70年来中国化学海洋学研究的主要进展

我国的海洋化学工作者通过70年来,特别是近30年来的化学海洋学研究,实现了我国与世界先进水平进入同步发展的快车道,其显著的特点是:(1)化学海洋学研究从元素地球化学分布系统转向了以揭示深层次海洋生物地球化学过程为核心的研究;(2)化学海洋学研究实现了多领域、多视点的综合交叉研究;(3)更加关注了人为影响与自然变化共同作用下的海洋生态环境变化研究,对近海和海岸带而言,更加注重从海陆统筹一体化角度探析化学物质的分布迁移特征。本文从生源要素的海洋生物地球化学过程、微/痕量元素与同位素的海洋化学研究、生物过程作用下的化学海洋学过程等角度,重点总结归纳和分析了30年来我国海洋化学研究的重要进展和发展状况,以期对化学海洋学的进一步研究提供借鉴和启迪。     

底栖有孔虫(Florilus decors)壳体微量元素/钙比值的LA-ICP-MS原位微区分析方法及应用——以长江口外海域为例

深海沉积物中有孔虫壳体的微量元素、同位素测试技术已较为成熟,而河口近海沉积物中有孔虫壳体元素微区测试却鲜有报道。本文报道了一种利用激光剥蚀电感耦合等离子体质谱（LA-ICP-MS）分析法测试取自长江口外沉积物中的有孔虫壳体元素/钙比值的技术,研究了氦气载气流量、能量密度、束斑大小、激光剥蚀频率等参数对测试结果的影响,优化了活体有孔虫原位分析方法。应用确定的测试条件对2016年7月取自长江口外的底栖有孔虫优美花朵虫样品（Florilus decors）进行测试,发现Mg、Sr等元素/钙比值在壳体不同位置上无显著差异,而Mn的数据较为离散,可能与有孔虫生长过程中经历的水环境及其变化有关。     

Global Statistical Assessment and Cross-Calibration with Jason-2 for Reprocessed HY-2 A Altimeter Data

HY-2 A (Haiyang-2 A) satellite was launched on August 16, 2011 and radar altimeter is one of its main payloads. We reprocessed two years of HY-2 A altimeter sensor geophysical dataset records (SGDR) data. This paper presents the main results in terms of reprocessed HY-2 A altimeter data quality: verification of data availability and validity, monitoring several relevant altimeter parameters, and assessment of the HY-2 A altimeter system performances. A cross-calibration analysis of reprocessed HY-2 A altimeter data with Jason-2 was conducted. The reprocessed HY-2 A altimeter data show good quality and have a low level of noise with respect to Jason-2. The same geophysical correction methods were used to calculate the sea surface height (SSH) for the two missions. The mean standard deviations of the crossover differences for HY-2 A and Jason-2 are 5.24 cm and 5.34 cm, respectively. The mean standard deviation of the crossover differences between HY-2 A and Jason-2 is 5.37 cm. These show that HY-2 A can provide SSH measurements at almost the same level of accuracy as Jason-2. The relative SSH bias between HY-2 A and Jason-2 due to the Ultra Stable Oscillator (USO) drift is obviously observed, and it can affect the calculation of mean sea level and should be further studied and corrected.     

Instantaneous Shorelines as an Intermediate for Island Shoreline Mapping based on Aerial/Satellite Stereo Images

Island shoreline mapping based on field measurements by collecting visually discernible features is costly and even unrealistic to be implemented in practice because of the nonuniqueness, fuzziness, and ambiguity of shoreline features. The MHHW (the mean higher high water) shoreline, i.e., the intersection of the coastal profile with the MHHW, is recommended to be chosen as a significant shoreline indicator of an island. An approach for mapping the MHHW shoreline using the aerial/satellite stereo images is proposed. In the proposed procedure, first, the height difference between the instantaneous shoreline and the MHHW shoreline is calculated by the ocean tide model; then the orthometric/normal height of the instantaneous shoreline is determined from the stereo images; last, the instantaneous shoreline is used as an intermediate for determination of the height of the MHHW shoreline. The proposed procedure is applied to the MiaoZiHu Island located in the East China Sea. Preliminary experimental result shows that in ideal cases, the horizontal positional accuracy of the extracted shoreline can reach 0.2 m from aerial images of 0.1 m resolution.     

中国降水季节内振荡的气候特征分析

利用谐波分析、功率谱分析的方法,对全国730个站点自1951～2000年逐日降水资料进行气候平均分析,研究全国降水季节内振荡的分布特征.研究结果表明,中国大部分地区的降水主要以季节变化为主,而在长江中下游流域主要以季节内振荡为主.气候平均下降水的准双周振荡和Madden and Julian Oscillation(简称MJO)的振幅都在4月份开始加强,在11月份开始减弱,而MJO全年表现都很显著,准双周振荡主要在夏季显著;MJO主要分布在36°N以南的长江中下游地区,准双周振荡主要分布在115°E以西的内陆.     

6种鱼类肌肉组织肌苷酸的检测分析

采用高效液相色谱技术,在国内首次测定了条纹斑竹鲨(Chilocsyllium plagiosum)、大黄鱼(Pseudosci-aena crocea)、鳜(Siniperca chuatsi)、青石斑鱼(Epinephelus awoara)、牙鲆(Paralichthys olivaceus)和乌塘鳢(Bostrichthys sinensis)等6种鱼类新鲜和冻存肌肉组织中肌苷酸含量。结果表明:(1)不同鱼类肌肉组织中肌苷酸质量比不同,牙鲆新鲜肌肉组织中肌苷酸质量比最高,为4.214 mg/g,其余5种鱼类为2.365~3.634 mg/g。(2)10 d冻存试验中,经-70℃超低温冻存,6种鱼类冻存肌肉组织中肌苷酸质量比均高于新鲜肌肉组织,大黄鱼肌肉组织冻存1 d肌苷酸质量比达最大值,鳜肌肉组织冻存10 d肌苷酸质量比呈上升态势未出现最大值,其余5种鱼类肌肉组织肌苷酸质量比均在冻存第5天达到最大值。长时间的冻存将会降低食用鱼肉中肌苷酸质量比,导致鲜味下降,但经1周左右短时间的冻存后可明显提高鱼肉中肌苷酸质量比,增加鲜味,提高食用价值。     

中国沿海增减水的变化特征及与海平面变化的关系

本文通过对中国沿海25个观测站水位资料的分析,初步探讨了中国沿海1980-2012年增减水的变化特征及与海平面变化的关系。结果表明:（1）中国沿海增减水的季节变化特征明显,相邻站由于受到的气象状况相同,其沿海增减水变化的过程相近,但是变化幅度存在较大差异。从空间分布看,沿海增减水的变化幅度呈现中间大南北小的区域特征,自长江口至广东沿海,增减水的年变化幅度最大,年变幅平均为5.0~7.5 cm;南海周边及北部湾沿海,增减水的年变化幅度次之,年变幅平均为4.0~5.5 cm;自渤海至黄海沿海,增减水的年变化幅度较小,年变幅平均为3.3~3.5 cm。（2）从时间变化看,1980-2012年中国沿海年平均增减水长期基本没有趋势性变化,但明显存在2至5年的周期性变化信号,该信号的震荡幅度为0.1 cm。经过高频滤波后,对沿海月平均增减水序列与Niño3.4指数进行相关性分析,相关系数为-0.5,该相关系数通过了显著性检验,说明中国沿海的增减水变化与ENSO事件呈现负相关关系。（3）中国沿海增减水的长期变化及空间分布特征均与海平面变化不同。1980-2012年,中国沿海海平面的上升速率为2.9 mm/a,而增减水长期基本无趋势性变化;另外,其季节变化与海平面的季节变化从时间和区域上均不存在一致性。（4）但是,短期海平面的变化与增减水有关,并且增减水对短期海平面的贡献根据其具体情况而定,增水幅度大且持续时间长的过程对短期海平面有抬升作用,其贡献率最大可达65%;反之,减水幅度大且持续时间长的过程则对短期海平面有降低的作用。     

Explicit stress–strain equations for modeling frictional materials

In this paper, a comprehensive study on simulating the shearing behavior of frictional materials is performed. A set of two explicit equations, describing the relationship among the shear stress ratio and the distortional strain and the volumetric strain, are formulated independently. The equations contain three stress parameters and three strain parameters and another parameter representing the nonuniformity of stress and strain during softening. All the parameters have clear physical significance and can be determined experimentally. It is demonstrated that the proposed equations have the capacity of simulating the complicated shearing behavior of many types of frictional materials including geomaterials. The proposed equations are used to simulate the stress–strain behavior for 27 frictional materials with 98 tests. These materials include soft and stiff clays in both reconstituted and structured states, silicon sands and calcareous sands, silts, compacted fill materials, volcanic soils, decomposed granite soils, cemented soils (both artificially and naturally cemented), partially saturated soils, ballast, rocks, reinforced soils, tire chips, sugar, wheat, and rapeseed. It has been demonstrated that the proposed explicit constitutive equations have the capacity to capture accurately the shearing behavior of frictional materials both qualitatively and quantitatively. A study on model parameters has been performed.     

崂山隆起寒武系油气勘探前景预测——对比四川盆地和苏北盆地

南黄海盆地是下扬子克拉通板块的主体,也是我国唯一尚未获得油气突破的海区。尤其是崂山隆起,目前只有1口钻井,勘探程度极低,制约了油气勘探的进程。然而,南黄海盆地的烃源岩、储层、盖层和成藏条件与四川盆地和苏北盆地存在着相似的地方。对比分析四川盆地和苏北盆地寒武系可以发现：2个盆地的烃源岩丰度高,厚度大,TOC平均含量分别达4%和3.32%,都是较好的烃源岩;储层以震旦系和寒武系白云岩为主,裂隙发育使储层具有较高的孔隙度和渗透率;成藏模式包括新生古储、古生新储和自生自储。在缺少资料的情况下,通过类比四川盆地和苏北盆地来推测南黄海崂山隆起寒武系的油气地质特征和油气勘探前景。对比分析认为,崂山隆起寒武系具有较大的油气勘探前景,应加快勘探进程。     

不同培养方式及换水频率对坛紫菜(Porphyra haitanensis)自由丝状体生长及藻胆蛋白含量的影响

本实验以坛紫菜自由丝状体为材料,研究不同培养方式(静置、摇床、通气)和换水频率(5d、7d、10d、20d)对丝状体生长及藻胆蛋白(PE、PC)含量变化的影响。研究结果表明:坛紫菜自由丝状体在摇床培养条件下生长较好,特定生长速率可达10.832 7%~10.891 5%;摇床培养下的丝状体PE含量相对静置培养的较高一些,通气培养的相对较低,最高为36.816 8mg/g;静置条件下培养的丝状体PC含量最高,摇床培养次之,通气培养最低,最低为1.082 4mg/g。相同培养方式下,换水频率对丝状体特定生长速率影响不大;除通气培养外,换水频率20d其PE、PC含量较高。方差分析结果表明:实验范围内的培养方式及换水频率对丝状体特定生长速率大小、PE和PC含量不存在交互作用。本文实验结果对坛紫菜自由丝状体产业化应用于食品加工、色素提取等产业提供了实验理论和依据。