Effects of natural and calcined oyster shells on Cd and Pb immobilization in contaminated soils

In Korea, soils adjacent to abandoned mines are commonly contaminated by heavy metals present in mine tailings. Further, the disposal of oyster shell waste by oyster farm industries has been associated with serious environmental problems. In this study, we attempted to remediate cadmium (Cd)- and lead (Pb)-contaminated soils typical of those commonly found adjacent to abandoned mines using oyster shell waste as a soil stabilizer. Natural oyster shell powder (NOSP) and calcined oyster shell powder (COSP) were applied as soil amendments to immobilize Cd and Pb. The primary components of NOSP and COSP are calcium carbonate (CaCO₃) and calcium oxide (CaO), respectively. X-ray diffraction, X-ray fluorescence and scanning electron microscope analyses conducted in this study revealed that the calcination of NOSP at 770°C converted the less reactive CaCO₃ to the more reactive CaO. The calcination process also decreased the sodium content in COSP, indicating that it was advantageous to use COSP as a liming material in agricultural soil. After 30 days of incubation, we found that the 0.1 N HCl-extractable Cd and Pb contents in soil decreased significantly as a result of an increase in the soil pH and the formation of metal hydroxides. COSP was more effective in immobilizing Cd and Pb in the contaminated soil than NOSP. Overall, the results of this study suggest that oyster shell waste can be recycled into an effective soil ameliorant.     

Numerical forecasting of the time interval between successive M8 earthquakes along the Nankai Trough,southwest Japan,using ocean bottom cable network data

One possible approach to estimating the time interval between large-scale Tōnankai (Tōkai) and Nankai earthquakes on the Japan arc is sequential assimilation of crustal deformation data. We conducted numerical modeling of sequential assimilation using surface deformation calculated from earthquake generation cycle simulations along the Nankai Trough. To account for observation noise, we used measured ocean bottom pressure gauge data, excluding tidal modulation, from a station on the ocean bottom cable network Dense Oceanfloor Network System for Earthquakes and Tsunamis in the Kumano basin. We used sequential importance sampling as our data assimilation method. We found that as the amount of data increased, the estimated time interval between the Tōnankai and Nankai earthquakes approached the “true” observed interval. In addition, the noise in the pressure gauge data was sufficiently small that simulated crustal deformation patterns could be distinguished for different time intervals.     

Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

Double injection events of mafic magma into supersolidus Yucheon granites to produce two types of mafic enclaves in the Cretaceous Gyeongsang Basin,SE Korea

Petrographic and geochemical features of the Cretaceous Yucheon granites and their mafic microgranular/magmatic enclaves (MMEs), SE Korea, reveal that the MMEs originated from magma mixing. Mesoscopic and microscopic features indicate that mechanical mixing operated heterogeneously to produce the MMEs with a wide range of sizes and textures. Chemical compositions of amphibole, biotite, and plagioclase rims of both the MMEs and host granites are almost identical, indicating that chemical homogenization took place to some extent after the mechanical mixing. Plagioclase cores, however, have various compositions depending on the host rocks and/or sampling locations, suggesting their sluggish re-equilibration. The MMEs are divided into Type A (low TiO₂, very fine-grained, chilled margins) and Type B (high TiO₂, fine- to medium-grained, no chilled margins). The lower TiO₂ MMEs cooled more rapidly and interacted with granitic magma for a shorter period of time than the higher TiO₂ MMEs. Additionally, the former are less enriched in HREEs than the latter. Zoned plagioclase has two zones of increased An content. These features are indicative of double injection events of mafic magma. A previous model explains the magma mixing as resulting from the generation of a slab window due to Kula-Pacific ridge subduction. The model cannot, however, explain the eastward younging of the granites in Korea, necessitating a new, more elaborate model of Cretaceous geodynamics and magmatism in East Asia.     

Strategically Locating Wildlife Crossing Structures for Florida Panthers Using Maximal Covering Approaches

Crossing structures are an effective method for mitigating habitat fragmentation and reducing wildlife‐vehicle collisions, although high construction costs limit the number that can be implemented in practice. Therefore, optimizing the placement of crossing structures in road networks is suggested as a strategic conservation planning method. This research explores two approaches for using the maximal covering location problem (MCLP) to determine optimal sites to install new wildlife crossing structures. The first approach is based on records of traffic mortality, while the second uses animal tracking data for the species of interest. The objective of the first is to cover the maximum number of collision sites, given a specified number of proposed structures to build, while the second covers as many animal tracking locations as possible under a similar scenario. These two approaches were used to locate potential wildlife crossing structures for endangered Florida panthers (Puma concolor coryi) in Collier, Lee, and Hendry Counties, Florida, a population whose survival is threatened by excessive traffic mortality. Historical traffic mortality records and an extensive radio‐tracking dataset were used in the analyses. Although the two approaches largely select different sites for crossing structures, both models highlight key locations in the landscape where these structures can remedy traffic mortality and habitat fragmentation. These applications demonstrate how the MCLP can serve as a useful conservation planning tool when traffic mortality or animal tracking data are available to researchers.     

Effect of growing watershed imperviousness on hydrograph parameters and peak discharge

An increasing impervious area is quickly extending over the Wu‐Tu watershed due to the endless demands of the people. Generally, impervious paving is a major result of urbanization and more recently has had the potential to produce more enormous flood disasters than those of the past. In this study, 40 available rainfall–runoff events were chosen to calibrate the applicable parameters of the models and to determine the relationships between the impervious surfaces and the calibrated parameters. Model inputs came from the outcomes of the block kriging method and the non‐linear programming method. In the optimal process, the shuffled complex evolution method and three criteria were applied to compare the observed and simulated hydrographs. The tendencies of the variations of the parameters with their corresponding imperviousness were established through regression analysis. Ten cases were used to examine the established equations of the parameters and impervious covers. Finally, the design flood routines of various return periods were furnished through use of approaches containing a design storm, block kriging, the SCS model, and a rainfall‐runoff model with established functional relationships. These simulated flood hydrographs were used to compare and understand the past, present, and future hydrological conditions of the watershed studied. In the research results, the time to peak of flood hydrographs for various storms was diminished approximately from 11 h to 6 h in different decrements, whereas peak flow increased respectively from 127 m³ s^?1 to 629 m³ s^?1 for different storm intensities. In addition, this study provides a design diagram for the peak flow ratio to help engineers and designers to construct hydraulic structures efficiently and prevent possible damage to human life and property. Copyright © 2007 John Wiley & Sons, Ltd.     

Flows within the Ekman layer during spin-up of a thermally stratified fluid

Abstract

Finite-difference numerical solutions were obtained to present the flow and temperature field details within the transient Ekman layer during spin-up of a thermally stratified fluid in a cylinder. This complements the earlier studies on stratified spin-up which examined the flows in the interior core region. As the stratification increases, the following changes in the flow field are noticeable. The radial velocity in the Ekman layer decreases in magnitude. The azimuthal flows adjust smoothly from the interior region to the endwall boundary, and the Ekman layer in the azimuthal flow field fades. Vertical motions are inhibited, resulting in a weakened Ekman pumping. The axial vorticity field behaves similarly to the azimuthal flows. The temperature deviation from the equilibrium profile decreases, and the heat transfer flux from the endwall to the fluid decreases. The thickness of the thermal layer is larger than the velocity layer thickness. Illustrative comparisons of the relative sizes of the terms in the governing equations are conducted in order to assess the stratification effect in the adjustment process of the fluid.