The measurement and extraction of the <nu>6 atmospheric emission band of CFC-12 from interfering emission features

Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the ₆ band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated ₆-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 ₆ emission based for a very cold day has been estimated to be 0.27 W m⁻²±10%.     

Sea‐level and ocean‐current control on carbonate‐platform growth,Maldives, Indian Ocean

Multichannel high‐resolution seismic and multibeam data were acquired from the Maldives‐isolated carbonate platform in the Indian Ocean for a detailed characterization of the Neogene bank architecture of this edifice. The goal of the research is to decipher the controlling factors of platform evolution, with a special emphasis on sea‐level changes and changes of the oceanic currents. The stacking pattern of Lower to Middle Miocene depositional sequences, with an evolution of a ramp geometry to a flat‐topped platform, reflects variations of accommodation, which here are proposed to be primarily governed by fluctuations of relative sea level. Easterly currents during this stage of bank growth controlled an asymmetric east‐directed progradation of the bank edge. During the late middle Miocene, this system was replaced by a twofold configuration of bank development. Bank growth continued synchronously with partial bank demise and associated sediment‐drift deposition. This turnover is attributed to the onset and/or intensification of the Indian monsoon and related upwelling and occurrence of currents, locally changing environmental conditions and impinging upon the carbonate system. Mega spill over lobes, shaped by reversing currents, formed as large‐scale prograding complexes, which have previously been interpreted as deposits formed during a forced regression. On a regional scale, a complex carbonate‐platform growth can occur, with a coexistence of bank‐margin progradation and aggradation, as well as partial drowning. It is further shown that a downward shift of clinoforms and offlapping geometries in carbonate platforms are not necessarily indicative for a sea‐level driven forced regression. Findings are expected to be applicable to other examples of Cenozoic platforms in the Indo‐Pacific region.     

MIXTURE ANGLYSIS USING FACTOR ANGLYSIS I: CALIBRATION AND QUANTITATION

One of the major application areas of factor analysis, multivariate calibration and quantitation, is coveredin this review. The algorithms, methodologies and applications covered include principal componentregression, target transformation factor analysis, singular value decomposition and rank annihilationfactor analysis. Many important areas of research having relevance to multivariate calibration andquantitation problems are also covered in this review, including background correction, measurementerror, rank determination, cross-validation, figures of merit, detection of invalid samples, experimentaldesign, sample selection, statistical inference and wavelength selection.     

A crustal suture and lineament in North Africa

A possible suture between an old craton in West Africa and the Arabian—Nubian shield is marked by a persistent zone of Phanerozoic weakness. This zone extends between the Nile and Niger deltas and passes through the Qattara embayment, along the Bahariya fault, through the Kufra basin, between the Tibesti and Jabal al Uwaynat massifs, through the Bahr el Ghazal and Lake Chad areas, and along the Benoue trough.     

Robust biased estimation and its applications in geodetic adjustments

In this paper, a number of robust biased estimators (e.g. ordinary robust ridge estimator, robust principal components estimator, robust combined principal components estimator, robust single-parametric principal components estimator, robust root-root estimator) are established by means of a unified expression of biased estimators and based on the principle of equivalent weight. The most attractive advantage of these new estimators is that they can not only overcome the ill-conditioning of the normal equation but also have the ability to resist outliers. A numerical example is used to illustrate that these new estimators are much better than the least-squares estimator and various biased estimators even when both ill-conditioning and outliers exist. Received: 14 November 1995/Accepted: 11 February 1998     

Determination of post-glacial land uplift from the three precise levellings in Finland

We have calculated vertical velocities and their change in time from three precise levellings in Finland, with central epochs 1902, 1946, and 1986. Models with and without simultaneous determination of heights give the same results for velocities. Evidence for velocity change in time appears at first sight strong but on closer examination turns out to be inconclusive. We offer an alternative explanation in terms of levelling errors and estimate them. A new uplift map closely reproduces main features of earlier maps from partial data, but does not support some details in them. Received: 27 January 1997/ Accepted: 20 April 1998     

MINQUE for block diagonal bordered systems such as those encountered in VLBI data analysis

A sparse matrix method is developed for computing variance factors for block-diagonal, bordered systems of equations using MINQUE (Minimum Norm Quadratic Unbiased Estimation). This method greatly reduces the computational effort required to apply MINQUE, thus making it practical to compute variance factors for some very large systems of equations. The computer implementation of the method is described and applied to the computation of variance factors for a combination of 1609 VLBI (Very Long Baseline Interferometry) observing sessions. The purpose of this test was to compute a variance factor for each of the data sets and, perhaps, to obtain more realistic variance estimates to replace those in common use for the analysis of VLBI data. It was found that the method is satisfactory for use with such large problems, and the test served to verify that the variances in current use in VLBI data adjustments are adequate. Received: 26 November 1996 / Accepted: 12 December 1997