Marine Macrophyte Wrack Inputs and Dissolved Nutrients in Beach Sands

We investigated the role of sandy beaches in nearshore nutrient cycling by quantifying macrophyte wrack inputs and examining relationships between wrack accumulation and pore water nutrients during the summer dry season. Macrophyte inputs, primarily giant kelp Macrocystis pyrifera, exceeded 2.3 kg m⁻¹ day⁻¹. Mean wrack biomass varied 100-fold among beaches (range = 0.41 to 46.43 kg m⁻¹). Mean concentrations of dissolved inorganic nitrogen (DIN), primarily NO_x⁻-N, and dissolved organic nitrogen (DON) in intertidal pore water varied significantly among beaches (ranges = 1 to 6,553 μM and 7 to 2,006 μM, respectively). Intertidal DIN and DON concentrations were significantly correlated with wrack biomass. Surf zone concentrations of DIN were also strongly correlated with wrack biomass and with intertidal DIN, suggesting export of nutrients from re-mineralized wrack. Our results suggest beach ecosystems can process and re-mineralize substantial organic inputs and accumulate dissolved nutrients, which are subsequently available to nearshore waters and primary producers.     

Importance of predecessor basin history on sedimentary fill of a retroarc foreland basin: provenance analysis of the Cretaceous Magallanes basin,Chile (50–52°S)

An integrated provenance analysis of the Upper Cretaceous Magallanes retroarc foreland basin of southern Chile (50°30′–52°S) provides new constraints on source area evolution, regional patterns of sediment dispersal and depositional age. Over 450 new single‐grain detrital‐zircon U‐Pb ages, which are integrated with sandstone petrographic and mudstone geochemical data, provide a comprehensive detrital record of the northern Magallanes foreland basin‐filling succession (>4000‐m‐thick). Prominent peaks in detrital‐zircon age distribution among the Punta Barrosa, Cerro Toro, Tres Pasos and Dorotea Formations indicate that the incorporation and exhumation of Upper Jurassic igneous rocks (ca. 147–155 Ma) into the Andean fold‐thrust belt was established in the Santonian (ca. 85 Ma) and was a significant source of detritus to the basin by the Maastrichtian (ca. 70 Ma). Sandstone compositional trends indicate an increase in volcanic and volcaniclastic grains upward through the basin fill corroborating the interpretation of an unroofing sequence. Detrital‐zircon ages indicate that the Magallanes foredeep received young arc‐derived detritus throughout its ca. 20 m.y. filling history, constraining the timing of basin‐filling phases previously based only on biostratigraphy. Additionally, spatial patterns of detrital‐zircon ages in the Tres Pasos and Dorotea Formations support interpretations that they are genetically linked depositional systems, thus demonstrating the utility of provenance indicators for evaluating stratigraphic relationships of diachronous lithostratigraphic units. This integrated provenance dataset highlights how the sedimentary fill of the Magallanes basin is unique among other retroarc foreland basins and from the well‐studied Andean foreland basins farther north, which is attributed to nature of the predecessor rift and backarc basin.     

The Verification and Significance of Three Approaches to Longitudinal Stresses in High–resolution Models of Glacier Flow

With the purpose of improving the ice physics underpinning time–dependent glacier flowline models, three independent approaches for solving longitudinal stresses in glaciers are discussed and verified by application to Haut Glacier d'Arolla. To highlight any shortcomings, the reduced and much utilised driving stress approximation is also applied and compared. Modelled velocity patterns using the three full stress schemes exhibit consistency with one another and good coincidence with observed velocities for the 1991 summer melt season. Furthermore, these stress patterns indicate that longitudinal stresses are significant and of a similar order of magnitude as the basal shear stress components. However, the driving stress approximation yields erratic fluctuations in the stress and velocity fields which are neither realistic in terms of mass continuity nor agree with observations. Basal decoupling experiments indicate a complex relationship between basal velocity and englacial stresses with considerable dampening of any basal perturbation occurring as it is dissipated towards the surface and transferred throughout the ice mass. The driving stress approximation fails to account at all for any such coupling. Experiments to identify the length scale over which longitudinal effects operate indicate that they are significant even up to 10 ice thicknesses. The implication here is that longitudinal stresses play a significant role in determining glacier dynamics on length scales up to at least 2 km and that the predictive power of models of glacier flow based purely on the driving stress approximation is therefore subject to significant limitations. Inclusion of longitudinal stresses overcomes one of the main limitations imposed on such models and, given the potential ease of incorporation of the schemes described here, this deficiency may readily be resolved.     

Surface complexation of U(VI) on goethite (α-FeOOH)

Sorption of U(VI) to goethite is a fundamental control on the mobility of uranium in soil and groundwater. Here, we investigated the sorption of U on goethite using EXAFS spectroscopy, batch sorption experiments and DFT calculations of the energetics and structures of possible surface complexes. Based on EXAFS spectra, it has previously been proposed that U(VI), as the uranyl cation , sorbs to Fe oxide hydroxide phases by forming a bidentate edge-sharing (E2) surface complex, >Fe(OH)₂UO₂(H₂O)_n. Here, we argue that this complex alone cannot account for the sorption capacity of goethite (α-FeOOH). Moreover, we show that all of the EXAFS signal attributed to the E2 complex can be accounted for by multiple scattering. We propose that the dominant surface complex in CO₂-free systems is a bidentate corner-sharing (C2) complex, (>FeOH)₂UO₂(H₂O)₃ which can form on the dominant {101} surface. However, in the presence of CO₂, we find an enhancement of UO₂ sorption at low pH and attribute this to a (>FeO)CO₂UO₂ ternary complex. With increasing pH, U(VI) desorbs by the formation of aqueous carbonate and hydroxyl complexes. However, this desorption is preceded by the formation of a second ternary surface complex (>FeOH)₂UO₂CO₃. The three proposed surface complexes, (>FeOH)₂UO₂(H₂O)₃, >FeOCO₂UO₂, and (>FeOH)₂UO₂CO₃ are consistent with EXAFS spectra. Using these complexes, we developed a surface complexation model for U on goethite with a 1-pK model for surface protonation, an extended Stern model for surface electrostatics and inclusion of all known UO₂-OH-CO₃ aqueous complexes in the current thermodynamic database. The model gives an excellent fit to our sorption experiments done in both ambient and reduced CO₂ environments at surface loadings of 0.02-2.0 wt% U.     

The Jovian surface condition and cooling rate

A theory which is almost fully analytic is used to investigate Jupiter's cooling rate. We find that a simple model of contraction with adiabatic interior structure gives a total cooling time to the present which is in good agreement with the age of the solar system. The interplay between the surface condition and the cooling rate is exhibited and discussed. The current rate of change of the effective temperature is calculated to be ?1°K/0.145×10⁹ yr. Discrepancies with fully numerical investigations of the Jovian age and cooling rate are noted.