OPTIMIZED FAST HANKEL TRANSFORM FILTERS1

In the linear digital filter theory for calculation of Hankel transforms it is possible to find explicit series expansions for the filter coefficients. A method is presented for optimizing the Hankel filters calculated in this way. For a certain desired accuracy of computation, the sampling density and filter length are minimized by choosing the parameters determining the filter characteristics according to the analytical properties of the input function. A new approach to the calculation of the filter coefficients has been developed for these optimized filters. The length of the filters may be further reduced by introducing a shift in the sampling scheme.     

The magmatic- and hydrothermal-dominated fumarolic system at the Active Crater of Lascar volcano,northern Chile

Low-to-high temperature fumaroles discharging from the Active Crater of Lascar volcano (northern Chile) have been collected in November 2002, May 2005 and October 2006 for chemical and isotopic analysis to provide the first geochemical survey on the magmatic-hydrothermal system of this active volcano. Chemical and isotopic gas composition shows direct addition of high-temperature fluids from magmatic degassing, mainly testified by the very high contents of SO₂, HCl and HF (up to 87,800, 29,500 and 2,900 μmol/mol) and the high R/Ra values (up to 7.29). Contributions from a hydrothermal source, mainly in gas discharges of the Active Crater rim, has also been detected. Significant variations in fluid chemistry, mainly consisting of a general decrease of magmatic-related compounds, i.e. SO₂, have affected the fumarolic system during the period of observation, indicating an increase of the influence of the hydrothermal system surrounding the ascending deep fluids. The chemical composition of Active Crater fumaroles has been used to build up a geochemical model describing the main processes that regulate the fluid circulation system of Lascar volcano to be utilized in volcanic surveillance.     

Primary production in the Strait of Gibraltar: Carbon fixation rates in relation to hydrodynamic and phytoplankton dynamics

Primary production was studied at nine sites distributed within the Strait of Gibraltar (Southern Spain) and North-Western (NW) Alboran Sea by analyzing photosynthesis-irradiance (P–I) relationships and integrated primary production rates in relation to the different types of Deep Chlorophyll Maxima (DCM) detected in the area. The characteristics of the DCM were examined by several methods, including flow cytometry, quantification of transparent expolymer particles and fluorimetric measurements that were applied in order to assess the photo-physiological state of the phytoplankton assemblages with respect to their species composition and water column structure (hydrology). The photosynthetic parameters (derived from P–I relationships) and integrated primary production (range 6–644 mg m⁻² d⁻¹) responded greatly to the diverse DCM identified and thereby the spatial variability of the primary production observed in the region was found to depend upon the occurrence of the different types of phytoplankton accumulations, which were themselves indicative of the previous history of the water column. The net contribution of the primary production to the air–sea CO₂ exchange process was also evaluated in the area. Results indicated that this region behaved as a net sink for the atmospheric CO₂, with the intensity of the flux being strongly modulated by the wind intensity.     

Biotic and inorganic control on travertine deposition at Bullicame 3 spring (Viterbo, Italy): A multidisciplinary approach

A multidisciplinary characterization of an active thermal spring in central Italy has been undertaken with the aim of (i) ascertaining whether microbiological activity plays a relevant role in hot-depositing travertines and (ii) establishing an experimental protocol able to identify similar effects in fossil travertines. Water, gas, and travertine samples were investigated by chemical (ICP/MS, SEM/EDS), physical (DTA-DTG), isotopic (δ¹⁸O, δD, and δ¹³C), mineralogical (XRPD), and spectroscopic (EPR) techniques. Twenty-four samples (three for each phase) were collected every 5 °C temperature drop, along a ∼100 m long artificial channel near Viterbo (Bullicame 3, Latium, central Italy). A microbiological characterization was carried out in parallel, sampling the channel every 10 °C temperature drop.The Bullicame 3 system is revealed to be composed of two markedly different subsystems: a water/gas interface, where a kinetically fast exchange allows equilibrium of components both in water and in gases; a solid/water interface, where travertine precipitation occurs, influenced by microbiological activity. A peculiar lattice shrinking of calcite was identified, as well as an anomalous value of the zero-field splitting parameter from the EPR measurements. The interpretation of these anomalies is confirmed by the identification of calcifying cyanobacteria throughout the channel path.Our results point out that microbiological activity can play a significant role in travertine deposition from hot springs. Furthermore, the proposed approach, representing a tool to identify crystal chemical remnants of past microbiological activity, could be applicable to fossil travertines.     

Oxygen isotope fractionation in synthetic magnesian calcite

Mg-bearing calcite was precipitated at 25°C in closed system free-drift experiments from solutions containing NaHCO₃, CaCl₂ and MgCl₂. The chemical and isotope composition of the solution and precipitate were investigated during time course experiments of 24-h duration. Monohydrocalcite and calcite precipitated early in the experiments (<8 h), while Mg-calcite was the predominant precipitate (>95%) thereafter. Solid collected at the end of the experiments displayed compositional zoning from pure calcite in crystal cores to up to 23 mol% MgCO₃ in the rims. Smaller excursions in Mg were superimposed on this chemical record, which is characteristic of oscillatory zoning observed in synthetic and natural solid-solution carbonates of differing solubility. Magnesium also altered the predominant morphology of crystals over time from the {104} to {100} and {110} growth forms.The oxygen isotope fractionation factor for the magnesian-calcite-water system (as 10³lnα_Mg-cl-H2O) displayed a strong dependence on the mol% MgCO₃ in the solid phase, but quantification of the relationship was difficult due to the heterogeneous nature of the precipitate. Considering only the Mg-content and δ¹⁸O values for the bulk solid, 10³lnα_Mg-cl-H2O increased at a rate of 0.17 ± 0.02 per mol% MgCO₃; this value is a factor of three higher than the single previous estimate (Tarutani T., Clayton R.N., and Mayeda T. K. (1969) The effect of polymorphims and magnesium substitution on oxygen isotope fractionation between calcium carbonate and water. Geochim. Cosmochim. Acta 33, 987-996). Nevertheless, extrapolation of our relationship to the pure calcite end member yielded a value of 27.9 ± 0.02, which is similar in magnitude to published values for the calcite-water system. Although no kinetic effect was observed on 10³lnα_Mg-cl-H2O for precipitation rates that ranged from 10^3.21 to 10^4.60 μmol · m⁻² · h⁻¹, it was impossible to disentangle the potential effect(s) of precipitation rate and Mg-content on 10³lnα_Mg-cl-H2O due to the heterogeneous nature of the solid.The results of this study suggest that paleotemperatures inferred from the δ¹⁸O values of high magnesian calcite (>10 mol% MgCO₃) may be significantly underestimated. Also, the results underscore the need for additional experiments to accurately characterize the effect of Mg coprecipitation on the isotope systematics of calcite from a chemically homogeneous precipitate or a heterogeneous material that is analyzed at the scale of chemical and isotopic zonation.     

The AC-geoelectrical sounding method: a combined electric/electromagnetic prospecting tool

Since 1979 the Laboratory of Geophysics, University of Aarhus, has been developing a new prospecting tool for obtaining information on the topmost 100 m of the earth. The method is an extension of the conventional geoelectric sounding method, but instead of direct current (DC) the AC-geoelectrical sounding method uses alternating current (AC) with frequencies in the range 100 Hz to 20,000 Hz. The use of alternating current adds an inductive contribution to the ordinary galvanic electric field, thus producing two different sorts of information about the underlying earth structure. These two sets of information are, in many cases, of complementary nature, which enables determination of the ground parameters much more accurately than would otherwise be possible from ordinary DC-geoelectrical soundings. Among these cases is the high resistivity equivalence which appears so frequently in Danish Quaternary deposits.     

Age and composition of the Amanay Seamount, Canary Islands

A number of samples have been dredged from the upper parts of Amanay and El Banquete Seamounts, yet volcanic materials have been collected only on Amanay Seamount. Based on textural features and the presence or absence of kaersutite, two main types of olivine pyroxene basaltic rocks have been identified. The rocks are basanites with high enrichment in the most incompatible elements, similar to that displayed by Ocean Island Basalts. Samples from Amanay Seamount formed due to a low degree of melting of an enriched mantle, very similar to that which probably caused the Miocene volcanic activity of Fuerteventura. The age of Amanay volcanic rocks, 15.3 ± 0.4 and 13.1 ± 0.3 Ma, is similar to those of the older volcanic units exposed in the nearby islands (Gran Canaria, Fuerteventura and Lanzarote). This proves the formation of a separate submarine volcanic edifice coeval with the other edifices of the Eastern Canarian Volcanic Ridge. Volcanic activity on the submarine edifice is thought to have ceased at about 13 Ma, simultaneous with the adjacent main volcanic construction.     

Oceanographic and meteorological forcing of the pelagic ecosystem on the Gulf of Cadiz shelf (SW Iberian Peninsula)

The spatial and temporal distribution of physical, chemical and biological variables of the NE continental shelf of the Gulf of Cadiz were analyzed monthly during almost three annual cycles. This analysis was performed with the aim of deriving the main forcing factors controlling variability at inter-annual, seasonal and short-time scales. Meteorological forcing related to heavy episodes of rainfall that affected river discharges and the wind regime, controlled both the currents along the shelf together and the nutrient concentrations of the surface waters. Meteorological forcing in turn determined the subsequent development and maintenance of phytoplankton blooms. Superimposed on the seasonal cycle typical of temperate latitudes, the inputs of continental nutrients mainly from the Guadalquivir River, along with episodes of upwelling favored by the predominance of westerly winds triggered phytoplankton growth on the shelf, highlighting the markedly relevant role of this large estuary in the control of the biological activity on the shelf.     

重要性不同的现有结构抗震加固设计地震动参数研究

提出了重要性不同的现有结构抗震加固设计基准期取值原则,给出了现有结构抗震加固设防水准的定义。基于地震危险性特征分区,利用地震动参数的危险性曲线公式对重要性不同的现有结构抗震加固设计地震动参数进行了分析。同时,为了便于工程设计人员使用,给出了现有结构设计地震动参数取值的简化方法。最后,通过算例解释了理论方法和简化计算方法中抗震加固设计地震动参数的取值方法和步骤。     

早期碳酸盐胶结作用对砂岩孔隙演化的影响——以塔里木盆地满加尔凹陷志留系砂岩为例

塔里木盆地满加尔凹陷志留系砂岩为无障壁的潮坪、滨岸及辫状河三角洲沉积的岩屑砂岩和岩屑质石英砂岩,对满北和满东、满南地区志留系砂岩成岩作用序次尤其是碳酸盐胶结的时间、方式和特征、物性的对比研究认为:砂岩中碳酸盐胶结的时间早晚对砂岩孔隙演化具有重要影响,满北地区志留系砂岩发育有大量早期泥晶碳酸盐胶结,显微镜下研究表明这种胶结作用发生在岩石受到充分压实之前,呈基底式胶结,岩石颗粒呈点接触或漂浮状分布于早期碳酸盐胶结物之中,这种胶结作用抑制了岩石后期的压实作用。尽管目前其埋藏达5 000～6 500 m,但其经历的压实作用并不强烈,粒间发育大量早期的碳酸盐胶结物,后来这些胶结物被溶蚀,形成了大量次生孔隙。而在满东和满南地区的志留系砂岩,碳酸盐胶结发生在岩石经过充分压实之后,晚期的碳酸盐胶结物仅分布于岩石经充分压实后的粒间孔隙中,含量较前者低,后期可供溶蚀的碳酸盐比前者少,因而溶蚀形成的次生孔隙有限。因此,尽管满东满南地区志留系埋藏比满北浅（3 700～5 000 m）,碳酸盐胶结物含量也低,也发育晚期碳酸盐胶结物的溶蚀,但岩石的压实作用比满北强,物性比满北低差。这主要与碳酸盐胶结的早晚有关,早期碳酸盐胶结对孔隙演化具有明显控制作用,有利于岩石孔隙的保存,为后来的溶蚀形成次生孔隙提供了条件。