Calcic amphiboles in calc-alkaline and alkaline magmas: thermobarometric and chemometric empirical equations valid up to 1,130°C and 2.2 GPa

The following article presents constraints of the stability of Mg-rich (Mg/(Mg + Fe²⁺) > 0.5) calcic amphibole in both calc-alkaline and alkaline magmas, testing of previous thermobarometers, and formulation of new empirical equations that take into consideration a large amount of literature data (e.g. more than one thousand amphibole compositions among experimental and natural crystals). Particular care has been taken in choosing a large number of natural amphiboles and selecting quality experimental data from literature. The final database of experimental data, composed of 61 amphiboles synthesized in the ranges of 800–1,130°C and 130–2,200 MPa, indicates that amphibole crystallization occurs in a horn-like P–T stability field limited by two increasing curves (i.e. the thermal stability and an upper limit), which should start to bend back to higher pressures. Among calcic amphiboles, magnesiohornblendes and tschermakitic pargasites are only found in equilibrium with calc-alkaline melts and crystallize at relatively shallow conditions (P up to ~1 GPa). Kaersutite and pargasite are species almost exclusively found in alkaline igneous products, while magnesiohastingsite is equally distributed in calc-alkaline and alkaline rocks. The reliability of previous amphibole applications was checked using the selected experimental database. The results of this testing indicate that none of the previous thermobarometers can be successfully used to estimate the P, T and fO₂ in a wide range of amphibole crystallization conditions. Multivariate least-square analyses of experimental amphibole compositions and physico-chemical parameters allowed us to achieve a new thermobarometric model that gives reasonably low uncertainties (T ± 23.5°C, P ± 11.5%, H₂O_melt ± 0.78wt%) for calc-alkaline and alkaline magmas in a wide range of P–T conditions (up to 1,130°C and 2,200 MPa) and ∆NNO values (±0.37 log units) up to 500 MPa. The ^AK-^[4]Al relation in amphibole can be readily used to distinguish crystals of calc-alkaline liquids from those of alkaline magmas. In addition, several chemometric equations allowing to estimate the anhydrous composition of the melts in equilibrium with amphiboles of calc-alkaline magmas were derived.     

量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。     

长春市旅游产品开发研究

搞好长春市旅游产品的开发与设计对其旅游业的发展极为重要，长春市旅游资源类型多样，内容丰富，主要有生态旅游资源，电影文化旅游资源，产业旅游资源，殖民遗迹旅游资源，辽金文化旅游资源等五大资源优势。文章在分析这些资源优势的基础上，结合长春市国内外旅游客源市场的背景与现状，提出了旅游产品开发的具体思路，即在今后的开发中应突出地方特色。增强参与性，以七大旅游产品系列为依托，重点开发冰雪旅游，生态旅游，文化旅游和产业旅游。     

青藏高原东部表层土壤色度的空间变化特征及其环境意义

认识青藏高原东部现代表土的色度特征及其空间分布,理解其与现代气候因子之间的联系,对于高原地区黄土-古环境重建和揭示第四纪环境变化历史具有重要意义。通过对研究区表层土壤色度的详细分析,对比现代气候资料,探讨了青藏高原东部表层土壤色度的空间变化特征及其环境意义。结果表明：① 高原东部表土色度参数空间变化特征差异显著,表现为随纬度升高,土壤亮度呈先减小后增大的趋势,而红度和黄度则逐步减小;随经度的升高,黄度先增大后减小,而红度值逐步减小;红度和黄度整体随着海拔上升而呈先减小后升高的特征。这些变化特征和差异是表土色度对高原东部复杂地理环境和水热条件变化响应的结果。② 在高原的干旱-半湿润区,土壤亮度对降水的响应敏感;红度和黄度对大尺度的温度变化响应较敏感,而较冷的环境下,红度对温度响应复杂,但与降水存在一定的联系。红度/黄度比值主要指示了气候控制下的赤铁矿和针铁矿的变化和竞争,对干旱-半湿润区域的降水变化响应较为敏感。青藏高原东部现代表土色度与气候密切相关,其空间变化特征一定程度上反映了该地区现代气候因子的空间变化;另一方面由于该区地形和气候复杂多变,部分色度指标与气候关系复杂,在重建青藏高原东部黄土古环境变化历史时需要谨慎。     

1961-2005年华东地区高温气候特征

Based on the daily maximum temperature data covering the period 1961-2005, temporal and spatial characteristics and their changing in mean annual and monthly high temperature days (HTDs) and the mean daily maximum temperature (MDMT) during annual and monthly HTDs in East China were studied. The results show that the mean annual HTDs were 15.1 and the MDMT during annual HTDs was 36.3℃ in the past 45 years. Both the mean annual HTDs and the MDMT during annual HTDs were negative anomaly in the1980s and positive anomaly in the other periods of time, oscillating with a cycle of about 12-15 years. The mean annual HTDs were more in the southern part, but less in the northern part of East China. The MDMT during annual HTDs was higher in Zhejiang, Anhui and Jiangxi provinces in the central and western parts of East China. The high temperature process (HTP) was more in the southwestern part, but less in northeastern part of East China. Both the HTDs and the numbers of HTP were at most in July, and the MDMT during monthly HTDs was also the highest in July. In the first 5 years of the 21st century, the mean annual HTDs and the MDMT during annual HTDs increased at most of the stations, both the mean monthly HTDs and the MDMT during monthly HTDs were positive anomalies from April to October, the number of each type of HTP generally was at most and the MDMT in each type of HTP was also the highest.     

南极长城站海雾特征分析

本文根据对海雾气象要素场、大气层结和天气形势的分析及其持续时间和季节、年际变化的统计分析,结合个例,讨论了南极长城站海雾的特征和形成机制。认为长城站海雾大多为平流冷却雾,高频率的偏北风和南大洋极锋附近显著的经向海温梯度是长城站多海雾的根本原因;夏半年海雾要多于冬半年,海雾的年际分布差异明显;海雾可出现于0-17m/s的各级风力中,3-11m/s偏北风最有利于海雾的维持;气温为-2-4℃、气-海温差为0-2℃时最易出现海雾;海雾的发生一般伴有稳定的大气层结;"东高西低"是长城站海雾的主要天气形势;海雾的持续时间取决于高压在南极半岛维持时间的长短,平均有10个小时。     

塔克拉玛干沙漠腹地大气气溶胶散射特征研究

利用沙漠腹地塔中气象站积分浊度计的2004年观测资料,结合同期PM10质量浓度、能见度和常规气象资料,分析了塔克拉玛干沙漠腹地气溶胶散射系数的变化特征,以及气溶胶散射系数与PM10质量浓度、能见度的关系。研究表明,2004年塔中气溶胶散射系数、PM10质量浓度、能见度日平均值分别为124.74±187.30 Mm-1,538.9±841.7 μg·m-3,12 748±7 274 m。塔中气溶胶散射系数小时平均值出现频率最高的区间主要在100 Mm-1以下,中午气溶胶散射系数小,早晚气溶胶散射系数大;冬春两季的凌晨空气中含有较多的粒子,气溶胶散射系数较大;气溶胶散射系数小时平均值与PM10质量浓度变化规律基本一致,2004年1—6月的气溶胶质量散射系数平均值为0.37 m2·g-1;散射系数与能见度日平均值非线性相关较好,两者呈负幂函数关系。     

上天梯膨润土在钻井泥浆中的应用研究

信阳上天梯矿区钙基膨润土可分为四个自然类型。根据矿石理化性能和蒙脱石晶体结构特征，选用第Ⅲ类矿石，运用对辊挤压钠化法和最佳工艺进行实验研究，获得钻井泥浆用Ａ．Ｐ．Ｉ级膨润土。     

基于GML/SVG的WebGIS体系结构设计与实现

随着Internet的飞速发展,WebGIS也进入了蓬勃发展的阶段,而制约WebGIS发展的问题也日益突出。本文针对WebGIS中存在的地理空间数据语义共享和网络带宽日益紧张的问题,引入了GML和SVG,在此基础上提出并论证的基于GML和SVG的WebGIS系统的方案和应用模式,并详析了实现该系统的体系结构和相关技术,最后给出了该系统的应用实例。     

Periodic Behavior and Stochastic Fluctuations of Solar Activity: Proper Orthogonal Decomposition Analysis

We use the Proper Orthogonal Decomposition (POD) to investigate the spatiotemporal features of the solar activity. Daily observation in the period 1949–1996 of the green coronal emission line at 530.3 nm are used as indicators of the activity behavior. We show that few POD modes suffice in describing both the space and time main periodicities. In particular, being affected by a strongly energetic stochastic behavior, daily data are described by five POD modes, while two POD modes are enough to describe the butterfly diagram in monthly averaged data. Apart from the basic period T₀ = 11 years, using daily data we found evidences for intercycle temporal periodicities.