Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.     

Zircon LA-ICP-MS U-Pb age, Ce^4＋/Ce^3＋ ratios and the geochemical features of the Machangqing complex associated with copper deposit

1IntroductionQuite a number of porphyry copper deposits havebeen found in the Cenozoic alkali-intrusions along theJinshajiang-Ailaoshan-Red River fault zone,whichconstitute the Cenozoic ore belt in China.The Cenozo-ic alkali-intrusive rocks are similar in…     

VSP资料约束地层反滤波研究

浅地表的低速带和地层滤波作用导致地震信号的能量衰减,地震子波的高频快速衰减,速度频散的子波变形,对地震底层分析带来了严重的影响。地层反滤波算法就是为了消除地层对子波的影响,利用VSP中的直达下行波推算出每个地层滤波算子,计算出各个地层滤波算子的反算子,然后利用这些反算子恢复出地表记录中损失掉的高频成分,减弱地层滤波对波形的影响,增加地表记录的频率成分和波形的准确度。分析实际地震资料表明,经过地层反滤波处理后的记录频率成分明显提升,地质构造更加准确、清晰。     

存储区域网技术及其在国土资源行业中的应用

本文简要介绍了存储区域网(SAN)的概念、结构及特点,对SAN与DAS、NAS存 储模式在性能、可用性等方面做了比较,并结合具体建设案例,指出了国土资源行业 存储系统建设采用SAN结构的优势。     

Land-Parcel Land-Use History as a Key to Site Selection for Documenting Soil Contamination Risk： a Case Study from Australian Suburbia

In that orcharding in early-to-mid twentieth century southeastern Australia involved use of certain heavy metal and As compounds in regular pest-control spray procedures, some interest attaches to the possibility that these landparcels are underlain by soils with above-background Cu, Pb and As levels. Interpreta- tion of Land-cover changes allowed land parcels previously occupied by orchards to be identified in the 1950s through time-series air-photos. A comparison of soil analysis results referring to soil samples from control sites, and from land parcels formerly occupied by orchardists, shows that contamination （above-background） levels of cations in the pesticides can be found in the top 6 cm of former orchard soils. It is clear that digital spatial data handling and culturally-informed air photo interpretation has a place in soil contamination studies, land-use planning （with particular reference to re-development） and in administration of public health.