Intrusion of igneous rocks — Physical aspects

Igneous rocks occur in two predominant modes. The plutonic mode is characterized by intrusive emplacement under compressional tectonic stress regimes. The volcanic mode is dominated by the eruption of large volumes of magma through fault controlled dyke structures in extensional tectonic stress regimes.Those typical intrusive phenomena are discussed in the light of the physical parameters like the dynamic-thermal regime of the lithosphere, the nature and source of buoyant forces as well as mechanical aspects of subsolidus flow of rocks.Twodimensional numerical models on the basis of typical parameter specifications and by means of a coupled dynamic-thermal physical approximation are presented. The simulation of buoyantly-driven diapiric intrusions has been adopted to derive parameters which are critically controlling the transport and emplacement of intrusion under surroundings of variable viscosity. Both sill-type and batholith-type structures are presented and discussed with respect to their predominant dependence on mechanical and physical conditions.

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Zusammenfassung Magmatische Gesteine treten in zwei vorherrschenden Erscheinungsformen auf. Die Plutonite sind charakterisiert durch eine intrusive Platznahme unter kompressiven tektonischen Spannungsbedingungen. Die Vulkanite werden beherrscht von gro\en Volumina eruptierten Magmas, das vorzugsweise durch weiträumige Bruchsysteme unter Zugspannungsbedingungen aufsteigt.Derartige magmatische Phänomene werden aus der Sicht physikalischer Parameter wie dynamisch-thermische Bedingungen der Lithosphäre, der Natur und des Ursprungs von Auftriebskräften sowie der Mechanik von Gesteinsformationen diskutiert.Es werden zweidimensionale numerische Modellrechnungen auf der Grundlage typischer Parameterbereiche vorgestellt. Die Rechnungen basieren auf einer dynamisch-thermischen Approximation von Flie\vorgängen. Sie werden eingesetzt zur Untersuchung von diapirartigen Intrusionsvorgängen, die durch Dichteinversionen angetrieben sind. Hierbei sollen die Parameter bestimmt werden, die Aufstieg und Platznahme der Intrusionen bestimmen. Die Umgebung ist charakterisiert durch eine vorgebbare variable Viskosität. Sowohl linsenförmige Sill-Strukturen als auch typische Batholith-Strukturen werden mathematisch simuliert. Ihr Zusammenhang mit den strukturbestimmenden Parametern wird aufgezeigt.

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Résumé Les roches magmatiques se répartissent en deux catégories principales: la catégorie plutonique est caractérisée par une mise en place dans des régimes de contraintes tectoniques compressives; la catégorie volcanique est dominée par l'éruption de volumes importants de magma à travers des systèmes de cassures dans des régimes de contraintes tectoniques d'extension.Ces phénomènes intrusifs sont discutés à la lumière de paramètres physiques tels que: le régime thermique et dynamique de la lithosphère, la nature et l'origine des forces ascensionnelles, ainsi que les aspects mécaniques du fluage sub-solidus des roches.Les auteurs présentent des modèles numériques bidimensionnels basés sur des domaines paramétriques typiques, au moyen d'une approximation dynamo-thermique de phénomène d'écoulement. La simulation d'intrusions diapiriques permet de déduire les paramètres qui déterminent le transport et la mise en place d'une intrusion dans diverses conditions de viscosité de l'encaissant. Les structures de type sill et de type batholite sont discutées en relation avec les conditions mécaniques et physiques dont elles dépendent.

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Sodic Pyroxene and Sodic Amphibole as Potential Reference Materials for In Situ Lithium Isotope Determinations by SIMS

Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilímaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro‐drilled material analysed by MC‐ICP‐MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 ± 51 μg g^?1 (2s, n = 69, MC‐ICP‐MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 ± 3.6 μg g^?1 (2s, n = 33) as determined by SIMS. The seven micro‐drilled regions measured by solution MC‐ICP‐MS returned slightly lower concentrations (41–46 μg g^?1), but still overlap with the SIMS data within uncertainty. Based on MC‐ICP‐MS and SIMS analyses, the variation in δ⁷Li was about 1‰ in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC‐ICP‐MS and SIMS. The latter deviated from the MC‐ICP‐MS results by ?6.0 ± 1.9‰ (2s) for the amphibole and by ?3.9 ± 1.9‰ (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC‐ICP‐MS results, mean δ⁷Li values of +0.7 ± 1.2‰ (2s, n = 10) for the arfvedsonite crystal and of ?3.7 ± 1.2‰ (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.     

Macroscopic representation of structural geometry for simulating water and solute movement in dual-porosity media

The structure of macroporous or aggregated soils and fractured rocks is generally so complex that it is impractical to measure the geometry at the microscale (i.e., the size and the shape of soil aggregates or rock matrix blocks, and the myriad of fissures or fractures), and use such data in geometry-dependent macroscale flow and transport models. This paper analyzes a first-order type dual-porosity model which contains a geometry-dependent coefficient, β, in the mass transfer term to macroscopically represent the size and shape of soil or rock matrix blocks. As a reference, one- and two-dimensional geometry-based diffusion models were used to simulate mass transport into and out of porous blocks of defined shapes. Estimates for β were obtained analytically for four different matrix block geometries. Values for β were also calculated by directly matching analytical solutions of the diffusion models for a number of selected matrix block geometries to results obtained with the first-order model assuming standard boundary conditions. Direct matching improved previous results for cylindrical macropore geometries, especially when relatively small ratios between the outer soil mantle and the radius of the inner cylinder were used. Results of our analysis show that β is closely related to the ratio of the effective surface area available for mass transfer, and the soil matrix volume normalized by the effective characteristic length of the matrix system. Using values of β obtained by direct matching, an empirical function is derived to estimate macroscopic geometry coefficients from medium properties which in principle are measurable. The method permits independent estimates of β, thus allowing the dual-porosity approach eventually to be applied to media with complex and mixed types of structural geometry.     

The development and structure of nocturnal slope winds in a simple valley

The results of an observational and modeling study of the nocturnal slope winds in a simple valley are presented. The valley was approximately 225 m deep in the region of the measurements, and featured a uniform slope angle of approximately 23 ° on one of its sidewalls. The wind and temperature structure of the katabatic flows on the valley sidewalls were measured with tower-mounted instruments, and a Doppler sodar and instruments on a tethered balloon and a 61-m tower were used to determine the atmospheric conditions near the center of the valley. The temperature structure of the slope flows was summarized by characteristic scale parameters h and T for the inversion depth and strength, respectively. On the sidewalls 50 m above the valley floor, the inversion depths were generally smaller and the inversion strengths were weaker than they were on the sidewalls 100 m higher. These results differ significantly from those obtained over a simple slope of an isolated mountain or ridge. The down-valley winds are shown to be important in limiting the strength of the sidewall inversions. The formation of an inversion in the valley also has a pronounced effect on the structure of the slope flows. Numerical simulations suggest that the presence of adiabatic layers in the valley atmosphere is associated with decreases in the slope-flow inversion depth with increasing downslope distance. The simulations also indicate that the length scales that characterize the momentum and inversion depths behave similarly in flows down simple slopes but not in flows down the sidewalls of a valley.Work supported by the U.S. Army Research Office under Contract DA-AG29-K-0231 and the U.S. Department of Energy under Contract DE-AC06-76RLO 1830.     

Eh ph Diagrams for mn, fe, co, ni, cu and as Under Seawater Conditions: Application of two new Types of eh ph Diagrams to the Study of Specific Problems in Marine Geochemistry

E_H pH diagrams have been calculated using the PHREEQC programme in order to establish the predominance fields of Mn, Fe, Co, Ni, Cu and As in bottom waters from the Angola Basin. Predominance fields are presented separately for both aquatic species and solid mineral phases in order to simplify interpretation of the data. The diagrams show significant differences from standard E_H pH diagrams for these elements calculated for freshwater at 25 °C and 1 bar which assume an element concentration of 10^-6 M. In particular, our diagrams show that Mn²⁺ and NiCO ₃ ⁰ are the predominant aquatic species for Mn and Ni in bottom seawater and FeOOH, Fe₂O₃, Fe₃O₄, CoFe₂O₄, CuFe₂O₄, CuFeO₂, and Ba₃ (AsO₄)₂ the predominant solid phases for Fe, Co, Cu and As, respectively. Mn and Ni are therefore undersaturated and Fe, Co, Cu and As supersaturated in bottom seawater from the Angola Basin. Neither rhodochrosite (MnCO₃) nor siderite (FeCO₃) can form in this marine environment in equilibrium with seawater. A mixed Mn-Ca carbonate is therefore formed within the pore waters of reducing sediments. The high Ni/Cu ratios in cobalt-rich manganese crusts formed adjacent to the oxygen minimum zone may be explained by the change from Cu²⁺ to CuCl ₃ ^2- as the dominant aquatic species of Cu in seawater at an E_H of +0.48 V.     

K–Ar dating of authigenic minerals in siliciclastic sequences: an example from the south Sanfranciscana Basin (Western Minas Gerais,Brazil)

K–Ar dating was applied on authigenic potassic minerals which are abundant in sandstones from the south of the Sanfranciscana Basin, Western Minas Gerais State, central Brazil. The Quintinos Member fluvial sandstones (Três Barras Formation, Areado Group) contain significant amounts of authigenic K‐feldspar as microcrystals of adularia and sanidine habits. The ages of these microcrystals cluster into three groups: 106.1 ± 2.2, 89.9 ± 1.9 and 88.8 ± 1.8 Ma (from Albian to Coniacian). The older age of 106.1 ± 2.2 Ma was obtained from the coarse fraction analysed (10–20 µm) that can contain a mixture of detrital potassic minerals (K‐feldspar, muscovite, biotite and illite) and different authigenesis of K‐feldspar (overgrowths and microcrystals). Thus, only the younger ages were interpreted as precipitation of K‐feldspar microcrystals during the Late Cretaceous into the Quintinos Member sandstones. Moreover, these ages can document the formation of microcrystals within a few million years after deposition of the sandstones. The ages of authigenic illite from the Capacete Formation epiclastic sandstones (Mata da Corda Group) range from 88.5 ± 1.9 to 71.5 ± 1.9 Ma (Coniacian–Campanian). These results suggest the timing of the illitization event in these sandstones as well as a synchrony with K‐feldspar authigenesis in the Quintinos Member sandstones. These results are well constrained and are in agreement with stratigraphic, biostratigraphic and radiometric ages previously reported for the Sanfranciscana Basin. Copyright © 2014 John Wiley & Sons, Ltd.     

Vulkanismus und Graben-Bildung im Roten Meer

Zusammenfassung Von Vulkanit-Proben derValdivia-Kampagnen 1971/72 werden die Ergebnisse petrographischer und chemischer Untersuchungen dargestellt. Im zentralen Graben des Roten Meeres sind Olivin-Tholeiit-Baselte ohne modalen Pyroxen verbreitet. Außerhalb des zentralen Grabens treten neben vorwiegend holokristallinen Pyroxen-führenden Olivin-Tholeiit-Basalten Alkali-Basalte sowie basaltische Tuffe und Hyaloklastite auf. Vergleichsweise wurden Basalte und deren saure Differentiate aus dem Hinterland von Djibouti untersucht. Kristallisations- und Differentiationsgrad der Gesteine sind Abbild eines diapirartig aufgestiegenen Asthenolithen. Die Aufwölbung der Asthenosphäre wird durch die Einsenkung eines Scheitelgrabens kompensiert. Eine Trennung der kontinentalen Kruste betrifft nur den Bereich des zentralen Grabens.

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During theValdivia cruise 1971/72 volcanic fragments were raised from the bottom of the Red Sea, especially from the axial through. Data on petrography and chemistry are represented. The axial trough is floored with olivine-tholeiitic basalts without modal pyroxene. According to the rapid ascent from relatively shallow depth olivinetholeiitic magma reached the sea-floor before any substantial differentiation took place. Beyond the axial trough alkali-basalts, basaltic tuffs, hyaloklastites are distributed as well as olivine-tholeiitic basalts with modal pyroxene. For comparison basalts and their acid differentiates from the hinterland of Djibouti have been analyzed and discussed. The grade of crystallisation and fractionation of the melt is in a direct connection with the diapiric upwelling of the asthenosphere. The upwarped asthenosphere is compensated by normal faulting and rifting of the axial trough. The attenuation and separation of the continental crust is restricted to the axial trough.

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Résumé Pendant les campagnes de laValdivia en 1971/72, des échantillons de volcanites ont été prélevés au fond de la Mer Rouge, à des fins d'analyses pétrographiques et chimiques. Dans le fossé central il y a des basaltes tholéiitiques à olivine sans pyroxène modal. En dehors du fossé central apparaissent des basaltes alcalins, des tufs basaltiques et des hyaloclastites ainsi que des basaltes tholéiitiques à olivine et pyroxène modal prédominemment holocristallins. A titre de comparaison, des basaltes et leurs différenciats acides, prélevés dans le hinterland de Djibouti, ont été analysés. Le degré de cristallisation et de différenciation des roches est en relation avec l'asténolite monté par voie diapirique. Le bombement de l'asténosphère est compensé par l'enfoncement du fossé. La séparation de la croûte continentale est restreinte au fossé axial.

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Herrn Dr. H.Bäcker von derPreussag AG, Hannover, danken wir für dieÜberlassung des Proben-Materials und für das Einverständnis zur Publikation. Wir danken unseren Kollegen A.Baumann, Braunschweig, und H.Raschka, BfB Hannover, für die Bestimmung der Schwermetall- und Spurenelement-Gehalte sowie den Herren H.Pichler, Tübingen, und A.Schneider, Göttingen, für die Norm-Berechnungen.     

Methane emission measurements in urban areas in Eastern Germany

We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m²/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.     

Stratigraphische Untersuchungen im Paläozoikum des Montseny (Katalonien/Spanien)

The Catalonian Coast Bange and Inner Bange are the connecting link between the East-Pyrenees in the North and the Celtiberic Chains in the Southeast. During the Paleozoic the Catalonian Ranges differ from both areas by extreme eugeosynclinal conditions with very low rates of sedimentation. Similar conditions in the Hercynian of Spain are to be found in the “pelagic” areas of the southwestern part of the Sierra Morena from upper Ordovician to Lower Carboniferous times. Based on the mapping of the Avencó-Valley (a part of the Montseny-Mountains/Catalonia) the Paleozoic layers are described and a stratigraphic subdivision is worked out. The conformable sequence begins in the upper Ordovician (Caradoc) and continues to the Visean. Buntsandstein is unconformably overlying the Paleozoic. The Ordovician/Silurian boundary is determined by Graptolithes; the Silurian/Devonian boundary is located within a sequence of Orthoceras-limestone as elsewhere in the Catalonian Range. For lack of fossils the Devonian/Carboniferous boundary is not clearly defined; instead a lithologic boundary was used. Special stress has been laid upon sedimentary structures.