Mineralkogical and Petrochemical Characterisitics and Genesis of Laoniugou Geneiss in Jiapigou Gold Mine,Jilin Province

Detailed mineralogical and petrochemical studies show that the Laoniugou gneiss of the Jiapigou gold mine is composed mainly of plagioclase gneiss and irregular to lentiform plagioclase amphibolite melanic enclaves.The major element contents show an obvious bimodal and trondhjemitic series evolutional trend.This situation is significantly different from that encountered in bimodal calc-alkalic volcanic rocks in the rift-type Archaean greenstone belt.The contents of Rb,Sr and Ba are 7-21 ppm,153-363ppm and 201-1451 ppm respectively ,close to those of common Archaean grey gneisses.All the samples of plagioclase gneisses show positive Eu anomalies (even up to 4.6).The protoliths of the plagioclase gneiss are high-Al2O3 trondhjemitic series rocks,belonging to typical TTG of Archaean high-grade metamorphic terrain .The gneiss is quite similar to the B-type Amitsoq gneiss of W.Greenland .The authors believe that the plagioclase amphibolite enclaves are the relics of ancient oceanic crust while the plagioclase gneiss is the TTG ancient intrusive rock resulting from partial melting of the oceanic crust.     

Evidence for a new regional NW–SE fault and crustal structure in Tunisia derived from gravity data

A new Tunisian gravity map interpretation based on the Gaussian filtered residual anomaly, total horizontal gradient, and Moho discontinuity morphology established from gravity data exhibit a new regional northwest–southeast fault extending from Eastern Kairouan to Ghardimaou (Algeria–Tunisia Boundary). It presents a horizontal gradient maximum lineament that terminates the north–south Jurassic structures in the Kairouan plain. Further, this interpretation reveals other known fault systems and crustal structures in Tunisia. The new regional northwest–southeast fault constitutes with the north–south axis and Gafsa–Jefara faults the deepest faults coinciding with the Moho flexures, which had an important role in their initiation. They constitute the border intra‐continental crust faults of the Mesozoic rift. The newly recognized deep fault has critical implications for mineral and petroleum perspectives.     

The microscale cooling effects of water sensitive urban design and irrigation in a suburban environment

There is still considerable uncertainty about precipitation at high elevation in mountain terrain due to the relatively few in situ measurements available and to the particular variability of the parameter. In this study, several spatialization techniques were tested, some for climatological time scale and others for daily fields, for precipitation over the western Alps for the period of 1990–2012. The study domain and period were chosen for the quality of available in situ observations and density of the network. First, a weather-type classification was established with a technique based on canonical correlation analysis combining large- and regional-scale data. The spatialization techniques applied for the climatological time scale were adapted from the Aurelhy method which uses elevation and principal components of the topography as predictors. The spatialization techniques applied to daily fields were based on kriging of daily rain gauges and used the climatological fields as predictors. This study aims to validate the advantage of using the climatology of the weather type of the day as predictor for daily fields over a monthly climatology. The climatology of the weather type of the day seems to demonstrate some small improvement.Finally, annual means over the period of 1990–2012 were produced using several methods, including some from accumulation of daily fields and others from the spatialization of in situ station means. Precipitation at high elevations and vertical climatological gradients were particularly scrutinized. Annual means based on sums of daily fields seem to have better performances.This paper only presents results for precipitation but temperature was also analysed.     

The behaviour of platinum-group elements in basalts from the East Greenland rifted margin

. The continental flood basalts of the East Greenland volcanic rifted margin were extruded during continental breakup above the ancestral Iceland mantle plume at 55 Ma. Three distinct magma types, the low-Ti, high-Ti and very high-Ti series (LTS, HTS and VHTS respectively), are found intercalated in the ~6-km-thick Plateau Lava sequence. Incompatible trace elements indicate that the LTS are derived from a more depleted mantle source compared to HTS and VHTS. The LTS is characterised by increasing Cu (105 to 248 ppm) and Pd (7 to 24 ppb), constant Cu/Pd ratio (~10,000), and decreasing Ir (1.1 to <0.05 ppb) and Ru (1.8 to <0.3 ppb) concentrations during magmatic differentiation (16 to 7 wt% MgO). The constant Cu/Pd ratio reflects silicate- and chromite-dominated fractionation without concurrent segregation of sulphide. S-undersaturated differentiation is also indicated in the HTS, which also displays increasing Pd (6-16 ppb) and decreasing Ir concentrations (1 to <0.05 ppb) during differentiation, and the Cu/Pd ratios for the entire series average 21,000. However, some HTS samples have elevated Cu/Pd ratios (up to 33,000). Cu/Pd ratios in the HTS do not correlate with MgO, and this is interpreted to reflect varying Cu/Pd ratios of HTS parental magmas rather than S-saturated differentiation. During S-undersaturated differentiation of the LTS and HTS, Pt/Pd ratios decrease from 1.3 to 0.11 and 1.1 to 0.2 respectively, which indicates that Pd is much more incompatible than Pt during S-undersaturated differentiation. The VHTS consists exclusively of highly evolved samples with low MgO (6.6-6.1 wt%) and Pd/Ir ratios 98-228. Here, Cu/Pd ratios increase from 17,500 to 35,000 with decreasing Cr concentrations which indicate that these magmas experienced silicate fractionation with concurrent segregation of sulphide. The LTS represent melting of a depleted source and show high PGE concentrations and constant Cu/Pd ratios during S-undersaturated differentiation. Melting of a normal depleted upper mantle source generates S-saturated melts (MORB), and the depleted LTS source is therefore considered an extraordinary S-poor component within the ancestral Iceland plume. Of the three series, the VHTS contain the largest contribution from enriched mantle portions. The VHTS have similar PGE but much higher Nb concentrations for instance compared to the most evolved LTS and HTS samples, indicating that the enriched source contributes Nb but not PGE.     

Garnet and pyroxene compositions in some diamondiferous eclogites

Analyses are reported for garnet and pyroxene from 17 eclogites that contain diamond. The garnets contain small but significant contents of Na, Ti and P and the pyroxenes contain traces of K. The diamond-bearing eclogites do not constitute a unique compositional group but show a range of mineral compositions consistent with a very high P-T environment.     

Spatial and temporal patterns of sediment storage over 45 years in Carnation Creek,BC, a previously glaciated mountain catchment

The movement of sediment through mountain river networks remains difficult to predict, as processes beyond streamflow and particle size are responsible for the entrainment and transport of bedload sediment. In deglaciated catchments, additional complexity arises from glacial impacts on landscape organization. Research to date indicates that the quantity of sediment stored in the channel is an important component of sediment transport in systems which alternate between supply and transport limited states, but limited long-term field data exist which can capture storage-transfer dynamics over a timescale encompassing episodic supply typical of mountain streams. We use a 45-year dataset with annual and decadal-scale data on sediment storage, channel morphology, and wood loading to investigate the spatial and temporal organization of storage in Carnation Creek, a previously glaciated 11 km² catchment on Vancouver Island, British Columbia. Sediment is supplied episodically to the channel, including additions from debris flows in the early 1980s just upstream of the studied channel region. Analyzing the spatial and temporal organization of sediment storage along 3.0 km of channel mainstem reveals a characteristic storage wavelength similar to the annual bedload particle travel distance. Over time, two scales of variation in storage are observed: small-scale fluctuation of 3–10 years corresponding to local erosional and depositional processes, and larger scale response over 25–35 years related to supply of sediment from hillslopes. Complex relationships between storage and sediment transfer (i.e., annual change in storage) are identified, with decadal-scale hysteresis present in storage-transfer relations in sites influenced by hillslope sediment and logjams. We propose a conceptual model linking landscape organization to temporal variability in storage and to storage–export cycles. Collectively, our results reaffirm the importance of storage to sediment transport and channel morphology, and highlight the complexity of storage–transport interactions. © 2019 John Wiley & Sons, Ltd.     

SmNd age and REE geochemistry of Proterozoic arc-related igneous rocks in the Richtersveld subprovince, Namaqua Mobile Belt, Southern Africa

Igneous rocks of the Richtersveld Subprovince in South Africa and Namibia form a Palaeo-Mesoproterozoic arc complex, dominated by extrusive andesites and their plutonic equivalents (diorites, tonalites), although the whole spectrum of rock types from ultramafic to felsic is present. SmNd isotope data indicate an extrusion age of 2000 Ma, thereby confirming previously published RbSr and UThPb ages. Initial Nd, Sr and Pb isotope ratios indicate a juvenile crust-producing episode at this time, with rapid recycling of young crust to generate rhyolitic and granitic components within the arc complex. The Richtersveld Subprovince represents the oldest crust in the western Namaqua Province, which was subsequently recycled during post 2.0 Ga tectonothermal events, especially the 1200–1000 Ma Kibaran episode.     

Trace metals and radium in the Gulf of Mexico: An evaluation of river and continental shelf sources

Several studies have provided evidence for the enrichment of trace elements in coastal waters, particularly for copper. These enrichments have been attributed to diffusion from continental shelf sediments and to an influx of river water. We attempted to resolve between these sources by undertaking an extensive suite of measurements of trace metals (Cu, Ni, Cd), ²²⁶Ra and ²²⁸Ra in the surface waters of the Gulf of Mexico, along with trace metal profiles at 6 stations (April 1981 and December 1982). These data establish that enrichments of copper, nickel and cadmium occur in the shallow waters of the Gulf of Mexico. On the Mississippi continental shelf, high trace element concentrations (Cu, Ni: ～ 9 nmol/kg; Cd: ～ 200 pmol/kg) in lower-salinity waters (26‰) are similar to those observed in the Mississippi plume at the same salinity. This evidence suggests a river water source. On the other hand, trace element enrichments are also observed in the northern Gulf (Cu: +0.4 nmol/kg; Ni: +0.5 nmol/kg; Cd: +20 pmol/kg) which coincide with an increase in ²²⁸Ra but are not accompanied by decreased salinity. The excess of evaporation over precipitation in this region makes it possible that this water could be evaporated estuarine water; therefore, hydrographic observations cannot distinguish readily between river and shelf sources. A regional flux balance shows that most of the excess copper in the surface waters of the Florida Current can be supplied by the river-borne dissolved copper flux. Within the uncertainties of such calculations, the continental shelf copper flux must be less than or equal to the river flux.     

Salinity and Temperature Effects on Element Incorporation of Gulf Killifish <Emphasis Type="Italic">Fundulus grandis</Emphasis> Otoliths

Many applications of otolith chemistry use the ratios of strontium (Sr) and barium (Ba) to calcium (Ca) as indicators of salinity exposure, because typically, as salinity increases, Sr concentration increases and Ba concentration decreases. However, these relationships are nonlinear, can be confounded by temperature, and investigations of salinity and temperature effects on otolith chemistry produce varied results. To determine the relationships of temperature and salinity on Sr:Ca and Ba:Ca in otoliths, we used free ranging Gulf Killifish (Fundulus grandis) in the northern Gulf of Mexico. This species is ideal because it is euryhaline and exhibits limited movements. Otolith edge Sr:Ca and Ba:Ca ratios were related to the previous 30-day mean salinity and temperature experienced by fish. The best model to describe otolith Sr:Ca was one that included a positive asymptotic relationship for both salinity and temperature. However, the salinity asymptotic maximum was reached at 10 psu and changes in otolith Sr:Ca above 10 psu were indicative of temperature changes. Otolith Ba:Ca exhibited an exponential decreasing relationship with salinity, and an exponential increasing relationship with temperature, and these two models combined best explained otolith Ba:Ca. Above 10 psu, the modeled Ba:Ca ratio continued to decrease demonstrating that this ratio may be indicative of salinity changes beyond this value. Therefore, using both Sr:Ca and Ba:Ca could be beneficial in reconstructing fish environmental histories. Temperature effects on otolith element ratios could confound past salinity reconstructions as well and must be a result of endogenous processes, given that no relationship between temperature and water chemistry existed.