A comparative study of opaque phases in Qingzhen (EH3) and MacAlpine Hills 88136 (EL3): Representatives of EH and EL parent bodies

Abstract— Opaque minerals in the Qingzhen (EH3) and MacAlpine Hills (MAC) 88136 (EL3) enstatite chondrites were studied and compared with other EH and EL chondrites. All opaque minerals usually occur in multi‐sulfide‐metal clasts and nodules in the matrix between chondrules (El Goresy et al., 1988). The higher abundance of opaque minerals, the occurrence of niningerite and various alkali‐sulfides (e.g., caswellsilverite, phases A and B, djerfisherite) are diagnostic criteria for EH chondrites, while alabandite is characteristic for EL chondrites. In addition, EH chondrites are characterized by enrichments of Si in both kamacite and perryite, and alkali elements in sphalerite and chalcopyrite. The Mn contents of daubreelite and sphalerite are lower in EH than in EL chondrites. These are consistent with lower oxygen fugacity and higher H₂S fugacity of EH than EL chondrites. In contrast, the discovery of sphalerite and Zn‐rich daubreelite in MAC 88136 indicates that their absence in EL6 chondrites is probably related to thermal metamorphism in the parent body. Schreibersite microspherules are commonly enclosed in most sulfides in Qingzhen, but are absent in MAC 88136. They were once molten, and probably predated all sulfide host phases. The petrographic setting and chemical compositions of the sulfide hosts of the schreibersite microspherules in EH3 chondrites are consistent with formation by condensation. The earliest sulfide condensates oldhamite and niningerite occupy the interiors of the clasts and nodules, whereas the rims consist of troilite and djerfisherite. In addition, in Qingzhen, some other troilite, djerfisherite and sphalerite assemblages coexist with perryite. They were produced by sulfurization of metallic Fe‐Ni in the nebula. In MAC 88136, sulfurization of Si‐bearing Fe‐Ni metal is less pronounced, and it produced troilite, schreibersite and less abundant perryite. Two kinds of normal zoning and a reverse zoning trends of niningerite, and both normal and reverse zoning of sphalerite were found in clasts and nodules in Qingzhen. The coexistence of normal and reverse zoning profiles in niningerite grains in the same meteorite strongly suggests that they formed before accretion in the parent body, because an asteroidal metamorphic or an impact event in the parent body would have erased these contrasting profiles and destroyed the textural settings. In contrast, alabandite in MAC 88136 shows only normal zoning, with the FeS content decreasing to 9.3 mol% toward troilite, indicating very slow cooling at low temperature.     

Broadband Radio Bursts and Fine Structures during the Great Solar Event on 14 July 2000

25 MHz–7.6 GHz global and detailed (fine structure – FS) radio spectra are presented, which were observed in the NOAA 9077 active region for the Bastille Day (14 July 2000) flare at 10:10–11:00 UT. Besides broadband radio bursts, high-resolution dynamic spectra reveal metric type II burst, decimetric type IV burst and various decimetric and microwave FSs, such as type III bursts, type U bursts, reverse-slope (RS)-drifting burst, fiber bursts, patch and drifting pulsation structure (DPS). The peak-flux-density spectrum of the radio bursts over the range 1.0–7.6 GHz globally appears as a U-shaped signature. Analyzing the features of backbone and herringbones of the type II burst, the speeds of shock and relevant energetic electron beams were estimated to be 1100 km s⁻¹ and 58 500 km s⁻¹, respectively. Also the time sequence of the radio emission is analyzed by comparing with the hard X-rays (HXRs) and the soft X-rays (SXRs) in this flare. After the maxima of the X-rays, the radio emission in the range 1.0–7.6 GHz reached maxima first at the higher frequency, then drifted to the lower frequency. This comparison suggested that the flare included three successive processes: firstly the X-rays rose and reached maxima at 10:10–10:23 UT, accompanied by fine structures only in the range 2.6–7.6 GHz; secondly the microwave radio emission reached maxima accompanied by many fine structures over the range 1.0–7.6 GHz at 10:23–10:34 UT; then a decimetric type IV burst and its associated FSs (fibers) in the range 1.0–2.0 GHz appeared after 10:40 UT.     

A reliability‐based selective index for regional flood frequency analysis methods

In this paper, a new index is proposed for the selection of the best regional frequency analysis method. First, based on the theory of reliability, the new selective index is developed. The variances of three regional T‐year event estimators are then derived. The proposed methodology is applied to an actual watershed. For each regional method, the reliability of various T‐year regional estimates is computed. Finally, the reliability‐based selective index graph is constructed from which the best regional method can be determined. In addition, the selection result is compared with that based on the traditional index, root mean square error. The proposed new index is recommended as an alternative to the existing indices such as root mean square error, because the influence of uncertainty and the accuracy of estimates are considered. Copyright © 2003 John Wiley & Sons, Ltd.     

福建省地壳形变观测网络建设

介绍了福建省地壳形变观测网络的建设。福建省地壳形变观测网络，以GPS观测技术为主，结合精密水准、精密重力和流动地磁测量，将3者重合到GPS观测基准站上获取观测信息，初步构成一个时空相结合，点线面与长中短兼顾的高精度、高时空分辨率的地壳形变观测网络。该网络可动态监测福建省东南沿海地区地壳运动变化，为地震预测预报提供背景信息，将取得显著的社会效益和经济效益。     

Combined perturbation on near-earth satellite orbits

Using a semi-analytical method, we have obtained a first-order solution of the equations of motion of near-Earth satellites under the combined perturbing effect due to Earth's figure and air drag.     

Effect of Fe2+ ions on polarization behavior of X60 steel in CO2 saturated salty water

The effects of ferrous ions on cathodic and anodic polarization behavior of the X60 steel in CO₂ saturated salty water were studied by potentio-dynamic polarization method. The results show that the reducing current peak of cathodic polarization is affected significantly if FeCl₂ is added to the salty solution of controlled pH, but not the anodic polarization. It is considered that the ferrous ions accelerate the formation of a protective ferrous carbonate film. Films formed by addition of ferrous ions and those formed by ferrous ions produced from steel corrosion have the same forming mechanism. The former can fully meet the formative condition of the film and can play the role of inhibitor.     

关于加快长江上游干,支流综合开发治理的建议

笔者通过考察认为,以水电建设为龙头,加快长江上游干、支流综合开发治理是长江流域开发的一个重要组成部分,对推动整个流域经济的持续稳定发展具有重大的意义。文中论述了:1、先期开发治理长江上游干、支流是合理利用长江水资源,防治长江洪水灾害的关键。2、综合开发治理长江上游干、支流将能获得的巨大社会、经济与环境效益。3、加快开发长江上游干、支流的政策与措施。     

The yield and isotopic composition of radiolytic H2, a potential energy source for the deep subsurface biosphere

The production rate and isotopic composition of H₂ derived from radiolytic reactions in H₂O were measured to assess the importance of radiolytic H₂ in subsurface environments and to determine whether its isotopic signature can be used as a diagnostic tool. Saline and pure, aerobic and anaerobic water samples with pH values of 4, 7, and 10 were irradiated in sealed vials at room temperature with an artificial γ source, and the H₂ abundance in the headspace and its isotopic composition were measured. The H₂ concentrations were observed to increase linearly with dosage at a rate of 0.40 ± 0.04 molecules (100 eV)⁻¹ within the dosage range of 900 to 3500 Gray (Gy; Gy = 1 J Kg⁻¹) with no indication of a maximum limit on H₂ concentration. At ∼2000 Gy, the H₂ concentration varied only by 16% across the experimental range of pH, salinity, and O₂. Based upon this measured yield and H₂ yields for α and β particles, a radiolytic H₂ production rate of 10⁻⁹ to 10⁻⁴ nM s⁻¹ was estimated for the range of radioactive element concentrations and porosities typical of crustal rocks. The δD of H₂ was independent of the dosage, pH (except for pH 4), salinity, and O₂ and yielded an αD_H2O-H2 of 2.05 ± 0.07 (αD_H2O-H2 = (D/H)_H2O to (D/H)_H2), slightly less than predicted radiolytic models. Although this radiolytic fractionation value is significantly heavier than that of equilibrium isotopic exchange between H₂ and H₂O, the isotopic exchange rate between H₂ and H₂O will erase the heavy δD of radiolytic H₂ if the age of the groundwater is greater than ∼10³ to 10⁴ yr. The millimolar concentrations of H₂ observed in the groundwater of several Precambrian Shields are consistent with radiolysis of water that has resided in the subsurface for a few million years. These concentrations are well above those required to support H₂-utilizing microorganisms and to inhibit H₂-producing, fermentative microorganisms.     

地质体三维可视化建模的技术方法研究

地质体三维可视化模型具有形象、直观、动态、准确、信息丰富等特点,在指导地质找矿和矿山开发等方面具有很大的优势及实用价值。文章对地质体三维可视化建模的整个技术方法流程作了总结性阐述,并分析其技术关键,同时还进一步探讨了模型的分类及其应用。     

Improvement on the second-order solution of artificial satellite orbits

Three methods are proposed in this paper to lessen the complexity in the derivation and the resulting expressions of second-order analytical solutions of artificial satellite orbits while retaining the advantages of analytical solutions. Of the three, the one combining the theories of elliptical perturbation and of intermediate orbits is noteworthy for its simplicity. It can also be used with advantage in first-order and third- or higher order solutions.