Nachweis von Industriechemikalien (HPS,BPS und SPS) im Oberflächenwasser

Occurrence of Industrial Chemicals (HPS, BPS, and SPS) in Surface Water The paper gives the results of water examinations for different phenylsulfonamides. Random samples taken every month between May 1999 and August 2000 from surface water out of the river Rhine (kilometer 838), the river Ruhr (Mülheim Styrum) and the river Emscher (Oberhausen center) were tested for the corrosion inhibiting agent 6‐[methyl(phenylsulfonyl)amino]‐hexanoic acid (HPS) as well as its metabolites 4‐[methyl‐(phenylsulfonyl)amino]‐butanoic acid (BPS) and sarkosin‐N‐(phenylsulfonyl) (SPS). Furthermore, the sewage plant effluents of two municipal wastewater treatment plants from the rural area were also included in the monitoring program. The analytical method includes solid‐phase extraction (SPE), a derivatization step as well as gas chromatography mass spectrometry (GC‐MS). SPS is regularly found in all investigated surface waters, but only occasionally in the effluents of the two rural sewage plants. The median values for SPS amount to 0.09 μg/L in the river Rhine, 0.60 μg/L in the river Ruhr, and 0.70 μg/L in the river Emscher. BPS can only be found in the river Ruhr (median value: 0.08 μg/L) and in the river Emscher (median value: 0.41 μg/L). HPS was regularly found in a surface water for the first time. This substance can be detected in the Emscher through the whole measurement period. The median value for HPS amounts to 1.78 μg/L. Aditionally, the validation characteristics of an alternative analytical method including solid‐phase microextraction (SPME) is worked out. The fully automated process includes an on‐fiber methylation step and the GC‐MS. The repeatability standard deviation of the process amounts to RSD < 12%. Detection limits between 0.07 and 0.70 μg/L are achieved.     

Coronal holes and icosahedral symmetry

A new type of coordinates suitable to describe mass outflow out of coronal holes assuming symmetry under the icosahedral group is introduced.     

Evidence for the 22-year-cycle in the longitudinal distribution of sunspots

It was shown in an earlier paper that preferred hemispheres of solar activity alternate with the 22-year magnetic cycle, when analyzed in the 27.0 day Bartels rotation. Using data which cover the time between 1818 and 1983 we trace back this result to 1880 (cycle 12). Before 1880 no significant correlations are found.     

A spherical model for computing polarized radiation in Titan's atmosphere

The Huygens descent through Titan's atmosphere in January 2005 will provide invaluable information about Titan's atmospheric composition and aerosol properties. The Descent Imager/Spectral Radiometer (DISR) will perform upward and downward looking radiation observations at various spectral ranges and spatial resolutions. To prepare the DISR data interpretation we have developed a new model for radiation transfer in Titan's atmosphere. The model solves for the full three-dimensional polarized radiation field in spherical geometry. However, the atmosphere itself is assumed to be spherically symmetric. The model is initialized with a fast-to-compute plane–parallel solution based on the doubling and adding algorithm that incorporates a spherical correction for the incoming direct solar beam. The full three-dimensional problem is then solved using the characteristics method combined with the Picard iterative approximation as described in Rozanov et al. (J. Quant. Spectrosc. Radiat. Transfer 69 (2001) 491). Aerosol scattering properties are calculated with a new microphysical model. In this formulation, aerosols are assumed to be fractal aggregates and include methane gas absorption embedded into the extinction coefficient. The resulting radiance of the model atmosphere's internal field is presented for two prescribed DISR wavelengths.     

On changes of the rotation velocities of stable,recurrent sunspots and their interpretation with a flux tube model

The angular rotation velocities of stable, recurrent sunspots were investigated using data from the Greenwich Photoheliographic Results 1940 until 1968. We found constant rotation velocities during the passages on the solar disk with errors of about ±4 m s^–1. During their lifetime these spots show a decreasing braking of their rotation velocities from 0.8 to 0.3 m s^–1 per day. A plausible interpretation is found by assuming the spots to be coupled to a slowly rising subsurface flux tube and a rotation velocity which increases with depth.Mitteilungen aus dem Kiepenheuer-Institut Nr. 201.     

Factors shaping submerged bryophyte communities: A conceptual model for small mountain streams in Germany

Several models explaining species composition of aquatic bryophytes are available for specific regions. However, a more general, conceptual model applicable to a broader range of regions is lacking.We present a conceptual model ranking environmental factors determining submerged bryophyte communities in small mountain streams. It was tested on a dataset of 54 stream sections after removing the effect of stream size and altitude. Species responses were modeled with pH as predictor variable based on 97 stream sites covering six mountain regions all over Germany. Multiple regressions revealed the importance of primary growth factors (light, Ep(CO₂)) and substrate for the total submerged bryophyte coverage.The known distinction of hard- and softwater bryoflora was clearly supported. The floristic composition of headwaters was predominantly determined by the bicarbonate/ionic strength complex. Species response to pH values supported this result and thus our conceptual model. The primary growth resources light, Ep(CO₂) and availability of coarse streambed material explained one third (R_adjusted² = 0.34) of total submerged bryophyte cover. Disturbances, predominantly spates, reduce biomass but do not affect the basic floristic structure.In conclusion, conceptual models and monitoring methods focusing on aquatic bryophytes need to clearly distinguish “aquatic” from “submersed by chance”. All “aquatic bryophytes” found in Germany can also occur at least temporarily at non-submerged sites. Therefore, a distinction between primary growth factors and additional resources is recommended to disentangle factors determining aquatic bryophyte communities.     

NIZUSE: a deep seismic reflection line in north-eastern Germany

Out of a dense network of seismic reflection lines for hydrocarbon exploration in the North-east German Basin, several lines were recorded to 12 s TWT to obtain information about the structure of the crust and the crust-mantle transition. One of these profiles is presented here. This stretches for 110 km in a NNE direction between Neustrelitz and the island of Usedom. It reaches from the External Variscides in the south across the North German Massif into the Rügen-Pomorze Terrane in the Baltic Sea. Below Cenozoic-Mesozoic-Paleozoic cover with clear reflections down to base Zechstein, the reflectivity varies considerably with depth and also laterally. The Paleozoic and Precambrian sediments and basement are generally void of reflections, but the lower crust and the Moho show strong reflections. To the north the reflectivity decreases, and the Moho depth increases to beyond the bottom of the record section at 12 s. There are no direct indications for deep-reaching faults such as the Trans-European Fault in the north. The North German Massif acted as a ramp towards the Variscan Orogeny, similar to the London-Brabant Massif further west.     

The development and structure of nocturnal slope winds in a simple valley

The results of an observational and modeling study of the nocturnal slope winds in a simple valley are presented. The valley was approximately 225 m deep in the region of the measurements, and featured a uniform slope angle of approximately 23 ° on one of its sidewalls. The wind and temperature structure of the katabatic flows on the valley sidewalls were measured with tower-mounted instruments, and a Doppler sodar and instruments on a tethered balloon and a 61-m tower were used to determine the atmospheric conditions near the center of the valley. The temperature structure of the slope flows was summarized by characteristic scale parameters h and T for the inversion depth and strength, respectively. On the sidewalls 50 m above the valley floor, the inversion depths were generally smaller and the inversion strengths were weaker than they were on the sidewalls 100 m higher. These results differ significantly from those obtained over a simple slope of an isolated mountain or ridge. The down-valley winds are shown to be important in limiting the strength of the sidewall inversions. The formation of an inversion in the valley also has a pronounced effect on the structure of the slope flows. Numerical simulations suggest that the presence of adiabatic layers in the valley atmosphere is associated with decreases in the slope-flow inversion depth with increasing downslope distance. The simulations also indicate that the length scales that characterize the momentum and inversion depths behave similarly in flows down simple slopes but not in flows down the sidewalls of a valley.Work supported by the U.S. Army Research Office under Contract DA-AG29-K-0231 and the U.S. Department of Energy under Contract DE-AC06-76RLO 1830.     

K–Ar dating of authigenic minerals in siliciclastic sequences: an example from the south Sanfranciscana Basin (Western Minas Gerais,Brazil)

K–Ar dating was applied on authigenic potassic minerals which are abundant in sandstones from the south of the Sanfranciscana Basin, Western Minas Gerais State, central Brazil. The Quintinos Member fluvial sandstones (Três Barras Formation, Areado Group) contain significant amounts of authigenic K‐feldspar as microcrystals of adularia and sanidine habits. The ages of these microcrystals cluster into three groups: 106.1 ± 2.2, 89.9 ± 1.9 and 88.8 ± 1.8 Ma (from Albian to Coniacian). The older age of 106.1 ± 2.2 Ma was obtained from the coarse fraction analysed (10–20 µm) that can contain a mixture of detrital potassic minerals (K‐feldspar, muscovite, biotite and illite) and different authigenesis of K‐feldspar (overgrowths and microcrystals). Thus, only the younger ages were interpreted as precipitation of K‐feldspar microcrystals during the Late Cretaceous into the Quintinos Member sandstones. Moreover, these ages can document the formation of microcrystals within a few million years after deposition of the sandstones. The ages of authigenic illite from the Capacete Formation epiclastic sandstones (Mata da Corda Group) range from 88.5 ± 1.9 to 71.5 ± 1.9 Ma (Coniacian–Campanian). These results suggest the timing of the illitization event in these sandstones as well as a synchrony with K‐feldspar authigenesis in the Quintinos Member sandstones. These results are well constrained and are in agreement with stratigraphic, biostratigraphic and radiometric ages previously reported for the Sanfranciscana Basin. Copyright © 2014 John Wiley & Sons, Ltd.