Chemical composition of rock-forming minerals and crystallization physicochemical conditions of the Middle Eocene I-type Haji Abad pluton,SW Buin-Zahra,Iran

The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe³⁺?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H₂O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent.     

柴达木盆地东部烃源岩的生源与沉积环境

用色谱-质谱、稳定同位素质谱等分析测试技术，对柴达木盆地东部地区寒武系、奥陶系、泥盆系、石炭系和侏罗系岩样进行地球化学特征分析。从饱和烃生物标志化合物特征、正构烷烃单体碳同位素分布特征等方面入手，对该区的烃源岩的生源与沉积环境作了详细研究。结果表明，柴达木盆地东部地区古生界有机质多为菌、藻类生源，少数有陆源有机质混入（主要是石炭系）。有机质多为强还原环境的海相沉积，少数为海陆过渡相沉积。侏罗系在一些地区和层段并非典型的成煤环境，而是属于滨浅湖相，少数为半深湖-深湖环境，因此具有一定的生烃能力。     

河北秦皇岛斑鬣狗巢穴(灵仙洞)及斑鬣狗的集群死亡与埋藏

河北省秦皇岛灵仙洞发现了一批最后斑鬣狗化石,标本达上千件,至少代表了30个不同个体,包括3具骨架(其中骨架Ⅰ是世界上迄今所发现最完整的1具),还发现了一些其他哺乳动物化石,共计26属27种.根据动物群组成、地质地貌以及堆积物的综合分析判断,它的时代可能属于中更新世晚期至晚更新世早期.动物群的生态组合反映当时处于一个温热偏干、半封闭或开阔的山间草原而周边山上有树林的生态环境.标本(尤其是完整骨架)的保存为典型的原地埋藏,死后未受到包括斑鬣狗自身在内的动物干扰和破坏.斑鬣狗在动物群中占绝对优势以及幼年个体和粪化石的发现,表明灵仙洞是一处斑鬣狗族群的巢穴.与其他斑鬣狗巢穴不同的是:斑鬣狗的猎物稀少,鲜见斑鬣狗的活动痕迹,尤其是幼年斑鬣狗啃咬形成的特定产物“nibbling sticks”,这说明灵仙洞既非用于猎物遗骸的储藏,也非用于幼崽的抚养,而是一处共用巢穴,同时也表明灵仙洞的骨骼聚集与埋藏有着特定的成因和机理.     

Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

Glauconites from the Late Palaeocene — Early Eocene Naredi Formation,western Kutch and their genetic implications

Glauconitic minerals are considered as one of the valuable input parameters in sequence stratigraphic analysis of a basin. In the present study glauconitic minerals are reported from subtidal green shale facies in the lower part of the Late Paleocene-Early Eocene Naredi Formation of western Kutch. On the basis of the foraminiferal assemblage the glauconite bearing beds are interpreted to have formed in a mid shelf depositional settings of an unstable marine conditions. XRD studies confirm the glauconite mineralogy of the green pellets and provide an estimation of glauconite maturity. Textural attributes of the glauconites confirm their derivation by different degrees of alteration of precursor feldspar grains. Because of the authigenic origin and autochthonous nature, these glauconites hold promise for understanding sequence stratigraphy of the Palaeogene succession of the western Kutch.     

辽吉东部层状混合岩的成因

辽吉东部的层状混合岩与上、下围岩始终保持整合接触,反映它的体系基本上是封闭的,没有外来组份的加入。其组构、岩石化学、微量元素和稀土资料等表明层状混合岩不足岩浆型的,而是重熔岩浆型的,其原岩是沉积变质岩。     

The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

The Influence of Chlorine on the Determination of Combined Water: An Investigation of a Correction Procedure

Differential thermal analysis, pH determination and ion chromatography were used to investigate the interference of chlorine in the determination of combined water (H₂O⁺) by the Penfield tube gravimetric method. The magnitude of the chlorine interference was quantified and a correction method was proposed to obtain accurate results for H₂O⁺. The method was applied to the determination of H₂O⁺ in deep sea sediments containing chlorine and certified reference materials of oceanic polymetallic nodules.     

桥梁气象专题研究与服务

根据实际开展的桥梁气象专题研究，分析桥梁气象研究与服务如何面对国内大型桥梁建设发展趋势所带来的机遇和挑战，提出开展桥梁气象研究与服务的必要性，并从桥位气候背景、桥位气象参数取值、桥梁气象研究方法以及桥梁施工及营运期气象服务与保障等方面介绍桥梁气象专题研究及服务应开展的主要内容，同时，给出一个已投入实际使用的桥梁施工期气象环境监测与预警系统的建设思路。     

多普勒雷达基本观测量直接同化对模式物理量场的影响

在GRAPES一3DVar雷达同化模块的基础上,建立了多普勒径向速度和基本反射率因子的直接同化观测算子,实现了雷达反射率因子和径向速度的直接同化,并对2007年7月3日的江淮梅雨进行了模拟试验。结果表明,多普勒径向速度的直接同化的主要影响表现在风场上,能够改善几乎整个三维风场分析,在雷达影响半径范围内,风场明显得到加强,影响当时天气的系统及其高低层配置被合理模拟,但对湿度场影响甚微。雨水混合比的直接同化的主要影响表现在湿度场上,改进了模式对湿度场的模拟,对降水的影响十分显著,有利于准确模拟降水的发展和维持,减小了Spin—up现象;其亦可使整个风场微弱增强,但影响甚微。