Urban Dispersion Modelling and Experiments in the Daytime and Nighttime Atmosphere

An analytical model of atmospheric dispersion in urban areas in both daytime and nighttime conditions is presented. The model is based on a Gaussian formulation where the horizontal and vertical diffusion coefficients are determined according to analytical theories. The model is validated with dispersion measurements from field experiments conducted in Oklahoma City, Salt Lake City, St. Louis and London, U.K. The theory is in good agreement with the data for both daytime and nighttime conditions. The data support the conclusion that the magnitude of the nighttime stratification in the urban atmosphere is weak; however, its effects on dispersion are not negligible. The predicted existence of two distinct dispersion regimes, in the near and in the far field, is also confirmed by the data. The good collapse of the data suggests that urban dispersion is governed by the characteristic length scales of atmospheric boundary-layer turbulence, rather than urban canopy length scales that are more likely to affect dispersion only in the vicinity of the source.     

Formation and alteration of plagiogranites in an ultramafic-hosted detachment fault at the Mid-Atlantic Ridge (ODP Leg 209)

We examined small-scale shear zones in drillcore samples of abyssal peridotites from the Mid-Atlantic Ridge. These shear zones are associated with veins consisting of chlorite + actinolite/tremolite assemblages, with accessory phases zircon and apatite, and they are interpreted as altered plagiogranite melt impregnations, which originate from hydrous partial melting of gabbroic intrusion in an oceanic detachment fault. Ti-in-zircon thermometry yields temperatures around 820°C for the crystallization of the evolved melt. Reaction path modeling indicates that the alteration assemblage includes serpentine of the adjacent altered peridotites. Based on the model results, we propose that formation of chlorite occurred at higher temperatures than serpentinization, thus leading to strain localization around former plagiogranites during alteration. The detachment fault represents a major pathway for fluids through the oceanic crust, as evidenced by extremely low δ¹⁸O of altered plagiogranite veins (+3.0–4.2‰) and adjacent serpentinites (+ 2.6–3.7‰). The uniform oxygen isotope data indicate that fluid flow in the detachment fault system affected veins and adjacent host serpentinites likewise. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Fragmentation during Rock Falls: Two Italian Case Studies of Hard and Soft Rocks

In recent years, rock fall phenomena in Italy have received considerable attention for risk mitigation through in situ observations and experimental data. This paper reports the study conducted at Camaldoli Hill, in the urban area of Naples, and at Monte Pellegrino, Palermo, Italy. The rocks involved are volcanic Neapolitan yellow tuff (NYT) in the former area and dolomitic limestone in the latter. Both rocks, even though with different strength characteristics, have shown a significant tendency towards rock fragmentation during run out. This behavior was first investigated by comparing the volumes of removable blocks on the cliff faces (V ₀) and fallen blocks on the slopes (V _f). It was assumed that the ratio V _f/V ₀ decreases with the distance (x _f) from the detachment area by an empirical law, which depends on a coefficient α, correlated with the geotechnical properties of the materials involved in the rock fall. Finally, this law was validated by observation of well-documented natural rock falls (Palermo) and by in situ full-scale tests (Naples). From the engineering perspective, consideration of fragmentation processes in rock fall modeling provides a means for designing low-cost mitigation measures.     

A review of jet grouting practice and development

The jet grouting technique was originally initiated in the UK and progressively developed following the needs for larger geometries, ease of implementation, economic rationality, and better mechanical properties. This paper presents a comprehensive review of the development and practice of jet grouting through some fundamental concepts and relevant case studies. Subsequently, a laboratory testing program is performed to investigate the factors affecting the efficacy of the twin grouting system. The principal objective of this study is to define the suitable conditions for the jet grouting efficacy regarding economic rationality as well as quality control. For the first phase, a particular emphasis is placed on the properties of jet columns, site geological conditions, implementation methods, and the justification of each selected treatment option, while the second phase mainly focuses on the unconfined compressive strength (UCS) tests. It follows that the mono-fluid jet grouting system presents a valuable flexibility in dealing with complex configurations; yet, the double- and triple-fluid systems are more indicated for cases of mass treatments for which large portions of space must be treated and overlapping is fundamentally important for the reliability of the treatment. Furthermore, it was established that the efficacy of the twin-jet method primarily relies on the proper adequacy of some critical parameters, namely, the cement content, the water-cement ratio, and cement slurry-water glass ratio. In spite of some uncertainties inherently related to the technique, the UCS test represents the quintessential laboratory index for evaluating the mechanical properties of grouted elements, deriving jet grouting efficacy and the economics of jet grouts.     

The governance and evolution of local production networks in a cluster: the case of Taiwan’s machine tool industry

The competitive advantages of spatially concentrated and networked production systems, in terms of flexibility and adaptivity, have been well documented. This paper contributes to this literature by improving our understanding regarding the underlying mechanisms behind the governance and evolution of such a production system. By using the case of Taiwan’s machine tool (MT) industry, this paper demonstrates how lead firms depend on their relational capabilities or relation-building skills, nurtured greatly by cluster embeddedness, to effectively govern their suppliers in the production networks. While the production systems constantly evolve, this paper also discusses the ongoing reconfiguration of Taiwan’s MT production networks stimulated by lead firms’ efforts to tackle the cluster’s emerging diseconomies so as to sustain their competitiveness. This paper concludes that a cure to deal with the cluster’s diseconomies would be the reinforcement of industrial clustering.     

Ab initio quantum mechanical study of γ-AlOOH boehmite: structure and vibrational spectrum

The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc2₁, P2₁/c. Cmcm turns out to correspond to a transition state, whereas Cmc2₁ and P2₁/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm⁻¹). For the Al-OH bending modes (800–1,300 cm⁻¹) an absolute differences of 50–100 cm⁻¹ is observed; for the OH stretching modes (3,200–3,500 cm⁻¹) it increases to 120–200 cm⁻¹: anharmonicity is large because OH groups are involved in strong hydrogen bonds.     

Biocalcification in the Eastern Oyster (<Emphasis Type="Italic">Crassostrea virginica)</Emphasis> in Relation to Long-term Trends in Chesapeake Bay pH

Anthropogenic carbon dioxide (CO₂) emissions reduce pH of marine waters due to the absorption of atmospheric CO₂ and formation of carbonic acid. Estuarine waters are more susceptible to acidification because they are subject to multiple acid sources and are less buffered than marine waters. Consequently, estuarine shell forming species may experience acidification sooner than marine species although the tolerance of estuarine calcifiers to pH changes is poorly understood. We analyzed 23 years of Chesapeake Bay water quality monitoring data and found that daytime average pH significantly decreased across polyhaline waters although pH has not significantly changed across mesohaline waters. In some tributaries that once supported large oyster populations, pH is increasing. Current average conditions within some tributaries however correspond to values that we found in laboratory studies to reduce oyster biocalcification rates or resulted in net shell dissolution. Calcification rates of juvenile eastern oysters, Crassostrea virginica, were measured in laboratory studies in a three-way factorial design with 3 pH levels, two salinities, and two temperatures. Biocalcification declined significantly with a reduction of ∼0.5 pH units and higher temperature and salinity mitigated the decrease in biocalcification.     

Hydrochemical and Multivariate Statistical Evaluation of Heavy Metals in Shallow Alluvial Aquifers of North Brahmaputra Plain,India

The aim of this study was to display distribution and relationships of heavy elements in the unconfined, shallow alluvial aquifers of the lower Jia Bharali catchment and adjoining areas in central part of North Brahmaputra Plain (NBP), India using hydrochemical as well as multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis. The original matrix was made up of 10 trace elements (As, Cd, Cu, Co, Cr, Fe, Mn, Pb, Ni and Zn) estimated from 50 shallow alluvial dug wells in both the wet and the dry season for a duration of 3 hydrological years (2008–2011). Except As, Cu and Zn all the other toxic metals in the shallow aquifers were found exceeding the WHO maximum permissible limits for drinking water. PCA extracted five varimax factors as geogenic, agricultural and anthropogenic explaining about 71.2% of the total variance in the wet season and 69.3% total variance in the dry season. Hierarchical cluster analysis classified the dug wells into two groups in the wet season and three groups in the dry season with respect to the heavy elements. The results emphasized the need for routine monitoring and management in order to avoid contamination of groundwater sources in the NBP with respect to the dissolved trace elements.     

Site Specific Ground Motion Modeling and Seismic Response Analysis for Microzonation of Baku,Azerbaijan

We investigated ground response for Baku (Azerbaijan) from two earthquakes of magnitude M6.3 occurred in Caspian Sea (characterized as a near event) and M7.5 in Shamakhi (characterized as a remote extreme event). S-wave velocity with the average shear wave velocity over the topmost 30 m of soil is obtained by experimental method from the V _P values measured for the soils. The downtown part of Baku city is characterized by low V_S30 values (< 250 m/s), related to sand, water-saturated sand, gravel-pebble, and limestone with clay. High surface PGA of 240 gal for the M7.5 event and of about 190 gal for the M6.3 event, and hence a high ground motion amplification, is observed in the shoreline area, through downtown, in the north-west, and in the east parts of Baku city with soft clays, loamy sands, gravel, sediments.