A Target Detection Method for Hyperspectral Imagery Based on Two-Time Detection

To solve the low detection efficiency problem of Constrained Energy Minimization (CEM) method used for hyperspectral remote sensing imagery, this paper firstly presents two improved detection methods: principal component CEM (PCCEM) and matrix taper CEM (MTCEM). Then, based on these two methods, a more optimized Two-Time detection (TTD) method is proposed. Primarily, the targets of interest in the hyperspectral image are detected by using the PCCEM and MTCEM method. Then the autocorrelation matrix of non-target pixels is estimated according to the target detection results. Finally, based on this autocorrelation matrix, a new weight vector is constructed for the second detection. Under the effect of this new weight vector, the output energy of the target can be kept at unity and the output energy of the background is suppressed at the same time. Then, the improvement of target detection result can be realized. Experimental results on a real world hyperspectral data show the efficiency of the proposed TTD method to improve the detection performance.     

An improved ionosphere interpolation algorithm for network RTK in low-latitude regions

A traditional interpolation algorithm with the linear interpolation method (LIM) using a fixed number of reference stations is widely used in network RTK to obtain the ionospheric delays for the users. In low-latitude regions, where the ionosphere is relatively active, however, large interpolation errors exist, especially for satellites at low elevation angles. Considering the characteristics of “coinciding ionospheric pierce points (CIPPs)” with a similar nature of ionospheric delays, an improved interpolation algorithm is proposed. In this algorithm, all stations with CIPPs are used to establish the interpolation model; thus, more precise interpolation model is achieved. To validate the performance of the proposed algorithm, data from some reference stations in Guangdong Province of China were used, and the results are compared with those with the traditional interpolation algorithm. Numerical analysis shows that the interpolation accuracy of the proposed algorithm increases by 10–30% compared with the traditional one. Since the number of reference stations is flexible, the proposed algorithm can also balance the model accuracy with the computation burdens. In addition, the proposed algorithm is less affected by the selection of master reference station. In terms of network RTK on-the-fly positioning, the time-to-first-fix is reduced when replacing the traditional interpolation algorithm with the proposed one.     

Characterization,dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb<Subscript>x</Subscript>Ca<Subscript>1−x</Subscript>)<Subscript>5</Subscript>(PO<Subscript>4</Subscript>)<Subscript>3</Subscript>OH] at 25 °C and pH 2–9

Background

The interaction between Ca-HAP and Pb²⁺ solution can result in the formation of a hydroxyapatite–hydroxypyromorphite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)], which can greatly affect the transport and distribution of toxic Pb in water, rock and soil. Therefore, it’s necessary to know the physicochemical properties of (Pb_xCa_1?x)₅(PO₄)₃(OH), predominantly its thermodynamic solubility and stability in aqueous solution. Nevertheless, no experiment on the dissolution and related thermodynamic data has been reported.

Results

Dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃(OH)] in aqueous solution at 25 °C was experimentally studied. The aqueous concentrations were greatly affected by the Pb/(Pb + Ca) molar ratios (X_Pb) of the solids. For the solids with high X_Pb [(Pb_0.89Ca_0.11)₅(PO₄)₃OH], the aqueous Pb²⁺ concentrations increased rapidly with time and reached a peak value after 240–720 h dissolution, and then decreased gradually and reached a stable state after 5040 h dissolution. For the solids with low X_Pb (0.00–0.80), the aqueous Pb²⁺ concentrations increased quickly with time and reached a peak value after 1–12 h dissolution, and then decreased gradually and attained a stable state after 720–2160 h dissolution.

Conclusions

The dissolution process of the solids with high X_Pb (0.89–1.00) was different from that of the solids with low X_Pb (0.00–0.80). The average K _sp values were estimated to be 10^?80.77±0.20 (10^?80.57–10^?80.96) for hydroxypyromorphite [Pb₅(PO₄)₃OH] and 10^?58.38±0.07 (10^?58.31–10^?58.46) for calcium hydroxyapatite [Ca₅(PO₄)₃OH]. The Gibbs free energies of formation (ΔG _f ^o ) were determined to be ?3796.71 and ?6314.63 kJ/mol, respectively. The solubility decreased with the increasing Pb/(Pb + Ca) molar ratios (X_Pb) of (Pb_xCa_1?x)₅(PO₄)₃(OH). For the dissolution at 25 °C with an initial pH of 2.00, the experimental data plotted on the Lippmann diagram showed that the solid solution (Pb_xCa_1?x)₅(PO₄)₃(OH) dissolved stoichiometrically at the early stage of dissolution and moved gradually up to the Lippmann solutus curve and the saturation curve for Pb₅(PO₄)₃OH, and then the data points moved along the Lippmann solutus curve from right to left. The Pb-rich (Pb_xCa_1?x)₅(PO₄)₃(OH) was in equilibrium with the Ca-rich aqueous solution.

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Graphical abstractLippmann diagrams for dissolution of the hydroxypyromorphite–hydroxyapatite solid solution [(Pb_xCa_1?x)₅(PO₄)₃OH] at 25??C and an initial pH of 2.00.

     

Research on Creep Deformation and Control Mechanism of Weak Surrounding Rock in Super Large Section Tunnel

Geotechnical and Geological Engineering - In order to solve the difficulties of creep deformation of surrounding rock in super large section tunnel, taking Letuan tunnel of Binlai expressway, a...     

Tracing origins of sewage and organic matter using dissolved sterols in Masan and Haengam Bay,Korea

Masan and Haengam Bays in Korea are highly polluted and semi-enclosed. Domestic and industrial effluents are directly or indirectly discharged into the bays through sewage treatment plants (STP) and creeks. In this study, 15 dissolved sterol compounds were determined in order to understand their sources and relative contribution. Freshwater samples were taken from 13 creeks and at two STP sites on a monthly basis. Total dissolved sterol concentrations ranged from 993 to 4158 ng/L. The concentrations of sterols in winter were higher than in summer. Among the sterols analyzed, cholesterol, β-sitosterol, coprostanol and cholestanone were major compounds in creek water. Seawater samples were concurrently collected at 21 stations in Masan Bay. Total sterol concentrations ranged 118–6,956 ng/L. Inner bay showed high concentrations of sterols in summer, while outer bay showed high sterol concentrations in winter. Among the sterols, cholesterol, β-sitosterol and brassicasterol were major compounds in seawater. In order to examine the contribution of urban sewage, the concentration of coprostanol and fecal sterol ratios were calculated. Most of the creek water, inner bay and near STP outlet samples were affected by sewage. Terrestrial organic matters accounted for a high proportion of dissolved organic matter origin. Fecal origins were relatively high in the inner bay areas and in the STP outlet, while sterols of marine origin were high in the outer bay areas.     

地勘单位经济指标考核体系探讨

地勘单位执行多年的经济指标考核体系一般由决算总收入、新增资本积累、净资产总额、应收账款与存货占经营收入比率、提取折旧额、提交煤炭资源量,人均年收入等七项指标组成。该指标体系经过多年运行,已经趋于成熟。但是该指标考核体系没有考虑到不同单位的综合经济实力和生产能力水平的差异,忽略了不同单位之间的主营业务性质和区域性差异,使考核结果公平性存在一定的缺陷。本文依据全面考核原则、科学考核原则、可操作性原则,探讨了如何改进经济指标考核体系,并提出了可供实施的企业经济效益综合指数考核指标体系。     

云南老王寨金矿区煌斑岩中碳酸盐的化学成分及其意义

本文报道了云南老王寨金矿区非矿化、矿化煌斑岩中不同产状碳酸盐的化学成分，结果表明本区煌斑岩中为次生碳酸盐，原生碳酸盐含量不超过１％；煌斑岩蚀变、矿化为不同阶段的产物；碳酸盐脉活动发生在成矿作用之后。     

Study on Deformation Failure Mechanism and Control Technology of Surrounding Rock in Soft Rock Roadway

Geotechnical and Geological Engineering - In order to reveal the mechanism of surrounding rock deformation and instability of soft rock roadway in 12# working face of Puhe coal mine, and...     

Effective environmental management through environmental knowledge management

Owing to the green revolution, environmental problems have now become some of the most important issues worldwide. Environmental knowledge management, which combines the strengths of environmental management and knowledge management, will become a popular tool for businesses in the near future. In this paper, through interviews of staff at different levels and in different departments of the business, i. e. managers and engineers and using the environmental knowledge circulation process, the authors evaluate the success of environmental knowledge management when applied to China Steel Corporation in Taiwan. From the case study, the authors found that China Steel Corporation has applied the environmental knowledge circulation process for over thirty years. The company continually improves its environmental and financial performance through environmental knowledge creation, environmental knowledge accumulation, environmental knowledge sharing, environmental knowledge utilization and environmental knowledge internalization. Water pollution and air emissions have reduced year on year and total energy consumption has reduced by 20 % from 1979 to 2006. On the other hand, China Steel Corporation also makes a profit and reduces cost through energy sold, by-products and recycling. Continuous improvement in environmental knowledge management has rendered China Steel Corporation in the most profitable steel company in Taiwan and the world’s twenty fifth largest steel producing company in 2006.