越南东北部Cat Ba岛泥盆系-石炭系过渡层的初探

The Pho Han Formation is exposed on southern Cat Ba Island, Hai Phong Province in northeastern Vietnam, and intercalates the Devonian and Carbonif-erous (D-C) boundary (Ta and Doan, 2007; Komatsu et al., 2012). The D-C boundary section consists mainly of limestone beds, numbered from 1 to 167, interca-lated with alternating black organic-rich shales. The limestone yields abundant brachiopods, crinoid-stems and conodonts. Preliminary investigations on strati-graphy (conodont biostratigraphy and δ13C) and sedi-mentology of beds 113-133 were undertaken in this study.     

Geoblocks Recognition and Delineation of the Earthquake Prone Areas in the Tuan Giao Area (Northwest Vietnam)

The goal of the paper is to reveal the hierarchical block structure in the Tuan Giao area (Northwest Vietnam) and, on that base, to identify areas prone to earthquakes with M ≥ 5. Four large geoblocks of the second rank have been delineated on the basis of the joint analysis of geological, geophysical, geomorphic, and remote sensing data. The second rank geoblocks have been divided into smaller sub-blocks of the third rank. The recent geodynamics of the geoblocks have been characterized using geomorphic, seismological, gravity, and GPS data.The system of the delineated geoblocks is viewed as the Geodynamic Blocks model. The areas prone to earthquakes with M ≥ 5 have been identified using the pattern recognition algorithm CORA-3. The objects of the recognition were defined as circular areas, where boundaries of the geoblocks intersect each other. The recognition results confirm high seismic potential of the study region and provide information on potential earthquake sources for seismic hazard assessment: a number of boundary intersections have been identified as areas prone to earthquakes with M ≥ 5, where events of such magnitude have not been recorded up to date. Mordern geothermal activity and anomalies of dissolved methane (up to 10000 nL/L), helium and hydrogen in the hot mineral water springs prove high permeability of the study area and its active seismo-tectonic state.     

Relationships between persistent organic pollutants and carbonaceous materials in aquatic sediments of Taiwan

Recent studies have shown that many persistent organic pollutants (POPs, e.g., polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs) and various pesticides), are strongly associated with carbonaceous materials (including organic carbon (OC) and black carbon (BC)). We hypothesize that carbonaceous materials can be used as a first-order pollution index, to indicate areas where POP pollution may require further investigation. We tested our hypothesis and found that strong, positive correlations between BC and OC contents versus the concentrations of PCBs (and PAHs) existed in estuarine sediments of the Danshui River in 2005 and 2008. Thus, our preliminary results demonstrate that POC and BC are potential indicators of the POP pollution potential in fluvial sediments of the Danshui River in Taiwan. This innovative approach can provide a simple, relatively inexpensive and expedient means to monitor concentrations of POPs in polluted aquatic sediments of Taiwan, and/or those having a legacy of POP inputs.     

Speciation of dissolved selenium in the Kaoping and Erhjen rivers and estuaries,southwestern Taiwan

Analytical methods of dissolved Se species in river water and seawater were established and applied to study dissolved Se speciation in the Kaoping and Erhjen rivers and estuaries, southwestern Taiwan. The Kaoping and Erhjen rivers and estuaries were respectively in relatively oxygenated and oxygen-deficient conditions as revealed from the distributions of dissolved oxygen, DOC, nutrients, and dissolved Mn. Concentrations of dissolved total Se increased downstream in the riverine sections, ranging from 0.6 nM to 1.2 nM for the Kaoping River and from 0.8 nM to 1.05 nM for the Erhjen River. The dissolved total Se was only slightly higher in the Erhjen middle estuary than in the Kaoping middle estuary in spite of heavier pollution in the former. The dissolved total Se behaved rather conservatively in the Kaoping estuary but nonconservatively in the Erhjen estuary resulting from anthropogenic inputs, and in this respect showed similarities with the behavior of redox-sensitive Mn. The predominant species of selenium were Se(VI) and organic Se in the Kaoping River and Se(VI) in the Kaoping estuary. The elevated concentration of Se(VI) in the Kaoping estuary may stem from the degradation of organic Se and oxidation of Se(IV). On the other hand, Se(IV) and organic Se were equally dominant in the Erhjen River, and Se(IV) was predominant through most of the Erhjen estuary. The elevated distribution of Se(IV) in the Erhjen middle estuary may result mostly from partial decomposition of organic Se, but further oxidation of Se(IV) was inhibited in reducing waters. However, Se(VI) became dominant at Erhjen outer estuary where water was oxygenated by the replacement of intruded coastal seawater. Apparently, the speciation of dissolved Se was mainly controlled by the biological and redox processes in the Kaoping and Erhjen rivers and estuaries.     

Dynamic response of cylindrical shell structures subjected to underwater explosion

This study investigated the linear and nonlinear dynamic responses of three cylindrical shell structures subjected to underwater small charge explosions in a 4 m×4 m×4 m water tank. The dimensions of the cylindrical shell structures were 90 cm×30 cm×1 mm (length×diameter×thickness). Both ends of the cylindrical shell were mounted with thick plates to provide support and create an enclosed space. The three cylindrical shell structures were un-stiffened, internally stiffened and externally stiffened, respectively. The experiments involving the dynamic response of cylinders subjected to underwater explosion (UNDEX) were performed under different standoff distances, varying from 210 to 35 cm. A small quantity of explosives was used to generate the shock loading. The plastic deformation of the cylindrical shell was observed at a standoff distance of less than 50 cm. Other conditions were tested to examine cylinder linear response. Dynamic analyses were performed for the experimental model using FEM and compared with the test results. The accelerations and dynamic strains of cylindrical shells obtained from the experiment were compared with those obtained by FE analysis. Finally, problems related to small-scale UNDEX experiments performed in small water tanks were analyzed.     

Controls of 234Th removal from the oligotrophic ocean by polyuronic acids and modification by microbial activity

To gain new insights into the variability of particulate organic carbon (POC) fluxes and to better understand the factors controlling the POC/²³⁴Th ratios in suspended and sinking particulate matter, we investigated the relationships between POC/²³⁴Th ratios and biochemical composition (uronic acids, URA; total carbohydrates, TCHO; acid polysaccharides, APS; and POC) of suspended and sinking matter from the Gulf of Mexico in 2005 and 2006. Our data show that URA/POC in sediment traps (STs), APS/POC in the suspended particles, and turnover times of particulate ²³⁴Th in the water column and those of bacteria in STs inside eddies usually increased with depth, whereas particulate POC/²³⁴Th (10–50 μm) and the sediment-trap parameters (POC flux, POC/²³⁴Th ratio, bacterial biomass, and bacterial production) decreased with depth. However, this trend was not the case for most biological parameters (e.g., phytoplankton and bacterial biomass) or for the other parameters at the edges of eddies or at coastal-upwelling sites.In general, the following relationships were observed: 1) ²³⁴Th/POC ratios in STs were correlated with APS flux, and these ratios in the 10–50 μm suspended particles also correlated with URA/POC ratios; 2) neither URA fluxes nor URA/POC ratios were significantly related to bacterial biomass; 3) the sum of two uronic acids (G2, glucuronic, and galacturonic acid, which composed most of the URA pool) was positively related to bacterial biomass; and 4) the POC/²³⁴Th ratios in intermediate-sized particles (10–50 μm) were close to those in sinking particles but much lower than those in > 50 μm particles. The results indicate that acid polysaccharides, though a minor fraction (~ 1%) of the organic carbon, act more likely as proxy compound classes that might contain the more refractory ²³⁴Th-binding biopolymer, rather than acting as the original ²³⁴Th “scavenger” compound. Moreover, these acid polysaccharides, which might first be produced by phytoplankton and then modified by bacteria, also influence the on-and-off “piggy-back” processes of organic matter and ²³⁴Th, thus causing additional variability of the POC/²³⁴Th in particles of different sizes.     

海冰动力学的混合拉格朗日-欧拉数值方法

综合考虑欧拉坐标下有限差分法(FDM)在海冰动力学计算中的效率,以及拉格朗日坐标下光滑质点流体动力学方法(SPH)对海冰流变行为的精确模拟,本文发展了一种海冰动力学的混合拉格朗日-欧拉(HLE)数值方法。该方法首先在拉格朗日坐标下将海冰离散为若干个具有厚度、密集度的海冰质点,并由这些海冰质点通过Gauss函数对欧拉网格上的海冰参量进行积分插值;然后,在欧拉坐标下对海冰动量方程进行差分计算以确定各网格节点的海冰速度,并由此采用Gauss函数积分插值出拉格朗日坐标下各海冰质点的速度分布;最后,通过对海冰质点运动和分布的计算,确定出各海冰质点的位置、厚度和密集度等参量。采用该HLE方法对规则区域内的海冰堆积过程和涡动风场作用下的海冰动力演化趋势进行了数值试验;最后,采用该HLE方法对渤海海冰的动力过程进行了72h数值模拟,其计算结果与卫星遥感图像和现场观测资料吻合较好。以上计算结果均表明该HLE方法在海冰动力学数值模拟中具有较高的计算效率和模拟精度,可用于海冰动力过程的数值模拟。     

Distributions of carbohydrate species in the Gulf of Mexico

In order to study the role of polysaccharides in the cycling of marine organic matter and transparent exopolymeric particles (TEP), the concentrations of total carbohydrates (p-TCHO), total uronic acids (URA) and total acid polysaccharides (APS) in suspended and sinking particles, as well as carbohydrates in the filter-passing “dissolved” phase (d-TCHO), were measured in vertical profiles along a N–S transect in the Gulf of Mexico, across a cold core (CCR) and a warm core (WCR) ring (eddy) during both July 2000 and May 2001. The concentrations of d-TCHO in 2000 ranged from 4 to 22 μM C, with a subsurface maximum, which was located slightly above the depth of chl a maximum, amounting to, on average, 34% of DOC in the CCR, and 13% in the WCR. The concentration of particulate carbohydrates (p-TCHO) in different size fractions (0.7–10, 10–53, and >53 μm) ranged from 0.04 to 1.1, 0.005 to 0.40, and 0.006 to 0.26 μM C, respectively, indicating that carbohydrates are mostly concentrated in small particles (0.7–10 μm). URA and APS were similarly concentrated in small particles, in which, on average, URA accounted for 87% and 57% of total URA, and APS for 92% and 88% of total APS in 2000 and 2001, respectively. URA accounted for 3–9% of carbohydrates in suspended particles, suggesting that URA are a minor component of the p-TCHO pool. Due to its surface-reactive nature, URA could play a major role in the coagulation of particles and macromolecules despite its relatively low abundance. While, on average, p-TCHO and total APS were more enriched in suspended particles than in sinking particles in both 2000 and 2001, the opposite was true for URA in both years. The greater contents of URA that are present in settling particles compared to suspended particles could indicate a mass flow in the direction of sinking particles, either caused by coagulation, by bacterial reworking of particulate and colloidal organic matter, or by their more refractory nature.