and rutile, some contain additional nepheline and K-feldspar, suggesting crystallization from more undersaturated alkaline magma while the Weldborough field of NE Tasmania also contains molybdenite and beryl, suggesting at least some interaction with more fractionated ‘granitic-type’ magmas. There is a large range in PT conditions calculated for the metamorphic rubies (from 780 to 940 °C, through 800 to 1150 °C up to 1000 to 1300 °C). Fluid/melt inclusion studies on magmatic corundums generally suggest that they formed in a CO₂-rich environment from a ‘syenitic’ melt under a range of T conditions from 720 to 880 °C up to 1000 to 1200 °C. Oxygen isotope studies reveal that typical magmatic corundums have values of + 4.4 to 6.9‰, whereas metamorphic corundums from the same basaltic host have lower values of + 1.3 to 4.2‰.Geochronological studies have shown that some fields produced a simple eruptive and zircon/corundum crystallization event while others had multiple eruptive events but only one or two zircon crystallization events. For a few fields, some corundums/zircons crystallized in storage regions and then remained relatively inert for periods of 200 to 400 Ma without significant change before transport to the surface in the Cenozoic. Tectonic studies of the Australian region suggest that many of the corundums crystallized from magmas related to episodic basaltic volcanism in a tectonic regime of extension, associated with the opening of the Tasman and Coral Seas. For the Asian region, the magmatic–polygenetic corundums within the basaltic fields largely crystallized in a tectonic regime of distributed E–W extension, whereas the metamorphic-metasomatic corundums crystallised in a transpressional regime associated with the collision of the Indian Plate with the Eurasian Plate (e.g., [Garnier, V., Giuliani, G., Maluski, H., Ohnenstetter, D., Deloule, E., 2003. Ar–Ar and U–Pb ages of marble-hosted ruby deposits from Central and South-east Asia. Geophysical Research Abstracts 5, 03751; Garnier, V., Giuliani, G., Ohnenstetter, D., and Schwarz, D., 2004. Les gisements de corindon: classification et genese. Les placers a corindon gemme. Le Regne Mineral 55, 7-47; Garnier, V., Ohnenstetter, D., Giuliani, G., Maluski, H., Deloule, E., Phan Trong, T., Pham Van, L., Hoang Quang, V., 2005a. Age and significance of ruby-bearing marble from the Red River Shear Zone, Northern Vietnam. Canadian Mineralogist 43, 1315–1329]).     

Response of xenotime to prograde metamorphism

Xenotime is a widespread accessory mineral in lower greenschist to upper amphibolite facies metasedimentary rocks from the Palaeoproterozoic Mount Barren Group, southwestern Australia. Xenotime is closely associated with detrital zircon, commonly forming syntaxial outgrowths, in samples of sandstone, micaceous quartzite, slate, phyllite, garnet-bearing semi-pelites, and in kyanite-, garnet-, and staurolite-bearing mica schists. In situ geochronology of xenotime from lower greenschist sandstones has previously yielded multiple U–Pb ages with peaks at ~2.0, ~1.7, and ~1.65 Ga, interpreted to represent the age of detritus, early diagenesis, and a later thermal event, respectively. New U–Pb dating of xenotime in slate yields a major population at ~1.7 Ga with a minor population at ~1.2 Ga, reflecting diagenetic and metamorphic growth, respectively, whereas xenotime in phyllite forms a minor age population at ~1.7 Ga and a main peak at ~1.2 Ga. Mid-greenschist facies semi-pelitic schists (quartz-muscovite-garnet) contain xenotime that formed before 1.8 Ga and at 1.2 Ga, representing detrital and peak metamorphic ages, respectively. Xenotime in samples of amphibolite facies schist (650°C and ~8 kbars) yields U–Pb ages of ~1.2 Ga, coinciding with the time of peak metamorphism. A single analysis of a xenotime core from an amphibolite facies schist gave an age of ~1.8 Ga, consistent with the presence of detrital xenotime. Our results suggest that detrital xenotime may be preserved under greenschist facies conditions, but is largely replaced during upper amphibolite facies conditions. Detrital xenotime is replaced through dissolution–reprecipitation reactions forming compositionally distinct rims during greenschist and amphibolite facies metamorphism at 1.2 Ga. Diagenetic xenotime is present in lower greenschist facies samples, but was not observed in metasedimentary rocks that had experienced temperatures above mid-greenschist facies metamorphism (450°C). The apparent disappearance of detrital and diagenetic xenotime and appearance of metamorphic xenotime during prograde metamorphism indicates that some of the yttrium, heavy rare earth elements, and phosphorus needed for metamorphic xenotime growth are probably derived from the replacement of detrital and diagenetic xenotime.     

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.     

Private sector involvement in urban governance: The case of Business Improvement Districts and Town Centre Management partnerships in England

Although it has many merits, the voluminous literature on urban governance gives scant attention to the actual involvement and positioning of business elites and businesses within Public-Private Partnerships. There is also little consensus among academics as to why the private sector become involved in such schemes. This paper begins to address these issues through a critical empirical examination of how and why the private sector is involved with three English Town Centre Management (TCM) partnerships and the Business Improvement District (BID) subsidiaries all three partnerships have recently developed. In order to do this, the empirical study is guided by a conceptual framework that foregrounds the relationship between (a) the opening up and monitoring of ‘institutional space’ by partnerships and the state, and (b) the motivations and ‘constrained agency’ of the business elites. The paper demonstrates that the positioning of the private sector is more multifarious and fractured than previous studies of urban governance have suggested. It also reveals that business elites and businesses view their participation as an ‘investment’ that needs to accrue significant financial returns and that partnership and state officials are highly selective in their choice of ‘who governs’.     

A morphological, sedimentological and geophysical investigation of the Woore Moraine, Shropshire, England

The Bar Hill-Whitchurch-Wrexham Morainic Complex is a large-scale glacial landform thought to represent either the maximum extent or the re-advance of the British-Irish Ice Sheet during the Late Devensian. The origin of the moraine remains uncertain as its key characteristics have not been studied in detail due to a lack of exposures from which its large-scale structure can be determined. The development of new technologies has enabled detailed examination of the topography and internal structure of such large-scale landforms. This paper describes a multi-disciplinary approach involving digital geomorphological mapping using enhanced resolution NextMAP™ digital surface models, geophysical imaging (electrical resistivity tomography) and conventional sedimentological analyses. This combination of techniques is useful for elucidating the origin of a large glacial landform in a region of poor exposure. Digital elevation models such as NextMAP™ offer an efficient and accurate method for landform-mapping, whilst electrical resistivity tomography was able to map the major constituent sediments of the moraine, which had in turn been identified in the single exposure available. Additional geophysical techniques should however be applied to provide further structural data and thereby enable a more detailed interpretation of the moraine's internal structure. Preliminary findings indicate that the moraine is a glaciotectonic landform composed of diamicton and glaciofluvial sediments, an origin consistent with recent suggestions that the Cheshire Plain contained an active ice lobe during the last glacial maximum.     

Distribution of Palaeozoic tectonic superimposed unconformities in the Tarim Basin,NW China: significance for the evolution of palaeogeomorphology and sedimentary response

Seismic and drilling well data were used to examine the occurrence of multiple stratigraphic unconformities in the Tarim Basin, NW China. The Early Cambrian, the Late Ordovician and the late Middle Devonian unconformities constitute three important tectonic sequence boundaries within the Palaeozoic succession. In the Tazhong, Tabei, Tadong uplifts and the southwestern Tarim palaeo‐uplift, unconformities obviously belong to superimposed unconformities. A superimposed unconformity is formed by superimposition of unconformities of multiple periods. Areas where superimposed unconformities develop are shown as composite belts of multiple tectonic unconformities, and as higher uplift areas of palaeo‐uplifts in palaeogeomorphologic units. The contact relationship of unconformities in the lower uplift areas is indicative of truncation‐overlap. A slope belt is located below the uplift areas, and the main and secondary unconformities are characterized by local onlap reflection on seismic profiles. The regional dynamics controlled the palaeotectonic setting of the Palaeozoic rocks in the Tarim Basin and the origin and evolution of the basin constrained deposition. From the Sinian to the Cambrian, the Tarim landmass and its surrounding areas belonged to an extensional tectonic setting. Since the Late Ordovician, the neighbouring north Kunlun Ocean and Altyn Ocean was transformed from a spreading ocean basin to a closed compressional setting. The maximum compression was attained in the Late Ordovician. The formation of a tectonic palaeogeomorphologic evolution succession from a cratonic margin aulacogen depression to a peripheral foreland basin in the Early Caledonian cycle controlled the deposition of platform, platform margin, and deep‐water basin. Tectonic uplift during the Late Ordovician resulted in a shallower basin which was followed by substantial erosion. Subsequently, a cratonic depression and peripheral or back‐arc foreland basin began their development in the Silurian to Early–Middle Devonian interval. In this period, the Tabei Uplift, the Northern Depression and the southern Tarim palaeo‐uplift showed obvious control on depositional systems, including onshore slope, shelf and deep‐water basin. The southern Tarim Plate was in a continuous continental compressional setting after collision, whereas the southern Tianshan Ocean began to close in the Early Ordovician and was completely closed by the Middle Devonian. At the same time, further compression from peripheral tectonic units in the eastern and southern parts of the Tarim Basin led to the expansion of palaeo‐uplift in the Late Devonian–Early Carboniferous interval, and the connection of the Tabei Uplift and Tadong Uplift, thus controlling onshore, fluvial delta, clastic coast, lagoon‐bay and shallow marine deposition. Copyright © 2015 John Wiley & Sons, Ltd.