Local air temperature tolerance: a sensible basis for estimating climate variability

The customary representation of climate using sample moments is generally biased due to the noticeably nonstationary behaviour of many climate series. In this study, we introduce a moment-free climate representation based on a statistical model fitted to a long-term daily air temperature anomaly series. This model allows us to separate the climate and weather scale variability in the series. As a result, the climate scale can be characterized using the mean annual cycle of series and local air temperature tolerance, where the latter is computed using the fitted model. The representation of weather scale variability is specified using the frequency and the range of outliers based on the tolerance. The scheme is illustrated using five long-term air temperature records observed by different European meteorological stations.     

Lead isotope and trace element composition of K-feldspars from peraluminous granitoids of the Late Devonian South Mountain Batholith (Nova Scotia, Canada): implications for petrogenesis and tectonic reconstruction

The South Mountain Batholith (SMB) of southwestern Nova Scotia (Canada) is a Late Devonian (~375 Ma) composite intrusion, which crops over an area of about 7,300 km². This peraluminous granitoid body consists of rocks ranging from granodiorite through monzogranite and leucomonzogranite to leucogranite that locally host greisen tin-base metal mineralization. K-feldspar displays large compositional variations of trace elements and Pb isotopic ratios, particularly in the highly fractionated rocks. Many variations are consistent with processes of fractional crystallization, but a distinct enrichment of Rb, Li and Cs accompanied by low K/Rb, Ba/Rb, Eu/Eu* and K/Cs ratios point to the role of fluids during the late stages of magmatic evolution. The correlation of Pb isotopic ratios with the enriched elements and their ratios implies that the isotopic variations are an integral part of the evolution of the SMB. Together with well-defined isochronal relationships of Pb systems in the feldspars, the correlation suggests that fractional crystallization accompanied in the late stages by fluid fractionation led to the formation of Li–F-rich leucogranites. Internally derived U-rich fluids fractionated U/Pb ratios, which in turn produced distinct variations of ²⁰⁶Pb/²⁰⁴Pb and ²³⁸U/²⁰⁴Pb ratios in K-feldspars. This implies that the Pb isotopic values of K-feldspar, which have traditionally been used for tectonic reconstructions, might have been modified in many granitic rocks. Thus, only early magmatic K-feldspars, which show no discernible effects of fluid fractionation yield the initial Pb isotopic compositions of the parental granitic magmas and their sources. The data also show that the geochemical characteristics of the leucogranites are the results of magmatic evolution rather than a distinctive source.     

Radium uptake during barite recrystallization at 23 ± 2 °C as a function of solution composition: An experimental Ba and Ra tracer study

High-purity synthetic barite powder was added to pure water or aqueous solutions of soluble salts (BaCl₂, Na₂SO₄, NaCl and NaHCO₃) at 23 ± 2 °C and atmospheric pressure. After a short pre-equilibration time (4 h) the suspensions were spiked either with ¹³³Ba or ²²⁶Ra and reacted under constant agitation during 120-406 days. The pH values ranged from 4 to 8 and solid to liquid (S/L) ratios varied from 0.01 to 5 g/l. The uptake of the radiotracers by barite was monitored through repeated sampling of the aqueous solutions and radiometric analysis. For both ¹³³Ba and ²²⁶Ra, our data consistently showed a continuous, slow decrease of radioactivity in the aqueous phase.Mass balance calculations indicated that the removal of ¹³³Ba activity from aqueous solution cannot be explained by surface adsorption only, as it largely exceeded the 100% monolayer coverage limit. This result was a strong argument in favor of recrystallization (driven by a dissolution-precipitation mechanism) as the main uptake mechanism. Because complete isotopic equilibration between aqueous solution and barite was approached or even reached in some experiments, we concluded that during the reaction all or substantial fractions of the initial solid had been replaced by newly formed barite.The ¹³³Ba data could be successfully fitted assuming constant recrystallization rates and homogeneous distribution of the tracer into the newly formed barite. An alternative model based on partial equilibrium of ¹³³Ba with the mineral surface (without internal isotopic equilibration of the solid) could not reproduce the measured activity data, unless multistage recrystallization kinetics was assumed. Calculated recrystallization rates in the salt solutions ranged from 2.8 × 10⁻¹¹ to 1.9 × 10⁻¹⁰ mol m⁻² s⁻¹ (2.4-16 μmol m⁻² d⁻¹), with no specific trend related to solution composition. For the suspensions prepared in pure water, significantly higher rates (∼5.7 × 10⁻¹⁰ mol m⁻² s⁻¹ or ∼49 μmol m⁻² d⁻¹) were determined.Radium uptake by barite was determined by monitoring the decrease of ²²⁶Ra activity in the aqueous solution with alpha spectrometry, after filtration of the suspensions and sintering. The evaluation of the Ra uptake experiments, in conjunction with the recrystallization data, consistently indicated formation of non-ideal solid solutions, with moderately high Margules parameters (W_AB = 3720-6200 J/mol, a₀ = 1.5-2.5). These parameters are significantly larger than an estimated value from the literature (W_AB = 1240 J/mol, a₀ = 0.5).In conclusion, our results confirm that radium forms solid solutions with barite at fast kinetic rates and in complete thermodynamic equilibrium with the aqueous solutions. Moreover, this study provides quantitative thermodynamic data that can be used for the calculation of radium concentration limits in environmentally relevant systems, such as radioactive waste repositories and uranium mill tailings.     

On the formation of element carbon during decomposition of CaCO3 at High P-T parameters under reducing conditions

This work presents data on the experimental study of CaCO₃ stability (3.0–5.5 GPa; 1300–1400°C) under reducing conditions modeling the presence of metallic iron. It is established that CaCO₃ is stable at the above P-T parameters under reducing conditions (in the presence of metallic Ti). CaCO₃ decomposed only when it chemically interacted with iron, forming Ca-ferrites and releasing solid carbon in the form of graphite in the closed system (in sealed Pt-ampoules).     

Thermodynamics of accelerating and rotating black holes

Thermodynamics of a large family of black holes from electrovacuum solutions of Einstein’s equations is studied. This family includes rotating and non-accelerating black holes with NUT charge, and rotating and accelerating black holes. The surface gravity, Hawking temperature and the area laws for these black holes are presented. The first law of thermodynamics is also given. An interesting outcome of our analysis is the restriction obtained on the magnitude of acceleration for these black holes.     

Temperature of interstellar warm ionized medium

This investigation on the temperature of the interstellar warm ionized medium (WIM) is characterized by the number and energy balance of the constituents of the WIM complex plasma viz. H plasma (electrons/ions/neutral atoms) and graphite dust, having a size distribution, characterized by the MRN (Mathis, Rumpl and Nordsieck) power law. Ionization of neutral atoms, electron–ion recombination, photoemission of electrons from and accretion on the dust and cooling through electron collisional excitation, followed by radiative decay of atoms has been included in the analysis. An appropriate expression for the rate of emission and mean energy of photoelectrons emitted from the surface of positively charged dust particles has been used which takes into account the dependence of absorption efficiency on wavelength of the radiation, radius of the particle and spectral irradiance distribution. The results of the parametric analysis have been displayed graphically. It is seen that the consensus values of temperature, surface potential on the dust particles and electron/ion/neutral atom densities, characteristic of interstellar warm ionized medium can be explained on the basis of plausible combinations of the dust particle density n _d and the parameter f _ex α _ex , where f _ex is the fraction of the energy of the neutral gas atoms which gets irradiated, α _ex n _e n _n is the number of the neutral atoms, which get excited per unit volume per unit time and n _e (n _n ) correspond to the density of electrons (neutral atoms).     

Effect of Variable Background on an Oscillating Hot Coronal Loop

We investigate the effect of a variable, i.e. time-dependent, background on the standing acoustic (i.e. longitudinal) modes generated in a hot coronal loop. A theoretical model of 1D geometry describing the coronal loop is applied. The background temperature is allowed to change as a function of time and undergoes an exponential decay with characteristic cooling times typical for coronal loops. The magnetic field is assumed to be uniform. Thermal conduction is assumed to be the dominant mechanism for damping hot coronal oscillations in the presence of a physically unspecified thermodynamic source that maintains the initial equilibrium. The influence of the rapidly cooling background plasma on the behaviour of standing acoustic (longitudinal) waves is investigated analytically. The temporally evolving dispersion relation and wave amplitude are derived by using the Wenzel–Kramers–Brillouin theory. An analytic solution for the time-dependent amplitude that describes the influence of thermal conduction on the standing longitudinal (acoustic) wave is obtained by exploiting the properties of Sturm–Liouville problems. Next, numerical evaluations further illustrate the behaviour of the standing acoustic waves in a system with a variable, time-dependent background. The results are applied to a number of detected loop oscillations. We find a remarkable agreement between the theoretical predictions and the observations. Despite the emergence of the cooling background plasma in the medium, thermal conduction is found to cause a strong damping for the slow standing magneto–acoustic waves in hot coronal loops in general. In addition to this, the increase in the value of thermal conductivity leads to a strong decay in the amplitude of the longitudinal standing slow MHD waves.