Statistical and geochemical assessment of groundwater quality in Teboursouk area (Northwestern Tunisian Atlas)

Teboursouk region, Northwestern Tunisia, is characterized by the diversity of its natural resources (petroleum, groundwater and minerals). It constitutes a particular site widely studied, especially from a tectonic stand point as it exhibits a complex architecture dominated by multi-scale synclinals and Triassic extrusions. It has typical karst landform that constitutes important water resources devoted for human consumption and agriculture activities, besides to the exploitation of the Mio-Plio-Quaternary aquifer (MPQ). Thus, hydrogeological investigations play a significant role in the assessment of groundwater mineralization and the evaluation of the used water quality for different purposes. Hence, the current study based on a combined geochemical–statistical investigation of 50 groundwater samples from the multilayered aquifer system in the study area give crucial information about the principal factors and processes influencing groundwater chemistry. The chemical analysis of the water samples showed that Teboursouk groundwater is dominantly of Ca–Mg–Cl–SO₄ water type with little contribution of Ca–Mg–HCO₃, Na–K–Cl–SO₄ and Na–K–HCO₃. The total dissolved solids (TDS) values range from 0.37 to 3.58 g/l. The highest values are located near the Triassic outcrops. Furthermore, the hydrogeochemistry of the studied system was linked with various processes such as carbonates weathering, evaporites dissolution of Triassic outcrops and anthropogenic activities (nitrate contamination). Additionally, the main processes controlling Teboursouk water system were examined by means of multivariate statistical analysis (PCA and HCA) applied in this study based on 10 physicochemical parameters (TDS, pH, SO₄, HCO₃, pCO₂, Ca, Mg, Na, K, Cl and NO₃). Two principal components were extracted from PCA accounting 61% of total variance and revealing that the chemical characteristics of groundwater in the region were acquired through carbonates and evaporite dissolution besides to nitrate contamination. Similarly, according to Cluster analysis using Ward’s method and squared Euclidean distance, groundwater from the studied basin belongs to five different groups suggesting that the geochemical evolution of Teboursouk groundwater is controlled by dissolution of carbonates minerals, chemical weathering of Triassic evaporite outcrops, cation exchange and anthropogenic activities (nitrate contamination).     

Constraints on the application of the MBT/CBT palaeothermometer at high latitude environments (Svalbard,Norway)

Branched glycerol dialkyl glycerol tetraethers (GDGTs) are membrane lipids of unknown bacteria that are ubiquitous in soil and peat. Two indices based on the distribution of these lipids in soils, the Cyclization of Branched Tetraethers (CBT) and the Methylation of Branched Tetraethers (MBT) indices have been shown to correlate with soil pH, and mean annual air temperature (MAT) and soil pH, respectively, and can be used to reconstruct MAT in palaeoenvironments. To verify the extent to which branched GDGTs in marine sediments reflect the distribution pattern on land and whether these proxies are applicable for palaeoclimate reconstruction in high latitude environments with a MAT of <0 °C, we compared the branched GDGT distribution in Svalbard soils and nearby fjord sediments. Although branched GDGT concentrations in the soil are relatively low (0.02–0.95 μg/g dry weight (dw)) because of the cold climate and the short growing season, reconstructed MATs based on the MBT/CBT proxy are ca. ?4 °C, close to the measured MAT (ca. ?6 °C). Concentrations of branched GDGTs (0.01–0.20 μg/g dw) in fjord sediments increased towards the open ocean and the distribution was strikingly different from that in soil, i.e. dominated by GDGTs with one cyclopentane moiety. This resulted in MBT/CBT-reconstructed MAT values of 11–19 °C, well above measured MAT. The results suggest that at least part of the branched GDGTs in marine sediments in settings with a low soil organic matter (OM) input may be produced in situ. In these cases, the application of the MBT/CBT palaeothermometer will generate unrealistic MAT reconstructions. The MBT/CBT proxy should therefore only be used at sites with a substantial input of soil OM relative to the amount of marine OM, i.e. at sites close to the mouth of rivers with a catchment area where sufficient soil formation takes place and the soil thus contains substantial amounts of branched GDGTs.     

GIS and multi-criteria analysis to select potential sites of agro-industrial complex

The selection of the potential sites to the creation of an agro-industrial complex requires a large amount of spatial information. Geographical information systems are capable of managing this information, providing the ability to integrate multiple layers of information and deriving new ones. This study incorporates environmental, social, economic, geological and infrastructural data. A multi-criteria analysis is performed to select the potential sites to the creation of an agro-industrial complex in the city of Sfax (the southern coast of Tunisia). The comparison by pair method adopted in this paper, based on a linear combination pondered after having assigned to every factor of decision a coefficient of level-headedness, creates many scenarios among which we selected the sustainable development one. This scenario assigned the highest weight to the economical, environmental and social factors (0.3 for each factor), which shows the presence of nine suitable sectors for the creation of an agro-industrial complex. The ELECTRE method enabled us to make a site ordering for the identification of the most three appropriate sites.     

Geological and geophysical studies of the Agoudal impact structure (Central High Atlas,Morocco): New evidence for crater size and age

Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km²) and 1:15,000 (2.25 km²) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (³⁶Cl) constrain the local erosion rates between 220 ± 22 m Ma^?1 and 430 ± 43 m Ma^?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data.     

Determination of the onset dates of the rainy season in central Amazon with equatorially antisymmetric outgoing longwave radiation

The present work provides a new methodology to determine onset dates of the rainy season (ONR) in central Amazon (CAM) using the antisymmetric in relation to the equator outgoing longwave radiation (OLR) (AOLR) data, for the 1979–2006 period. Spatial averages of the AOLR ( $\overline {AOLR} $ ) over the CAM for the ONR periods are obtained. These periods correspond to 25 pentads centered on the mean pentad for the ONR. The sign changes from positive to negative of the $\overline {AOLR} $ for the ONR periods indicate the transition from dry to wet season. Composites of several variables are done for pentads before and after the ONR dates. These composites show physically consistent features. The potential of the $\overline {AOLR} $ time series as an index for monitoring tasks is analyzed. The results here show that the $\overline {AOLR} $ for the ONR period captures the transition from dry to wet conditions in the CAM area during 2006. The advantages of this method are discussed. The new simple method proposed here seems to be efficient in determining the ONR in the CAM.     

How to evaluate the quality of coarse‐resolution DEM‐derived drainage networks

The quality of digital elevation model (DEM)‐derived river drainage networks (RDNs) is influenced by DEM quality, basin physical characteristics, scale, and algorithms used; these factors should not be neglected. However, few research studies analyse the different evaluation approaches used in the literature with respect to adequacy, meaning of the results, advantages, and limitations. Focusing on coarse‐resolution networks, this paper reviews the use of these techniques and offers new insights on these issues. Additionally, we propose adaptations for selected metrics and discuss distinct interpretations for the evaluation of RDNs derived at different spatial resolutions (1, 5, 10, 20, and 30 km) considering the Uruguay River basin (206,000 km²) as a case study. The results demonstrate that lumped basin/river characteristics and basin delineation analysis should not be used as evaluation criteria for RDN quality; however, some of these metrics offer useful complementary information. Percentage of the DEM‐derived RDN within a uniform buffer placed around a river network considered as reference and mean separation distance between these two networks are more suitable metrics, but the former is insensitive to serious errors. The change in reference from a fine‐scale network to a coarse‐resolution manual tracing network significantly augments the discrepancy of these largest errors when the mean distance metric was applied, and visual comparison analysis is necessary to interpret the results for other metrics. We recommend the use of the mean distance metric in combination with a detailed visual assessment, the importance of which increases as the resolution coarsens. In both cases, the impact of network quality can be further refined by quantifying the basin shape and river length errors.     

Poverty and environmental nexus in rural Pakistan: a multidimensional approach

The study examines the relationship between poverty and forest cover degradation in rural areas of Pakistan. The area selected for the study District Upper Dir is a rural and relatively backward region located in northwestern Pakistan, in Khyber-Pakhtunkhwa province. The study area is undergoing severe deforestation and natural disasters in the recent past. The study consists of two stages, in first stage the traditional Geographical information system image was used to analyze the spatial–temporal situation of the surroundings. In the second stage, well-designed questionnaire was used to collect the primary information from 420 randomly selected households of research areas. A multidimensional poverty index has been used to measure the poverty profile of the population. It has been found that 55% households were below the poverty line. Almost, 95% households are using wood for cooking purposes. High dependence on natural resources causes forest cover degradation while burning off too much wood causes CO₂ emission and leads to environmental degradation. A major portion of population is living on steeply sloped areas with certain risks. It is found that frequency of flash flood is 53% and agricultural land (54%) is at high risk and often flows with flash floods. It is concluded that there is strong correlation between multidimensional poverty and forest cover degradation which leads to climate and environmental risks.

     

The common oscillations of solar activity,the geomagnetic field,and the Earth's rotation

An oscillation with a period around 5.5 years is identified as being common to the geomagnetic field, the Earth's rotation, and solar activity variations. The large extrema of the cross-correlation functions and their oscillatory character are considered to be indicators of a physical relation between geophysical and solar phenomena.