通过对太白山三清池湖泊沉积柱芯的低频磁化率(χlf)、频率磁化率(χfd)、总有机碳(TOC)、粒度参数指标的时序序列进行小波分析,探讨太白山全新世气候变化过程及周期波动性.结果显示:中、晚全新世太白山气候变化具有明显的阶段性特征;千年尺度上,χlf、χfd、TOC和平均粒径参数序列反映的主周期分别为1427、1427、1427和1452 a,晚全新世5410 cal a B.P.距今期间存在8次显著的冷暖交替震荡;在百年尺度上,χlf、χfd、TOC和平均粒径参数序列还揭示出分别以492、492、467和467 a为周期的次一级变化,且整体上经历近似10次的短期冷暖波动.此外,以上结果与全球范围内全新世气候周期有着较好的一致性,表明我国东部高海拔地区在千年和百年尺度上,对全新世气候振荡同样具有相似的响应. 相似文献
The phase behavior of fluid is essential for predicting ultimate oil recovery and determining optimal production parameters. The pore size in shale porous media is nanopore, which causes different phase behaviors of fluid in unconventional reservoirs. Nanopores in shale media can be regard as semipermeable membrane to filter heavy components (sieving effect) in shale oil, which leads to the different distributions of fluid components and different phase behaviors. In addition, the phase behavior of fluid in nanopores can be significantly altered by large capillary pressure. In this paper, the phase behavior of fluid in shale reservoirs is investigated by a new two-phase flash algorithm considering sieving effect and capillary pressure. Firstly, membrane efficiency and capillary pressure are introduced to establish a thermodynamic equilibrium model that is solved by Rachford–Rice flash calculation and Newton–Raphson method. The capillary pressures in different pore sizes are calculated by the Young–Laplace equation. Then, the influences of sieving effect and capillary pressure on phase behavior are analyzed. The results indicate that capillary pressure can suppress the bubble point pressure of fluid in nanopores. The distributions of fluid components are different in various parts of shale media. In the unfiltered part, density and viscosity of fluid are higher. Finally, it is found that the membrane efficiency can be improved by CO2 injection. The minimum miscibility pressure for shale oil–CO2 system is also studied. The developed model provides a better understanding of the phase behavior of fluid in shale oil reservoirs.