Characteristics of carbonyl compounds in ambient air of Shanghai,China

The levels of carbonyl compounds in Shanghai ambient air were measured in five periods from January 2007 to October 2007 (covering winter, high-air-pollution days, spring, summer and autumn). A total of 114 samples were collected and eighteen carbonyls were identified. Formaldehyde, acetaldehyde and acetone were the most abundant carbonyls and their mean concentrations of 19.40 ± 12.00, 15.92 ± 12.07 and 11.86 ± 7.04 μg m⁻³ respectively, in the daytime for five sampling periods. Formaldehyde and acetaldehyde showed similar diurnal profiles with peak mixing ratios in the morning and early afternoon during the daytime. Their mean concentrations were highest in summer and lowest in winter. Acetone showed reversed seasonal variation. The high molecular weight (HMW, ≥C5) carbonyls also showed obvious diurnal variations with higher concentrations in the daytime in summer and autumn, while they were all not detected in winter. Formaldehyde and acetaldehyde played an important role in removing OH radicals in the atmosphere, but the contribution of acetone was below 1%. The carbonyls levels in high-air-pollution days were reported. More carbonyl species with higher concentrations were found in high-air-pollution days than in spring. These carbonyls were transported with other pollutants from north and northwest in March 27 to April 2, 2007 and then mixed with local sources. Comparing with Beijing and Guangzhou, the concentrations of formaldehyde and acetaldehyde in Shanghai were the highest, which indicated that the air pollution in Shanghai was even worse than expected.     

地震前兆数据库系统共享接口设计与实现

为解决分析预报等相关专业软件访问前兆数据库时存在的性能与安全问题,本文设计了地震前兆数据库系统共享接口软件。该软件可以隔离数据库与应用程序,对应用程序的数据使用情况进行审计与控制,切断非法、低效的数据访问请求;同时,使用连接池、数据缓存和数据压缩等技术提高前兆数据的访问速度。软件无需安装Oracle客户端,易于使用,屏蔽了数据库表结构的复杂性。     

Lateral variation in Moho depth around the southern Tanlu fault zone and its adjacent area

We estimated Moho depth beneath the southern Tanlu fault zone and its adjacent area using common-conversion-point(CCP)stacking of receiver fun-ctions,which were computed from teleseismic records of the CEArray.Our estimated Moho depth matches well with 2-D profiles derived from active-source deep seismic reflection surveys,suggesting that the calculated the Moho depth map is likely accurate beyond the 2-D profiles.Overall,the estimated Moho depth map showed a high spatial correlation with tectonic provinces,i.e.,Moho topographic boundaries are in good agreement with geological boundaries.Beneath the Dabie orogenic belt and the mountainous areas in southern Anhui Province,the Moho lies relatively deep,and there is an obvious difference in Moho depth between the two sides of this segment of the Tanlu fault.We further selected four depth profiles with dense instrumentation to show Moho depth changes across different tectonic blocks in the study area.We saw two step-like changes in Moho depth beneath the Xiangfan-Guangji and Gushi-Feizhong,which run parallel along the WNW-ESE direction and delineate the southern and northern bounds of the northern Dabie orogenic belt,which is likely the suture zone between the North China Block and South China Block.Crust beneath the northeast corner of the study area is significantly thinner than other areas,which is consistent with the crustal detachment model proposed for suturing between the North and South China blocks in the region east to the Tanlu fault.     

华北平原冀中坳陷东部SFQ1钻孔磁性地层年代学及其地质意义

可靠的地层年代标尺对于研究华北平原晚上新世以来沉积物记录的沉积环境演化、新构造运动及古气候演化具有重要意义.本文通过测定冀中坳陷东部的SFQ1钻孔岩芯古地磁,建立高分辨率磁性地层年代框架,并探讨其地质意义.结果表明:SFQ1孔中更新统底界埋深为71.0 m(布容期B/松山期M界线),下更新统底界埋深为197.8 m(松...     

(产刂)子坪铀矿床铀—铅同位素演化体系的研究

铲子坪铀矿床是产在下寒武统清溪组地层中受含矿层及层间构造双重因素控制的矿床。根据该矿床中各种岩石、矿石及矿物的铀—铅同位素体系的研究,大多数岩石样品的铀—铅同位素组成明显不平衡,据计算,含矿层及周围花岗岩中的铀主要以丢失为主,丢失量为30—80％。富矿石的一致性图解及铀—铅三阶段模式年令为t_1=523±16M.Y.,t_2=22±2M.Y.。沥青铀矿的等时线年令为75±4M.Y.,43±7M.Y.。岩石年令为416M.Y.。上述结果表明矿床中的铀主要由含矿层本身供给;可以区分出三个成矿阶段:沉积成岩的予富集,加里东期动力变质的初富集和燕山晚期——喜山早期渗流热液的再富集,因而本矿床属沉积再造的层控铀矿床。     

湖南七里坪夕卡岩型硼矿床的矿石特征及其矿床学意义

七里坪硼矿床的主要矿石类型从岩石学角度看是方解石岩 ,它们由硼矿物和方解石组成 ,二者都是含硼气液交代白云石大理岩 (围岩 )的结果。矿石的化学成分既富钙又富镁 ,钙来自方解石 ,镁来自硼矿物 ,贫其它成分 ,因此夕卡岩型硼矿床不是传统的镁夕卡岩矿床 ,而是钙镁质夕卡岩矿床。     

关于2001年11月14日昆仑山口西地震震级的调查

2001年昆仑山口西地震之后,相当多的研究文章使用了震级8.1的数据,但也有人对该震级表示怀疑.为了澄清数据来源,本文整理了国内外主要的地震目录网站,以及已有文章对该地震震级的使用情况,给出了不同的结果.最终表明,震级8.1的说法来自于国内大震速报目录.     

硫酸参与的长江流域岩石化学风化速率与大气CO2消耗

流域的岩石化学风化过程是全球碳循环中的重要环节。以往的流域水化学碳汇通量估算大多是基于碳酸的风化作用。而实际上,硫酸和碳酸一样,也参与了流域碳元素的地球化学循环,从而对全球碳循环过程产生影响。长江流域水体近几年出现酸化现象,大部分河段SO42-和Ca2+含量增高,其对应的岩石风化过程和大气CO2消耗速率也发生变化。文章对长江干流及主要支流2013年不同季节的离子组成进行监测,利用水化学平衡法和Galy估算模型,对长江流域岩石化学风化速率和CO2消耗通量进行了估算,对硫酸参与下的长江流域岩石风化和碳循环过程进行了分析。结果表明,长江流域水体离子主要来源于硅酸盐岩风化和碳酸盐岩风化。其中碳酸盐岩风化对河水离子贡献率为92%。在硅酸盐岩广泛分布的赣江流域,碳酸盐岩风化离子贡献也达85%。分析表明,硫酸参与了长江流域的岩石风化过程,对水体中离子产生一定影响。硫酸的参与加快了碳酸盐岩的化学风化速率,平均提高约30%,但是使流域大气CO2消耗速率降低。在不考虑蒸发岩溶蚀作用下,平均从516×103 mol/km2·a降至356×103 mol/km2·a,降低约31%。在各支流中,硫酸对乌江流域碳酸盐岩的风化和碳循环的影响最大,而对雅砻江的影响最小,这与乌江流域的含煤地层、矿床硫化物及大气酸沉降有关。     

煌斑岩—硫化物熔体液态不混溶作用的高温高压实验研究

本文以云南老王寨金矿区煌斑岩和黄铁矿为初始物,在1.5～3.0GPa、1162～1560℃条件下进行了煌斑岩—硫化物熔体液态不混溶作用实验。结果表明,煌斑岩硫化物熔体的液态不混溶作用可能发生于岩浆演化的早期（高压条件）,但如有硫存在,在岩浆演化的各个阶段（高压条件→低压条件）均可能出现煌斑岩硫化物熔体的液态不混溶作用;与煌斑岩熔体分离的硫化物熔体在温度场、压力场中作定向运移,逐渐聚集于相对低温、低压区;由于硫化物熔体的密度相对较大,因而与煌斑岩熔体之间出现明显的分层现象。     

电子自旋共振法年龄测定研究

电子自旋共振(ESR)法适用于第四纪样品的年龄测定.本文报道近2年来作者等对鹿角、丽蚌、石筍、黄土、珊瑚和贝壳样品的年龄测定,其结果与地层、TL和¹⁴C年龄相符.预示ESR法将会成为第四纪年代学研究的有力工具.