GIS-based approach for evaluating a community intrinsic resilience index

Natural Hazards - Community resilience refers to the degree to which a community can survive and recover following a disaster. While resilience itself is well understood, decisions that would...     

A double spike for osmium analysis of highly radiogenic samples

Geologic samples containing highly radiogenic Os (molybdenites and low-level, highly radiogenic (LLHR) samples) have no internal means by which to correct for mass fractionation during isotopic measurement by mass spectrometry. We describe a double spike for use with highly radiogenic samples, created by combining isotopically enriched ¹⁸⁸Os and ¹⁹⁰Os. Spiking molybdenite and other highly radiogenic minerals with this tracer allows for a fractionation correction, as well as a more reliable determination of common Os relative to analysis using single spikes.

The precise isotopic composition of the double spike is determined by a calibration against natural Os, in which two separate measurements are necessary: one each for the pure double spike and the spike–standard mixture. An estimate of the true composition of the spike is obtained by least squares approximation, and the errors are obtained by Monte Carlo methods. Sample analyses are then much more straightforward than the calibration because isotopic compositions of all components are known a priori.

Results obtained with a mixed Re-double Os spike demonstrate an improved reproducibility over individual ¹⁸⁵Re and ¹⁹⁰Os spikes. For an Archean in-house molybdenite standard we now observe a reproducibility of 0.08%. The ability to make a fractionation correction is essential for Os measurements made by ion counting. With the double Os spike, young samples and those with low Re contents (i.e., LLHR) can now be accurately analyzed. The ¹⁸⁸Os–¹⁹⁰Os double spike also allows a determination of the common Os contents of highly radiogenic samples. Common Os is poorly determined for ancient samples with high concentrations of ¹⁸⁷Os, which fortunately are not sensitive to estimates of common Os. Common Os can be reasonably well determined for younger samples and those with low Re contents. We report a common Os concentration of 0.4±0.1 ppb for an 11 Ma molybdenite. Consideration of common Os content is important for age determination of young samples and LLHR samples, and is not possible by other published means of Os analysis.     

U–Pb,Re–Os,and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar geochronology of the Nambija Au-skarn and Pangui porphyry Cu deposits,Ecuador: implications for the Jurassic metallogenic belt of the Northern Andes

New U–Pb, Re–Os, and ⁴⁰Ar/³⁹Ar dates are presented for magmatic and hydrothermal mineral phases in skarn- and porphyry-related ores from the Nambija and Pangui districts of the Subandean zone, southeastern Ecuador. Nambija has been one of the main gold-producing centers of Ecuador since the 1980s due to exceptionally high-grade ores (average 15 g/t, but frequently up to 300 g/t Au). Pangui is a recently discovered porphyry Cu–Mo district. The geology of the Subandean zone in southeastern Ecuador is dominated by the I-type, subduction-related, Jurassic Zamora batholith, which intrudes Triassic volcanosedimentary rocks. The Zamora batholith is in turn cut by porphyritic stocks, which are commonly associated with skarn formation and/or porphyry-style mineralization. High precision U–Pb and Re–Os ages for porphyritic stocks (U–Pb, zircon), associated prograde skarn (U–Pb, hydrothermal titanite), and retrograde stage skarn (Re–Os, molybdenite from veins postdating gold deposition) of the Nambija district are all indistinguishable from each other within error (145 Ma) and indicate a Late Jurassic age for the gold mineralization. Previously, gold mineralization at Nambija was considered to be Early Tertiary based on K–Ar ages obtained on various hydrothermal minerals. The new Jurassic age for the Nambija district is slightly younger than the ⁴⁰Ar/³⁹Ar and Re–Os ages for magmatic–hydrothermal minerals from the Pangui district, which range between 157 and 152 Ma. Mineralization at Nambija and Pangui is associated with porphyritic stocks that represent the last known episodes of a long-lived Jurassic arc magmatism (∼190 to 145 Ma). A Jurassic age for mineralization at Nambija and Pangui suggests that the Northern Andean Jurassic metallogenic belt, which starts in Colombia at 3° N, extends down to 5° S in Ecuador. It also adds a new mineralization style (Au-skarn) to the metal endowment of this belt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Potential impacts of climate change on warmwater megafauna: the Florida manatee example (Trichechus manatus latirostris)

Most discussions of impacts of Climate Change have focused on species from temperate or polar regions. Impacts to species inhabiting warm climates are often believed to be small relative to those of species living in cooler climates. However, it is evident that some tropical/sub-tropical species, including some marine megafauna may face potentially serious consequences from a changing climate. For example, larger, warmer oceans may appear to benefit marine wildlife species like cold-sensitive Florida manatees; however, findings regarding the impact of global climate change (GCC) on estuaries and nearshore areas of Florida indicate that predicted impacts of climate change may be detrimental to endangered manatees. An examination of how projected impacts of climate change will affect threats to manatees and their habitat indicates that threats may be exacerbated. The most significant threats to the Florida manatee population, such as cold-stress, watercraft collisions, and harmful algal blooms likely will increase. Habitat is likely to be degraded under future climate scenarios. Alterations to Florida’s marine environment are ongoing, yet current manatee management plans do not consider the impacts of climate change. The ability of manatees to adapt to change will be influenced by the speed of change and the degree to which human activity impedes or alters it. To minimize impacts to species we must recognize the influence GCC may have on populations, and begin to identify and implement ways to slow or reverse negative impacts arising from it.     

Subgrain-scale decoupling of Re and Os and assessment of laser ablation ICP-MS spot dating in molybdenite

Reproducibility of Re-Os molybdenite ages depends on sample size and homogeneity, suggesting that Re and Os are decoupled within individual molybdenite crystals and do not remain spatially linked over time. In order to investigate the Re-Os systematics of molybdenite at the subgrain (micron) scale, we report LA-ICP-MS Re-Os ages for an Archean molybdenite crystal from Aittojärvi, Finland, analyzed in situ in a white aplite matrix. A related Aittojärvi molybdenite (A996D), in the form of a very fine-grained mineral separate, is used as one of our in-house NTIMS standards, and thus its age of 2760 ± 9 Ma is well established. Measurements of (¹⁸⁷Re + ¹⁸⁷Os)/¹⁸⁵Re on micron scale spots along 200 μm traverses across the crystal yield a wide range of ages demonstrating that, in this case, microsampling of molybdenite does not produce geologically meaningful ages. Experimentation with mineral separations and sample size over a 7-yr period predicted that this would be the outcome. We suggest that ¹⁸⁷Os is more likely to be the mobile species, based on its charge and ionic radius, and that ¹⁸⁷Os becomes decoupled from parent ¹⁸⁷Re with time on the micron and larger scale. Incompatible charge and ionic radius for Os ions formed during reduction of molybdenite-forming fluids may explain the widely observed absence of common (initial) Os in molybdenite. Geologically accurate ages for molybdenite can only be obtained for fully homogenized crystals (or crystal aggregates) so that any post-crystallization ¹⁸⁷Re-¹⁸⁷Os decoupling is overcome.A growing number of geologically accurate ID-NTIMS ¹⁸⁷Re-¹⁸⁷Os ages for homogenized molybdenite suggest that postcrystallization mobility of radiogenic ¹⁸⁷Os must be limited to within the molybdenite mineral phase. We suggest that radiogenic ¹⁸⁷Os may be stored in micron scale dislocations, kink bands, and delamination cracks produced by deformation, and that the unusual structure and deformation response of molybdenite results in an increased chemical stability in this mineral. Migration of ¹⁸⁷Os into adjacent silicate phases is highly unlikely, but other contacting sulfides may take in Os. In an example from a Proterozoic skarn deposit at Pitkäranta (western Russia), we demonstrate minor loss of radiogenic ¹⁸⁷Os from molybdenite and a corresponding gain in adjacent chalcopyrite such that the molybdenite age is not perceptibly disturbed, whereas the resulting chalcopyrite ages are impossibly old. Therefore, it is unadvisable to perform Re-Os analytical work on any sulfide in contact or intimate association with molybdenite. In addition to large errors in the age, if the isochron method is employed, initial ¹⁸⁷Os/¹⁸⁸Os ratios could be erroneously high, leading to seriously errant genetic interpretations.     

Reconstructed cool- and warm-season precipitation over the tribal lands of northeastern Arizona

For over a decade, the Hopi Tribe and Navajo Nation of northeastern Arizona have suffered the effects of persistent drought conditions. Severe dry spells have critically impacted natural ecosystems, water resources, and regional livelihoods including dryland farming and ranching. Drought planning and resource management efforts in the region are based largely on the instrumental climate record, which contains a limited number of severe, sustained droughts. In this study, a new network of moisture-sensitive tree-ring chronologies provides the basis for evaluating the longer-term temporal variability of precipitation in the Four Corners region. By analyzing the earlywood and latewood components within each annual tree ring, we are able to generate separate, centuries-long reconstructions of both cool- (October-April) and warm-season (July-August) precipitation. These proxy records offer new insights into seasonal drought characteristics and indicate that the instrumental record fails to adequately represent precipitation variability over the past 400 years. Through the use of two different analysis techniques, we identify multiyear and decadal-scale drought events more severe than any in the modern era. Furthermore, the reconstructions suggest that many of the historically significant droughts of the past (e.g., 17th century Puebloan drought) were not merely winter phenomena, but persisted through the summer season as well. By comparing these proxy records with historical documents, we are able to independently validate the reconstructions and better understand the socioeconomic and environmental significance of past climate anomalies on the tribal lands of northeastern Arizona.     

Oxygen isotope compositions of selected laramide-tertiary granitoid stocks in the Colorado Mineral Belt and their bearing on the origin of climax-type granite-molybdenum systems

Quartz phenocrysts from 31 granitoid stocks in the Colorado Mineral Belt yield ¹⁸O values less than 10.4, with most values between 9.3 and 10.4. An average magmatic value of about 8.5 is suggested. The stocks resemble A-type granites; these data support magma genesis by partial melting of previously depleted, fluorine-enriched, lower crustal granulites, followed by extreme differentiation and volatile evolution in the upper crust.Subsolidus interaction of isotopically light water with stocks has reduced most feldspar and whole rock ¹⁸O values. Unaltered samples from Climax-type molybdenumbearing granites, however, show no greater isotopic disturbance than samples from unmineralized stocks. Although meteoric water certainly played a role in post-mineralization alteration, particularly in feldspars, it is not required during high-temperature mineralization processes. We suggest that slightly low ¹⁸O values in some vein and replacement minerals associated with molybdenum mineralization may have resulted from equilibration with isotopically light magmatic water and/or heavy isotope depletion of the ore fluid by precipitation of earlier phases.Accumulation of sufficient quantities of isotopically light magmatic water to produce measured depletions of ¹⁸O requires extreme chemical stratification in a large magma reservoir. Upward migration of a highly fractionated, volatile-rich magma into a small apical Climax-type diapir, including large scale transport of silica, alkalis, molybdenum, and other vapor soluble elements, may occur with depression of the solidus temperature and reduction of magma viscosity by fluorine. Climax-type granites may provide examples of ¹⁸O depletion in magmatic systems without meteoric water influx.     

Contested Space,Contested Livelihoods: A Review of Mongolia's Pastureland Management and Land‐Tenure Reform

In the early 2000s, the discovery of significant minerals wealth in the Gobi Desert marked the beginning of Mongolia's economic boom. Rapid GDP growth however challenges long‐held assumptions about place and land rights, leading to contested and sometimes contradictory outcomes, which are embedded in evolving perceptions and realities of land‐tenure rights, development rights, and local livelihood sustainability. Framed within the debates surrounding natural resources development and the contradictions in scale and user rights, this essay identifies three distinct periods of land‐tenure debate in Mongolia. In each period, pastureland management debates are influenced by different narratives, including those of development economists, scholars, NGOs, and local voices. This essay draws on an extensive review of policy documents and contemporary literature to consider the multiscalar implications of rapid national growth on internal population redistribution, land‐use rights, and the underlying importance of place.