Migration Fractionation of Neutral Nitrogen Compounds of Crude Oils from Tabei Oilfield in the Tarim Basin, China

The absolute amounts and relative distributions of neutral nitrogen compounds in the Tabei oilfield (e. G. Blocks Ln1-Ln1 1) showed remarkable migration fractionation in the vertical direction. From Ordovician reservoirs (O) to oil legs TⅢ and T Ⅰ of Triassic reservoirs in blocks LN1-LN11, the concentrations of [a] [c] decreased from 1. 59μg/g, 0.49μg/g to 0.17 μg/g (oil). The ratios of various alkylcarbazole isomers, such as 1,8-dimethylcarbazole/nitrogenpartially shielded isomers and 1,8-dimethylcarbazole/nitrogen-exposed isomers, were adopted as the indicators of petroleum migration. The ratios increased from 0.13, 0.20 to 0.67 and from going from the south to the north of the Tabei oilfield, the absolute concentrations of neutral nitrogen compounds decreased drastically, and the nitrogen-shielded isomers were enriched relative to nitrogen-exposed isomers and nitrogen-partially shielded isomers. Crude oils in the Tabei oilfield migrated laterally from the Jilake structure to the Sangtamu fault uplift and Lunnan fault uplift, and crude oils in the same fault uplift migrated and remigrated vertically from Ordovician reservoirs, to oil legs TⅢ to TⅠ of Triassic reservoirs.     

Geochemical Evidence for Coal and Carbonaceous Mudstone as the Possible Major Oil Source Rock in the Jurassic Turpan Basin,Northwest China

Petroleum geologists have debated whether the hydrocarbons from Jurassic coal measures are derived from the coals, carbonaceous mudstones or coal-measure mudstones in the Turpan Basin. Based on the geochemistry analysis of the 20 crude oils and 40 source rocks from the Turpan Basin, some data have been obtained as follows: carbon preference index and methylphenanthrene index of the Jurassic oils are 1.16–1.45 and 0.28–0.80, and the ααα C29 sterane 20S/(20S+20R) and C29 sterane ββ/(ββ+αα) are 0.44–0.51 and 0.4–0.54 respectively, which show the normal maturity of oils; the vitrinite reflectance of the source rocks from the Xishanyao to Badaowan Formations range from 0.47% to 0.97%, which indicate immature to mature thermal evolutionary stage and sufficient conditions for generating mass mature oil. The effect of hydrocarbon expulsion should be considered when studying the source of coal-derived oil by using Biomarkers. Biomarkers in the Jurassic oils from the basin are similar to those in the coals and carbonaceous mudstones, with a strong predominant content of pristane, relatively high ratio of C15/C16 sesquiterpenoids (>1), a relatively high content of low carbon number tricyclic terpanes and C24 tetracyclic terpane, little gammacerane and C29 Ts detected, an absolute predominant content of C29 sterane and a relatively high content of diasterane. However, the opposite characteristics are shown in mudstones, with an approximately equal content of pristane and phytane, relatively low ratio of C15/C16 sesquiterpenoids (<1), a relatively high content of high carbon number tricyclic terpanes and a low content of C24 tetracyclic terpane, peaks of gammacerane and C29 Ts detected obviously and an increasing C27 sterane content. All of these characteristics identify the coals and carbonaceous mudstones as the possible major oil source rocks in this area, and they were formed in the stronger oxidizing environment with shallower water than mudstones.     

The distribution of dimethylcarbazoles in oils from the Pearl River Mouth Basin, South China Sea

C2-carbazole isomers have been investigated in crude oils from the Hui-Liu Structure Ridge (HLSR) in the Pearl River Mouth Basin (PRMB), South China Sea. The NH shielded isomer, as well as the NH partially shielded isomers, was detected in high abundance and the NH exposed isomers in lower abundance. A small-enrichment trend of 1,8-dimethylcarbazole (DMC) was observed in crude oils along the western part of HLSR (WPHLSR), which may indicate little effect of migration on the C2-carbazole distributions. Two strikingly different distribution patterns of NH partially shielded isomers were observed in the reservoirs along the WPHLSR: one with a preference of 1,3- and 1,6-DMCs and the other with a preference of 1,4- and 1,5-DMCs. All of the oils occurring in the Upper reservoirs have a preference of 1,3- and 1,6-DMCs, whereas those trapped in the Lower reservoirs show a preference of 1,4- and 1,5-DMCs, which may indicate there are two petroleum migration systems in the WPHLSR.     

结构平稳随机地震反应时域分析:应用

以平面框架结构为例阐述了结构平稳随机地震反应时域分析方法的应用。首先利用静力凝聚方法大幅度地缩减结构的自由度数目，形成一维链状模型，使得结构运动方程中只包含各层反应从而大大降低计算工作量。其次推导了结点随机反应和层间随机反应的计算公式，可以方便地获得结构在理想白噪声、金井清谱和改进金井清谱三种随机地震地面运动激励下的协方差位移反应函数和协方差速度反应函数。最后通过一个单跨双层的平面框架结构实例，阐述了这种方法的使用过程。     

地理国情监测质量抽查常见问题及关键点分析

随着地理国情监测进入常态化阶段,监测成果在自然资源调查和统计等领域发挥了重要作用,保障监测成果质量显得尤为重要。为保证地理国情监测过程质量符合技术设计要求,本文从质量管理和生产过程质量控制出发,结合检查过程中的常见问题,分析确定过程质量抽查的关键点,并最终保障监测成果真实、准确、可靠,为今后地理国情监测生产和质量控制提供有益参考。     

桁架结构基于地震可靠性分析的优化方法

本文把桁架结构地震可靠性分析和最优化设计方法结合起来，以结构的地震失效率概率为目标函数，给出一种考虑地震可靠性的桁架结构的优化方法。该方法能够解决线性桁架体系在平稳的随机地震地面运动激励下的优化问题，并在给定投资的条件下设计出了安全可靠的桁架结构。     

关于建立信息地理学的讨论

从信息地理学产生的时代背景入手，先后讨论了信息地理学的基本概念和特点，信息地理学的研究内容及方法，信息地理学的基础理论问题等，最后展望了信息地理学的发展前景及潜力。     

增强CT对硬化性肺泡细胞瘤的诊断价值

目的：探讨硬化性肺泡细胞瘤的增强CT表现。方法：回顾性分析42例病理确诊的硬化性肺泡细胞瘤患者的CT图像。结果：42例均表现为肺内单发结节或肿块,边界清楚,形态呈圆形（11例）、类圆形（3例）和浅分叶形（28例）。分布呈周围型41例,中央型1例。合并贴边血管征29例,钙化11例,血管强化征8例,晕征6例,空气新月征1例。增强扫描轻度强化3例,中度强化15例,明显强化24例。10例行静脉期扫描,均见延迟强化。病灶直径0.9~8.5 cm,病灶> 3 cm组密度不均匀的概率较病灶≤3 cm组高,差异有统计学意义（P<0.05）。结论：PSP在增强CT上具有强化程度高、持续时间长的特点,结合CT形态学表现和强化特征,有助于该病的诊断。     

Petrogenesis and Metallogenesis of the Niumaoquan Gabbroic Intrusion Associated with Fe-Ti Oxide Ores in the Eastern Tianshan, NW China

The Niumaoquan layered gabbroic intrusion is in the southern margin of the Central Asian Orogenic Belt in North Xinjiang, China, and hosts a Fe-Ti oxide deposit in its evolved gabbroic phases. In this paper, we report zircon U-Pb age, Sr-Nd-Hf isotopes, plagioclase chemistry, and whole-rock geochemistry of the Niumaoquan layered gabbroic intrusion. Zircon grains separated from an anorthosite sample analyzed by laser ablation inductively coupled plasma mass spectrometry yielded a concordia age of 314.7±0.74 Ma, indicating that the Niumaoquan ore-bearing gabbroic intrusion was emplaced during the Late Carboniferous. The olivine gabbro texture and plagioclase chemistry suggest that plagioclase was an early crystallized silicate phase that crystallized prior to olivine. Fractional crystallization and accumulation of plagioclase significantly controlled the evolution of the Niumaoquan gabbroic intrusion and contributed to the formation of anorthosite layers, causing metallogenic elements to become enriched in the residual melt. The Niumaoquan gabbroic intrusion is characterized by the enrichment of large ion lithophile elements and depletion of high field strength elements, positive zircon εHf(t) values (+2.1 to +12.2), positive εNd(t) values (+3.3 to +5.2), and low initial 87Sr/86Sr ratios (0.7039 to 0.7047), suggesting that the parental magma was produced by interactions between metasomatized lithospheric mantle and depleted asthenospheric melts at an early post-collision stage. The Fe-Ti oxide mineralization of the Niumaoquan intrusion benefited from interactions between depleted asthenospheric melts and lithospheric mantle, and fractional crystallization of abundant plagioclase and magnesian minerals.     

利用古氧相和古生产力替代指标评价四川上寺剖面二叠系海相烃源岩

 中国具备良好的海相地层油气勘探前景,如何正确识别并合理评价海相烃源岩是中国海相盆地油 气勘探开发中亟待解决的关键问题。作者尝试利用多个微量元素分别作为古生产力和古氧相的综合替代指标, 来进行有效烃源岩评价。研究中利用四川广元上寺剖面二叠系中Mo,U ,V,Cu,Ni,Zn6个微量元素测试结 果,计算得到对应两组元素过剩值：Mo_xS ,U_XS ,v_xs 和Cu_xs,Ni_xs,Zn_xs;对这两组元素过剩值分别进行主成分分 析,得到两个系数- - -古生产力替代指标综合系数 （ 简称古生产力系数）和古氧相替代指标综合系数 （ 简称古 氧相系数） ,用以恢复海相烃源岩的古生产力和古氧相条件;将该系数与上寺剖面残余有机碳测试结果 （ THC含 量）进行相关性分析,依此确定古生产力和古氧相条件的定量等级划分。最终,根据该划分标准来判断上寺剖 面烃源岩的品质。利用古生产力和古氧相的综合替代指标方法可为海相烃源岩评价工作提供一些新思路。