Mitigation of asphaltics deposition during CO2 flood by enhancing CO2 solvency with chemical modifiers

CO₂ injected in the reservoir of McElroy Field, TX, for a CO₂ flood was in the supercritical state. Supercritical CO₂ fluid is capable of extracting light and intermediate hydrocarbons from rocks but is unable to extract heavy hydrocarbons and asphaltics. Therefore, plugging of asphaltics in reservoir rocks and a consequent reduction in injectivity and recovery may result when CO₂ only is used in enhanced oil recovery. By adding common solvents as chemical modifiers, the flooding fluid shows marked improvement in solvency for heavy components of crudes due to its increased density and polarity. Numerous supercritical CO₂ fluid extractions of dolomite rock from the Grayburg Formation containing known amount of spiked McElroy crude oil have been carried out to evaluate extraction efficiencies of CO₂ and CO₂ with chemical modifiers at various temperatures and pressures. All experiments show that extraction efficiency increases with increasing CO₂ pressure but decreases with increasing temperature. Addition of chemical modifiers to CO₂ also shows improved extraction efficiency and reduced asphaltic deposits. Under the pressure and temperature similar to McElroy reservoir conditions; chemically modified CO₂ yielded almost 3 times as much oil extracts as those in extractions with CO₂ only. It also reduced the asphaltics content in extracted rocks to nearly one half; indicating its potential for mitigating asphaltics plugging of formation rocks     

Escaping the Territorially Trapped East Asian Developmental State Thesis

Using a multiscalar approach, there has been a recent increase in geographic critiques of the East Asian developmental state thesis (DST). These critiques argue that the existing DST literature is epistemologically caught in a territorial trap. There has been less concern, however, about the methodology related to this research. In this article, I suggest that scholars consider not only the epistemological perspective but also the methodological dimension to effectively exploit the less territorially trapped DST research. Based on these analyses, this article emphasizes that interdisciplinary research using a multiscalar methodology and epistemology is required to better explain economic development in East Asia.     

A fixed full-matrix method for determining ice sheet height change from satellite altimeter: an ENVISAT case study in East Antarctica with backscatter analysis

A new method, called the fixed full-matrix method (FFM), is used to compute height changes at crossovers of satellite altimeter ground tracks. Using the ENVISAT data in East Antarctica, FFM results in crossovers of altimeter heights that are 1.9 and 79 times more than those from the fixed half method (FHM) and the one-row method (ORM). The mean standard error of height changes is about 14 cm from ORM, which is reduced to 7 cm by FHM and to 3 cm by FFM. Unlike FHM, FFM leads to uniform errors in the first-half and second-half height-change time series. FFM has the advantage in improving the accuracy of the change of height and backscattered power over ORM and FHM. Assisted by the ICESat-derived height changes, we determine the optimal threshold correlation coefficient (TCC) for a best correction for the backscatter effect on ENVISAT height changes. The TCC value of 0.92 yields an optimal result for FFM. With this value, FFM yields ENVISAT-derived height change rates in East Antarctica mostly falling between \(-3\) and 3 cm/year, and matching the ICESat result to 0.94 cm/year. The ENVISAT result will provide a constraint on the current mass balance result along the Chinese expedition route CHINARE.     

Generation of hazard-consistent ground motion

This paper presents an integrated approach for evaluating seismic hazard and establishing ground motion at a site. In this approach, we combine the advantage of probabilistic and deterministic seismic hazard analyses and generate synthetic ground motion by considering the characteristics of seismic source, path attenuation, and local soil condition. Furthermore, uncertainties in seismic and soil parameters are taken into account. The proposed approach can be used to establish site-specific ground motion for engineering applications.     

Chandra observations of Tycho’s supernova remnant

We present a newChandra observation of Tycho’s supernova remnant with the Advanced CCD Imaging Spectrometer. Multicolor Xray imaging reveals new details of the outer shock and ejecta. At energies between 4 and 6 keV, the outline of the outer shock is clearly revealed in X-rays for the first time. The distribution of the emission from lines of Si and Fe are confirmed to have a different morphology from each other, and the Si ejecta are shown to extend to the blast shock at several locations. Characteristic spectra of the outer shock and ejecta are also presented.     

Mortality and Physiological Responses with Regard to the Surf Clam,Mactra quadrangularis,Exposed to Chlorine

Ocean Science Journal - Carcinogenic disinfection by-products (DBPs) are formed as the result of the chlorination of power plant water cooling systems for biofouling purposes. Effects of cooling...     

Comparison of metal accumulation in the azooxanthellate scleractinian coral (Tubastraea coccinea) from different polluted environments

The response of metal accumulation in coral Tubastraea coccinea to various degrees of metal enrichment was investigated from the Yin-Yang Sea (YYS) receiving abandoned mining effluents, the Kueishan Islet (KI) hydrothermal vent field, and the nearshore area of remoted Green Island (GI). The concentrations of most dissolved metals were highest in seawater at YYS, followed by KI, and then GI, showing the effects of anthropogenic and venting inputs on metal levels. Five metals (Co, Fe, Mn, Ni, and Zn) yielded significant differences (p < 0.05) among the skeleton samples. We identified similar patterns in the metal–Ca ratios, indicating that the elevated metals in skeletons was a consequence of external inputs. The coral tissues were relatively sensitive in monitoring metal accumulation, showing significant differences among three locations for Cd, Co, Cu, Fe, Pb, Ni, and Zn. Specific bioconcentration factors provided strong support for the differential metal accumulation in skeletons and tissues.     

Characterization and identification of na-cl sources in ground water

Elevated concentrations of sodium (Na+) and chloride (Cl-) in surface and ground water are common in the United States and other countries, and can serve as indicators of, or may constitute, a water quality problem. We have characterized the most prevalent natural and anthropogenic sources of Na+ and Cl- in ground water, primarily in Illinois, and explored techniques that could be used to identify their source. We considered seven potential sources that included agricultural chemicals, septic effluent, animal waste, municipal landfill leachate, sea water, basin brines, and road deicers. The halides Cl-, bromide (Br), and iodide (I) were useful indicators of the sources of Na+-Cl- contamination. Iodide enrichment (relative to Cl-) was greatest in precipitation, followed by uncontaminated soil water and ground water, and landfill leachate. The mass ratios of the halides among themselves, with total nitrogen (N), and with Na+ provided diagnostic methods for graphically distinguishing among sources of Na+ and Cl- in contaminated water. Cl/Br ratios relative to Cl- revealed a clear, although overlapping, separation of sample groups. Samples of landfill leachate and ground water known to be contaminated by leachate were enriched in I and Br; this provided an excellent fingerprint for identifying leachate contamination. In addition, total N, when plotted against Cl/Br ratios, successfully separated water contaminated by road salt from water contaminated by other sources.