李口集区块煤储层地质条件及煤层气采收率

基于煤田勘探资料和矿井实际观测结果,结合测试分析和数值计算,对平顶山矿区李口集区块煤储层地质条件进行了研究。结果表明：区块内主煤层的煤体结构破坏严重,小型裂隙发育但连通性较差,含气量中等且属于低压煤储层,煤层气采收率偏低,地面原位开采的难度较大。为此,建议该区块的煤层气开发以矿井抽采为主,并在煤矿采动带和采空区辅以合理的地面抽采工程。     

珍珠陶石的夹层化合物法鉴定

应用联氨、使珍珠陶石形成其夹层物，然后再用水洗获是水合珍珠陶石，这种水合珍珠陶石具有十分特征的０．８３５ｎｍＸ射线衍射峰，而高岭石族的其它矿物却保持不变，利用这一明显的特征，可以容易地区分出混合在高岭石中的少量珍珠陶石。     

Lead isotope geochemical characteristics of Pb-Zn-Cu deposits on the southwestern margin of Tarim, and their significance

The polymetallic(Pb,Zn,Cu,etc) ore belt on the southwestern margin of Tarim is one of the major regions with the greatest prospecting potential in Xinjiang.Reported in this paper are the lead isotope data for 66 sulfide samples(including 50 galena samples,15 chalcopyrite samples and 1 pyrite sample) collected from such representative deposits as Tamu,Tiekelike,Kalangu,Abalieke,etc.in this ore belt.The Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb in the galena samples range from 17.931 to 18.176,15.609 to 15.818 and 38.197 to 38.944,with the average values of 18.017,15.684 and 38.462,respectively.Those in the chalcopyrite samples range from 17.926 to 18.144,15.598 to 15.628 and 38.171 to 38.583,with the average values of 18.020,15.606 and 38.262,respectively.The pyrite sample has the Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb to be 17.980,15.604 and 38.145,respectively.In combination with the previous Pb isotope data for sulfides,it is found that there is only a slight variation in the Pb isotopic composition of galena,chalcopyrite,sphalerite and pyrite in the ore belt.However,there is some difference in Pb isotopic characteristics between galena and chalcopyrite,especially the Pb isotopic composition of galena shows an obvious linear correlation with some other relevant parameters(e.g.β and γ).The comprehensive analysis suggested that lead in galena(maybe including sphalerite and pyrite) was derived principally from wall rocks and underlying basement,and that in chalcopyrite only originated from the basement.The single-stage model ages of these sulfides couldn’t indicate the time limit of metallogenesis(Pb,Zn,Cu,etc.),and the positive linear correlations for the Pb isotopic composition of galena are of no single-stage and two-stage Pb-Pb isochron significance.Furthermore,there are significant differences in Pb isotopic composition characteristics between the genetic type of deposits in this polymetallic ore belt and the Mississippi Valley type(MVT).In addition,the authors also pointed out that there is a phenomenon of differentiation(not paragenesis) for lead and copper elements during the process of metallogenesis in this ore belt.     

Sr,Nd and O Isotopic Studies on the Genesis of the Huashan Granite Complex1

Abstract Systematical Sr, Nd and O isotopic studies were made on the Huashan granite complex in Guangxi. In combination with the studies of geological, petrological and geochemical data, it is believed that the complex consists of granites of three stages, with different geneses and different source materials. They are not the products of differentiation and evolution of one single consanguineous magma. Granites of the 1st stage are of the Indosinian syntectic type or I type, also derived from a mixed mantle-crustal source. Those of the 2nd stage are of the early Yanshanian syntectic type or I type, also derived from a mixed mantle-crustal source, and those of the 3rd stage are of the late Yanshanian transformed type or S type, derived from a crustal source.     

Determination of Trace Silver in Polymetallic Ore Samples by Flame Atomic Absorption Spectrometry after Solid‐Phase Extraction Using a Microcolumn Comprising Eggshell Membrane

A rapid and inexpensive method was developed for the determination of trace silver in polymetallic ore samples by use of eggshell membrane (ESM), a natural biomaterial, as the solid‐phase extraction (SPE) adsorbent coupled with flame atomic absorption spectrometry (FAAS). The ESM was used for the separation/pre‐concentration of silver, and the parameters affecting sensitivity, such as pH, sample flow rate, eluent volume and eluent flow rate, were carefully investigated. ESM was found to be an effective solid phase extractant for the adsorption of trace silver over a wide range of acidity from 0.02 to 0.50 mol l^?1 HNO₃. The sample solution in 0.4 mol l^?1 HNO₃ was pumped through an ESM microcolumn at the rate of 1.0 ml min^?1. Silver was absorbed, and then eluted with a solution of 1.0% m/v thiourea–0.5% v/v HCl. Under these optimal conditions, ESM exhibited a good enrichment efficiency for silver with a dynamic adsorption capacity of 1.7 mg g^?1. The proposed method was applied to the FAAS determination of trace silver in polymetallic ores and geological reference materials, GSO‐2, 3 and 5, and GSD‐11, GSD‐12, and the determined values were in good agreement with certified values.     

鲁中碳酸岩中磷灰石同位素地球化学研究

鲁中地区分布着100多个碳酸岩体，微量元素含量及稀土配分等均与世界典型碳酸岩相近。而碳酸岩的碳氧及斑晶磷灰石的锶、钛同位素组成与典型地幔物质有差异，与富集地幔颇为近似，从而证实在山东地区陆壳下存在富集地幔源区。     

岩浆混合作用研究综述

本文详细阐述了近年来国内外对岩浆混合作用的研究进展,集中在混合作用的验证及地幔物质参与对混合作用的影响。从能量、物质运移的角度认识岩浆混合作用,以揭示上地幔、地壳的信息,并为认识区域构造一岩浆演化提供约束。综合归纳了岩浆混合作用主要的研究方法,系统总结了混合作用发生的规律及主要影响因素,并应用已有理论和数据进行简单的数值模拟,合理解释岩脉的不混合特征。作为壳一幔间物质与能量交换的重要形式,阐述了岩浆混合与底侵作用的关系,并介绍了常见的岩浆混合作用岩石成因模型。最后说明了岩浆混合作用今后的发展趋势和存在问题。     

塔中古溶洞见证晚奥陶世抬升幅度

塔中隆起区上奥陶统良里塔格组灰岩与桑塔木组砂—粉砂岩之间为不整合接触,昭示着这两个组沉积期之间存在一次历时约百万年的区域性构造抬升事件。中古31井良里塔格组三段的4 125.6～4 133.9 m井段为垮塌型溶洞沉积,洞顶距良里塔格组二段顶部190.6 m,溶洞中角砾状充填物主要来自良里塔格组洞壁本身的礁相灰岩,且见数厘米厚的暗河流水沉积纹层,未发现源于其它时代的颗粒混杂其间。这一事实指证了溶洞的形成和充填时代均为良里塔格组沉积之后、桑塔木组覆盖之前的晚奥陶世凯迪中期。具溶蚀力的淡水潜流带的深度一般不低于周围的海平面,由此可推断出该井区这次抬升出海平面之上的高度,即使忽略良里塔格组顶部可能经地表剥蚀的良里塔格组一段,抬升出水面部分至少也应该有190 m,藉生态地层学恢复洞壁礁灰岩沉积时的海水深度约为30 m±,因此总抬升幅度至少能达到220 m。     

日本大沼湖沉积物碳氮比值、有机碳同位素特征及其近400年的古气候环境意义

通过对日本大沼湖沉积物样品总有机碳含量(TOC)及其稳定同位素、总氮含量(TN)和C/N值的测定,结合沉积岩芯火山灰和1℃年代,分析了大沼湖沉积物中有机质的来源,探讨了沉积物有机碳同位素的主要影响因素.结果表明:大沼湖沉积物中有机质主要来源于自生藻类,受陆源输入的影响较小;沉积物δ13C值指示了夏季温度的变化.过去400年来,大沼湖地区存在1660～ 1730年和1780～ 1860年两个明显的冷期,与邻近地区冰芯、树轮和湖泊沉积物记录的冷期基本一致,分别对应于Maunder和Dalton太阳黑子极小期.     

大西洋上四个爆发性气旋的云微物理参量垂直分布特征分析

利用CloudSat卫星数据处理中心(CloudSat Data Processing Center,CloudSat DPC)提供的CloudSat卫星数据、欧洲中期天气预报中心(European Centre for Medium-Range Weather Forecasts,ECMWF)提供的ERA5再分析资料和美国国家航空航天局(National Aeronautics and Space Administration,NASA)提供的Aqua卫星可见光云图,对冬春季发生在大西洋上四个爆发性气旋个例的云微物理参量垂直分布特征进行了分析。结果表明:爆发性气旋中心云系多为层积云或积云,中心外围云系以雨层云为主,雨层云外部往往伴随着相似高度的高层云,气旋冷锋云带内以雨层云、高层云和高积云为主,冰粒子出现的最低高度与0℃等温线高度几乎重合;冰粒子有效半径随高度的增加而减小,而冰粒子数浓度随高度增加而增大;冰水含量大值区主要位于雨层云中部;液态水主要分布在高层云和层积云底部,冬季爆发性气旋个例内的液态水含量大于春季。