Increasing levels and biomagnification of persistent organic pollutants (POPs) in Antarctic biota

Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.     

Quiet-time periods observed by EPHIN/SOHO during the minimum of the 22nd solar cycle

An analysis of the hydrogen and helium isotopic composition from EPHIN data, during the quiet-time period from January 1 to June 1, 1996, is presented. An isotopic discrimination and background rejection have been applied and relationships between the abundances of ²H/¹H, ³He/⁴He, and ⁴He/¹H have been calculated. The energy spectra in the 4–50 MeV nucl^–1 range have been obtained and the contribution of the different spectral components have been analysed in this energy range. We conclude that the main contribution to the ⁴He spectrum is of anomalous origin, while the proton and ³He spectra have contributions mainly from particles of solar origin at low energies and from the galactic cosmic radiation modulated by the heliosphere at high energies. The deuterium spectrum is mainly of galactic origin.     

The development and structure of nocturnal slope winds in a simple valley

The results of an observational and modeling study of the nocturnal slope winds in a simple valley are presented. The valley was approximately 225 m deep in the region of the measurements, and featured a uniform slope angle of approximately 23 ° on one of its sidewalls. The wind and temperature structure of the katabatic flows on the valley sidewalls were measured with tower-mounted instruments, and a Doppler sodar and instruments on a tethered balloon and a 61-m tower were used to determine the atmospheric conditions near the center of the valley. The temperature structure of the slope flows was summarized by characteristic scale parameters h and T for the inversion depth and strength, respectively. On the sidewalls 50 m above the valley floor, the inversion depths were generally smaller and the inversion strengths were weaker than they were on the sidewalls 100 m higher. These results differ significantly from those obtained over a simple slope of an isolated mountain or ridge. The down-valley winds are shown to be important in limiting the strength of the sidewall inversions. The formation of an inversion in the valley also has a pronounced effect on the structure of the slope flows. Numerical simulations suggest that the presence of adiabatic layers in the valley atmosphere is associated with decreases in the slope-flow inversion depth with increasing downslope distance. The simulations also indicate that the length scales that characterize the momentum and inversion depths behave similarly in flows down simple slopes but not in flows down the sidewalls of a valley.Work supported by the U.S. Army Research Office under Contract DA-AG29-K-0231 and the U.S. Department of Energy under Contract DE-AC06-76RLO 1830.     

Chemical and tectonic controls on the formation of sparry magnesite deposits — the deposits of the northern Greywacke Zone (Austria)

The sparry magnesite deposits of the northern Greywacke Zone are situated at the base of thrust sheets. Model calculations and natural examples suggest that an inverse temperature gradient can only be established at the base of a thrust sheet if thrusting is so rapid as to be geologically unrealistic. Independently of this thrusting induces a fluid flow from the lower units to the front of the moving thrust sheet. Stability data of magnesite and dolomite in contact with fluids with different Ca/(Ca+Mg) ratios suggest that this tectonically induced fluid flow produce magnesite from preexisting dolomite by metasomatism.

---

Zusammenfassung Die Spatmagnesitvorkommen der Nördlichen Grauwackenzone liegen innerhalb von Deckengrenzen. Modellberechnungen zeigen, daß ein inverser Temperaturgradient sich nur dann an der Basis von Decken einstellen kann, wenn die Überschiebungsgeschwindigkeit so groß wird, daß sie geologisch unglaubwürdig ist. Deckenüberschiebungen erzeugen aber in jedem Fall in der überschobenen Einheit einen zur Deckenfront hin gerichteten Fluidstrom. Eine Betrachtung der Stabilitätsdaten für Magnesit und Dolomit im Gleichgewicht mit einer fluiden Phase mit unterschiedlichen Ca/(Ca+Mg)-Verhältnissen zeigt, daß durch einen solchen Fluidstrom metasomatisch Magnesit aus Dolomit gebildet werden kann.

---

Résumé Les dépôts de magnésite spathique de la Grauwacken Zone septentrionale sont situés à la base d'unités charriées. Un calcul de modélisation et des exemples naturels montrent qu'un gradient inverse de température ne peut s'établir à la base d'une unité charriée qu'à la condition d'admettre une vitesse de charriage tellement élevée qu'elle est irréaliste. D'autre part, le phénomene de charriage induit un déplacement de fluide depuis les unités inférieures vers le front de la nappe. Les données relatives aux conditions de stabilité de la magnésite et de la dolomite en présence de fluides de divers rapports Ca/Ca+Mg permettent de déduire que le flux ainsi engendré par la tectonique peut engendrer la magnésite par métasomatose à partir de dolomite préexistante.

---

. , , , , . . , Ca/(Ca+Mg) , , , , , , - .

     

Evaluation of the recharge processes and impacts of irrigation on groundwater using CFCs and radiogenic isotopes in the Silao-Romita basin, Mexico

The recharge processes in the overexploited aquifer of the Silao Romita basin, central Mexico, were investigated by means of gaseous tracers (chlorofluorocarbons, CFCs) and radioactive isotopes (C-14, tritium). CFC concentrations varied between 0.06 and 12 pmol/l (CFC-11), 0.03 and 1.7 pmol/l (CFC-12), and <0.01 and 0.23 pmol/l (CFC-113). CFC concentrations are controlled by irrigation return flow which became apparent by the comparison with tritium. Tritium activities ranged from 0 to 3.5 TU. The calculated mean residence times of 70 to more than 300 years are considerably lower than the ages estimated based on the CFCs data. These data showed that CFCs were not appropriate for groundwater dating in this particular area but the CFCs were suitable as a qualitative measure of the magnitude of irrigation return flow which proved to be a significant source of recharge in the irrigated areas. Radiocarbon activities were in the range of 6–109 pmC. Carbon-13 values varied between –11.9 and –7.2‰ VPDB. Modelling of carbon isotopes with NETPATH along a plausible flow path reveals considerable influences of exchange with soil CO₂ and carbonate dissolution. Radiocarbon data indicate, at least in one case, the existence of groundwaters with residence times of more than 10,000 years.     

On the collisional energy transfer between the constituents of the coronal plasma

It has been suggested that the distribution functions characterizing the constituents of the solar coronal plasma are non-Maxwellian. If so, an accurate treatment of the collisional momentum and energy exchange between the plasma constituents within the framework of hydrodynamic models requires a re-evaluation of the general transfer integrals in multi-component plasmas. We have evaluated these integrals numerically for both Maxwellian and non-Maxwellian distribution functions of the plasma species avoiding the standard approximation for the collision cross sections frequently employed in the literature. Significant differences are shown to exist in the energy exchange rates for different distributions. We also demonstrate the inadequacy of the assumption of thermodynamic equilibrium in the innermost solar wind and reveal the importance of an accurate evaluation of the transfer integrals for the solar coronal plasma based on more realistic velocity distributions.Presented at the CESRA-Workshop on Coronal Magnetic Energy Release at Caputh near Potsdam in May 1994.     

Geomagnetische Induktionspfeile in der ČSSR,Hervorgerufen durch Grossräumige Elektrische Leitfähigkeitsstrukturen

Резюме Значительные раэности электропроводности в горизонтальном направлении заставляют индуцируемые ионосферными временными вариациями электрические токи в подстиляющих слоях протекать по преимущественным направлениям. В статье представляются вызванные этим вариации вертикальной и горизонтальной составляющих для периодов 19–40 мун в 20 пунктах в ЧССР, где регистрировались магнитные вариации при помощи полевых регистрирующих станций.

---

---

Mitteilung Nr. 194 des Geomagnetischen Instituts Potsdam.     

Über den Schwermineralgehalt von anstehendem und verwittertem Brockengranit nördlich St. Andreasberg

Zusammenfassung Es wird der Gehalt an durchsichtigen Schwermineralen im anstehenden Granit und seinen Verwitterungsprodukten am Südrand des Brockengranitmassivs nördlich St. Andreasberg quantitativ untersucht.Die Korngrößenverteilung einzelner Schwerminerale im anstehenden und verwitterten Gestein wird angeführt. Dabei werden Rückschlüsse auf ihre mechanische und chemische Stabilität gezogen. und Zirkon hier fast nurmechanisch beeinflußbar sind.Die Verwitterung begünstigt die Bildung von Anatas, Epidot und vielleicht Brookit.Die Ausbildung der beschriebenen Schwermineralfamilie scheint das Ergebnis pneumatolytischer Bildungsbedingungen und hydrothermal-autometamorpher Umwandlung des Granits zu sein und erfährt letztlich eine Wandlung in situ durch die Verwitterung.     

Regional distribution and temporal trends of some contaminants in the water of the Baltic Sea

During a cruise on board RV Gauss in May/June 1988, joint investigations into organochlorine compounds, dissolved trace metals, petroleum hydrocarbons and basic hydrography were carried out at representative stations of the Baltic Monitoring Programme (BMP). The aim of the cruise was to study distribution patterns and — using previous data — to establish temporal trends if at all discernible.Each group of contaminants investigated showed specific characteristics, with differences even between compounds within the same group. The differences are due to:

Observations of Comet 9P/Tempel 1 around the Deep Impact event by the OSIRIS cameras onboard Rosetta

The OSIRIS cameras on the Rosetta spacecraft observed Comet 9P/Tempel 1 from 5 days before to 10 days after it was hit by the Deep Impact projectile. The Narrow Angle Camera (NAC) monitored the cometary dust in 5 different filters. The Wide Angle Camera (WAC) observed through filters sensitive to emissions from OH, CN, Na, and OI together with the associated continuum. Before and after the impact the comet showed regular variations in intensity. The period of the brightness changes is consistent with the rotation period of Tempel 1. The overall brightness of Tempel 1 decreased by about 10% during the OSIRIS observations. The analysis of the impact ejecta shows that no new permanent coma structures were created by the impact. Most of the material moved with . Much of it left the comet in the form of icy grains which sublimated and fragmented within the first hour after the impact. The light curve of the comet after the impact and the amount of material leaving the comet ( of water ice and a presumably larger amount of dust) suggest that the impact ejecta were quickly accelerated by collisions with gas molecules. Therefore, the motion of the bulk of the ejecta cannot be described by ballistic trajectories, and the validity of determinations of the density and tensile strength of the nucleus of Tempel 1 with models using ballistic ejection of particles is uncertain.