Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

2-D crustal Poisson’s ratio from seismic travel time inversion in Changbaishan Tianchi volcanic region

Based on the inversion method of 2D velocity structure and interface, the crustal velocity structures of P-wave and S-wave along the profile L ₁ are determined simultaneously with deep seismic sounding data in Changbaishan Tianchi volcanic region, and then its Poisson’s ratio is obtained. Calculated results show that this technique overcomes some defects of traditional forward calculation method, and it is also very effective to determine Poisson’s ratio distribution of deep seismic sounding profile, especially useful for study on volcanic magma and crustal fault zone. Study result indicates that there is an abnormally high Poisson’s ratio body that is about 30 km wide and 12 km high in the low velocity region under Tianchi crater. Its value of Poisson’s ratio is 8% higher than that of surrounding medium and it should be the magma chamber formed from melted rock with high temperature. There is a high Poisson’s ratio zone ranging from magma chamber to the top of crust, which may be the uprise passage of hot substance. The lower part with high Poisson’s ratio, which stretches downward to Moho, is possibly the extrusion way of hot substance from the uppermost mantle. The conclusions above are consistent with the study results of both tomographic determination of 3D crustal structure and magnetotelluric survey in this region. Foundation item: Key Project from China Earthquake Administration and the Project (95-11-02-01) from Ministry of Science and Technology (2001DIA10003). Contribution No. RCEG200401, Geophysical Exploration Center, China Earthquake Administration.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

Experimental study on soil CO2 emission in the alpine grassland ecosystem on Tibetan Plateau

The Tibetan Plateau, the Roof of the World, is the highest plateau with a mean elevation of 4000 m. It is characterized by high levels of solar radiation, low air temperature and low air pressure compared to other regions around the world. The alpine grassland, a typical ecosystem in the Tibetan Plateau, is distributed across regions over the elevation of 4500 m. Few studies for carbon flux in alpine grassland on the Tibetan Plateau were conducted due to rigorous natural conditions. A study of soil respiration under alpine grassland ecosystem on the Tibetan Plateau from October 1999 to October 2001 was conducted at Pangkog County, Tibetan Plateau (31.23°N, 90.01°E, elevation 4800 m). The measurements were taken using a static closed chamber technique, usually every two weeks during the summer and at other times at monthly intervals. The obvious diurnal variation of CO2 emissions from soil with higher emission during daytime and lower emission during nighttime was discovered. Diurnal CO2 flux fluctuated from minimum at 05:00 to maximum at 14:00 in local time. Seasonal CO2 fluxes increased in summer and decreased in winter, representing a great variation of seasonal soil respiration. The mean soil CO2 fluxes in the alpine grassland ecosystem were 21.39 mgCO2 · m-2 · h-1, with an average annual amount of soil respiration of 187.46 gCO2 · m-2 · a-1. Net ecosystem productivity is also estimated, which indicated that the alpine grassland ecosystem is a carbon sink.     

Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

The Quantitative Identification of Regional Mine and Natural Earthquakes and Its Application

INTRODUCTIONThe structural mine earthquake in coal mines refers to the quake induced by excavationengineeringthatleadstorupturingor change of geological structure and weakness surfaceintheinteriorof rock mass.According to the origin,mine earthquakes can b…     

Least-squares wave-path migration

We present a new least-squares migration method called least-squares wave-path migration. The proposed method combines an iterative conjugate-gradient solver with a stationary-phase wave-path migration operator. Numerical tests demonstrate that (i) least-squares wave-path migration is computationally more efficient than and almost as accurate as Kirchhoff least-squares migration, and (ii) many of the artefacts seen in wave-path migration images are suppressed after several conjugate-gradient iterations. Previous results have shown that 3D wave-path migration is up to 100 times faster than a standard 3D Kirchhoff migration, but sometimes at the cost of reduced quality. With the proposed least-squares wave-path migration method, the image quality in wave-path migration can be improved at an acceptable increase in computational cost.     

当前国际水文学科技术领域的研究方向

根据联合国有关机构发布的公报和世界各国近年来的学术研究情况，整理出了近期水文学科在地表水、地下水、水质、水资源系统、大气～土壤～植被、大陆侵蚀、冰雪、遥感技术和示踪技术等领域的热门研究课题，在一定程度上反映了当前国际上水文学科的研究和发展方向，对国内同行有一定的参考价值。     

在卸荷产生拉剪情况下裂隙岩体的力学行为

据岩体在卸荷情况下的拉剪应力状态,确定了节理岩体的线弹性断裂力学模型。依照此模型,可以得到相对远离裂隙(该位置的点到裂隙中心的距离比裂缝长度大)且受裂隙影响区域内应力、应变和变形方程。这些对评估裂隙岩石变形有重要的参考意义。通过用理论方程的计算结果和卸荷情况下试验观测所得的数据对比,证明该模型应用于实际工程中具有可行性。