∼3,850 Ma tonalites in the Nuuk region,Greenland: geochemistry and their reworking within an Eoarchaean gneiss complex

The Eoarchaean (>3,600 Ma) Itsaq Gneiss Complex of southern West Greenland is dominated by polyphase orthogneisses with a complex Archaean tectonothermal history. Some of the orthogneisses have c. 3,850 Ma zircons, and they vary from rare single phase metatonalites to more common complexly banded migmatites. This is due to heterogeneous strain, in situ anatexis and granitic veining superimposed during younger tectonothermal events. In the single-phase tonalites with c. 3,850 Ma zircon, oscillatory-zoned prismatic zircon is all 3,850 Ma old, but shows patchy ancient loss of radiogenic Pb. SHRIMP spot analyses and laser ablation ICP-MS depth profiling show that thin (usually < 10 μm) younger (3,660–3,590 Ma and Neoarchaean) shells of lower Th/U metamorphic zircon are present on these 3,850 Ma zircons. Several samples with this simple zircon population occur on islands near Akilia. In contrast, migmatites usually contain more complex zircon populations, with often more than one generation of igneous zircon present. Additional zircon dating of banded gneisses across the Complex shows that samples with c. 3,850 Ma igneous zircon are not just a phenomenon restricted to Akilia and adjacent islands. For example, migmatites from Itilleq (c. 65 km from Akilia) contain variable amounts of oscillatory-zoned 3,850 Ma and 3,650 Ma zircon, interpreted, respectively, as the rock age and the time of crustal melting under Eoarchaean metamorphism. With only 110–140 ppm Zr in the tonalites and likely magmatic temperatures of >850°C, zircon solubility–melt composition relationships show that they were only one-third saturated in zircon. Any zircon entrained in the precursor magmas would thus have been highly soluble. Combined with the cathodoluminesence imaging, this demonstrates that the c. 3,850 Ma oscillatory zoned zircon crystallised out of the melt and hence gives a magmatic age. Thus the rare well-preserved tonalites and palaeosome in migmatites testify that c. 3,850 Ma quartzo–feldspathic rocks are a widespread (but probably minor) component in the Itsaq Gneiss Complex. C. 3,850 Ma zircon with negative Eu anomalies (showing growth in felsic systems) also occurs as detrital grains in rare c. 3,800 Ma metaquartzites and as inherited grains in some 3,660 Ma granites (sensu stricto). These demonstrate that still more c. 3,850 Ma rocks were present, but were recycled into Eoarchaean sediments and crustally derived granites. The major and trace element characteristics (e.g. LREE enrichment, HREE depletion, low MgO) of the best-preserved c. 3,850 Ma rocks are typical of Archaean TTG suites, and thus argue for crust formation processes involving important contributions from melting of hydrated mafic crust to the earliest Archaean. Five c. 3,850 Ma tonalites were selected as the best preserved on the basis of field criteria and zircon petrology. Four of these samples have overlapping initial ɛ_Nd (3,850 Ma) values from +2.9 to +3.6± 0.5, with the fourth having a slightly lower value of +0.6. These data provide additional evidence for a markedly LREE-depleted early terrestrial mantle reservoir. The role of c. 3,850 Ma crust should be considered in interpreting isotope signatures of the younger (3,800–3,600 Ma) rocks of the Itsaq Gneiss Complex. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Soil moisture dynamics under different land uses on karst hillslope in northwest Guangxi,China

Temporal and spatial dynamics of soil moisture are little known on karst hillslope with shallow soil in subtropical region. The objectives of this paper were (1) to investigate the temporal dynamics of soil moisture at depth of 0–10 cm under different land uses; and (2) to understand the relationship between mean and coefficient of variation (CV) of moisture contents on karst hillslope in northwest Guangxi, China. Soil moisture contents had a moderate variation (CV 17.5–30.3%) over an 8-month period and they had a significant difference among different land uses at the 0.01 level with a decreasing order: native scrubland > abandoned cropland and sloping cropland > economic forestland. There were higher mean and lower CV of moisture contents in rainy season than those in drought season. Mean and CV of moisture contents had a significant negative linear relationship except in abandoned cropland with higher soil and vegetation heterogeneity. This suggested that spatial variability of soil moisture within sampling sites would decrease when soils were wet and increase when soils were arid. Compared with rainy season, more soil samples may be needed and the interval for sampling should be shortened in drought season. Such information provided some insights to better understand the dynamics and variability of soil moisture at a larger scale in karst region of southwest China.     

An approximate analytical solution for measuring air permeability of asphalt samples partially saturated with water

In coastal areas, abnormally high pressure may be caused by the tide-induced water table variation under extensive pavements, particularly during rainfall. To simulate the rainfall infiltration effects on the air permeability of asphalt pavements in coastal area, column-shaped asphalt sample was fixed in the upper part of a steel cylinder with its upper surface saturated with ponding water (depth < 5 mm) and open to the atmosphere. The cylinder’s lower part formed an air chamber. The chamber was pressurized and then the air therein was released naturally through the sample. The pressure variation with time in the chamber was recorded for analysis. Based on the Green–Ampt piston model for the surface water infiltration, an approximate analytical solution was derived to describe the pressure–time relationship in the chamber. A new parameter called the escape pressure was introduced to describe the air pressure needed for the chamber air to break through the capillary pressure induced by the ponding water. The analytical solution gave good estimations of both the escape pressures and the harmonic averages of the permeabilities of the wet and dry parts of 14 samples in the sense that excellent fittings were obtained between the observed and predicted air pressures in the air chamber. The estimated escape pressure ranges from 0.0 to 1.74 kPa. The harmonic average of the permeabilities of the wet and dry parts is 5–94% of the dry sample’s permeability.     

Local dynamical equivalence of certain food webs

An important challenge in theoretical ecology is to find good coarse-grained representations of complex food webs. Here, we use the approach of generalized modeling to show that it may be possible to formulate a coarse-graining algorithm that conserves the local dynamics of the model exactly. We show examples of food webs with a different number of species that have exactly identical local bifurcation diagrams. Based on these observations, we formulate a conjecture governing which populations of complex food webs can be grouped together into a single variable without changing the local dynamics. As an illustration, we use this conjecture to show that chaotic regions generically exist in the parameter space of a class of food webs with more than three trophic levels. While our conjecture is at present only applicable to relatively special cases, we believe that its applicability could be greatly extended if a more sophisticated mapping of parameters were used in the model reduction.     

Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.     

Direct and Indirect Validation of Potential Fishing Zone Advisory off the Coast of Uttara Kannada,Karnataka

The technique of predicting Potential Fishing Zone using satellite derived sea surface temperature and chlorophyll is becoming an important aspect for the fishermen. In the present study an attempt has been made to compare fish density/catch per unit effort in the areas predicted by Satellite imagery and available to fishermen via electronic display boards at the fish landing centers of Uttara Kannada district, Karnataka with those of non predicted areas. Direct and Indirect validation was done. Direct method means comparing the catch using fishing vessels simultaneously in the notified region with that of catch from non notified region. And in indirect method by comparing catch data from landing centers on notified days with that of non notified days. Direct validation off Karwar showed that catch was significantly higher in notified (PFZ) area with high densities as compared to non notified (non PFZ) regions. When comparisons of landing center data of Karwar, Tadadi and Bhatkal are done it is evident that in all the centers during the period under study, higher catches were observed on notified days than non notified days except in Bhatkal centre in 2009–10. There by validating the accuracy of PFZ predictions and economic gains to fishermen.     

Stratigraphic relations and habitat of the Bende fish teeth,southeastern Nigeria

The age and habitat of the Bende fish fossils have remained a matter of controversy with interpretations ranging between the Paleocene Imo Formation and the Eocene Ameki Formation. Outcrop-based sequence stratigraphic analysis presented in this work shows that the Imo and Ameki Formations together include three laterally extensive estuarine central basin/offshore mud rock units that are associated with the 59.7, 58.1, and the 56.8 ma maximum flooding surfaces, respectively. Field evidence and stratigraphic analysis show that the Bende fossil bones are hosted by the mud rock unit containing the 58.1 ma maximum flooding surface, while the Ameke bone fossils are contained within the condensed section associated with the 56.8 ma maximum flooding surface. Apart from highlighting the relevance of sequence stratigraphy in paleobiological interpretations, this study shows that the Bende fish fauna which Arua first assigned to the Eocene Ameki Formation indeed belongs to the Paleocene Imo Formation.     

Spatial and temporal variability of mesozooplankton and tintinnid ciliates in a seasonally hypersaline estuary

The zooplankton community of Mission Bay, San Diego, California, was monitored over two years, to study spatial and temporal patterns and the response of zooplankton species composition to environmental variation. Data were collected every two weeks from six stations and included hydrographic parameters, dissolved nutrient concentrations, and phytoplankton and zooplankton species composition. Hydrography varied seasonally, along a spatial gradient from the mouth to the back of the bay, and between the two years around the influence of rainfall. Spatially, Mission Bay could be divided into three regions during this study based on hydrography and zooplankton species composition. Zooplankton species composition followed a predictable seasonal progression, with different groups of species being characteristic to particular times of the year. Variability in zooplankton species composition was also evident between years, as certain species were more common in one or the other year of the study. Spatial patterns were more consistent than temporal ones, and related to distance from the mouth of the bay during much of the year and distance from freshwater inlets during the relatively short rainy season. Multivariate analysis revealed that variation in zooplankton species composition was best related to measured abiotic factors (temperature, salinity, rainfall, and tidal velocity).     

Flow and transport predictions during multi-borehole tests in fractured chalk using discrete fracture network models

Multi-borehole pumping and tracer tests on the 10 to 100-m scale were conducted in a fractured chalk aquitard in the Negev Desert, Israel. Outcrop and core fracture surveys, as well as slug tests in packed-off intervals, were carried out at this site to obtain the parameters needed for construction of a stochastic discrete fracture network (DFN). Calibration of stochastic DFNs directly to the multiple borehole test data was inadequate. Instead, two equivalent deterministic DFN flow models were used: the vertical-fractures (VF) model, consisting of only vertical fractures, and the fractures’ intersections (INT) model, consisting of vertical and horizontal fractures with enhanced transmissivity at their intersections. Both models were calibrated against the multi-borehole response of one pumping test and their predictions were tested against three other independent pumping tests. The average accuracies of all transient drawdown predictions of the VF and INT models were 65 and 66%, respectively. In contrast to this equality in average drawdown predictions of both models, the INT model predicted better important breakthrough curve features (e.g., first and peak arrival times), than the VF model. This result is in line with previously assumed channeled flow, derived from analytical analysis of these pumping and tracer tests. Ronit Nativ, deceased, may her memory be blessed.     

Numerical simulation of physical and dynamical characteristics associated with the severe thunderstorm on April 5, 2015 at Kushtia and Jhenaidah

The paper deals with the study of the physical and dynamical characteristics of a severe thunderstorm, which had occurred on April 5, 2015, at about 2100 UTC in the southwestern Bangladesh with location around 23.3–23.7N and 89.0–89.4E within the upazilas (sub-districts) of Kumarkhali and Shailkupa under the districts of Kushtia and Jhenaidah, respectively. The thunderstorm was associated with numerous hails of large size. More than 5000 birds which used to live in the bird sanctuary at Shailkupa and 22,011 birds in Chhaglapara Bird Sanctuary of Kumarkhali died as they were hit by the hails. Large hails also damaged crops, houses and forests over the thunderstorm hit areas. The evolution of the thunderstorm is studied by the WRF model, which is initialized using the National Centers for Environmental Prediction Final reanalysis data of 0000 UTC of April 5, 2015. The simulated results provide a basis to study the physical and dynamical characteristics of the thunderstorm, which are generally not identified by the meteorological observations which are too sparse. The model has captured a micro-low over Kumarkhali and its neighborhood, which favored the occurrence of the severe thunderstorm. The model simulated rainfall is about 26 mm near the place of occurrence, which matches well with the area where the reflectivity of hydrometeor is maximum. The convective available potential energy is found to be 1600 J kg^?1 at 1730 UTC near the place of occurrence of the thunderstorm; this indicates high atmospheric instability over the thunderstorm location for the formation of the thunderstorm. The vertical velocity, convergence, cloud water mixing ratio and the ice water mixing ratio and their vertical extensions are found to be satisfactory and responsible for the occurrence of large hails associated with the thunderstorm.