Thermal expansion of fayalite,Fe2SiO4

Thermal expansion of single-crystal fayalite has been measured by a dilatometric method at temperatures between 25 °C and 850 °C. The results show the presence of anomalous expansion in the b axis, which is correlated to the anomalous variation of elastic moduli with temperature. Grüneisen's parameter is 1.10 and the thermal Debye temperature is 565 K, which is close to the acoustic Debye temperature of 511 K.     

Single crystal X-ray and Mössbauer study of shocked ilmenite to 80 GPa

Shock loading experiments on single crystal ilmenite (FeTiO₃) are carried out up to peak pressures of 80 GPa using a newly built two-stage light gas gun. Shock effects are investigated by means of X-ray precission technique and Mössbauer spectroscopy. Shock effects are largely controlled by the anisotropic nature of the ilmenite structure. Considerable deformations are observed even in a pressure level of 30 GPa in the shocked crystal when the shock propagation direction is parallel to the c axis, whereas little effects are seen up to 55 GPa when the crystal is shocked parallel to the c plane (cleavage plane). The greatest deformation is introduced in the planes containing the c axis, while less remarkable effects are seen in the plane perpendicular to the c axis. Residual effects are favorably compared with the compression anomalies found in the Hugoniot measurements by King and Ahrens (1976). Mössbauer measurements also reveal that a fraction of highly disturbed regions increases with increasing shock loading pressure. These observations are explained in terms of current heterogeneous yielding model of brittle substances under shock loading, where internal fragmentation is preferentially formed so as to give c-platelet domains that are mutually misoriented with each other.     

Distribution of some trivalent ions between melt and single crystals of Mg2SiO4 grown by the Czochralski method

Partition coefficients for trace amounts of trivalent ions between artificial single crystals of Mg₂SiO₄ grown by the Czochralski method and the coexisting melt have been determined by neutron activation analysis. They are found to vary greatly with the amount of visible imperfections in the crystal and slightly with the concentration of the ions in the melt. Plots of the partition coefficients against ionic radius of the trace ions give a pattern which agrees qualitatively with that found in a natural olivine phenocryst-groundmass pair.     

Spectroscopic properties of Cr-doped melilite crystals

 Four kinds of Cr-droped melilite crystals, Ca₂MgSi₂O₇ (akermanite), CaAl₂SiO₇ (gehlenite), CaGa₂SiO₇ (Ga-gehlenite) and CaGa₂GeO₇ (GaGe-gehlenite), with different sizes of the sites for Cr ions to substitute, were grown in series, using both the CZ and FZ techniques. Although Cr⁴⁺ is regarded as a major species in melilites, the existence of Cr⁶⁺ in gehlenite is also suggested from the change in absorption spectra by annealing, and the dependence of distribution coefficient of Cr ions on growth atmosphere. Spectral peak shifts are not obvious if the host crystal field is altered in melilites, because the local environment of the sites for Cr ion is possibly changed by reforming the packing features of the host lattice. Received February 7, 1996 / Revised, accepted September 20, 1996