Simplified synthesis of an 8-hydroxyquinoline chelating resin and a study of trace metal profiles from Jellyfish Lake, Palau

We report a simplified synthesis, and some performance characteristics, for 8-hydroxyquinoline (8-HOQ) covalently bonded to a chemically resistant TosoHaas TSK vinyl polymer resin. The resin was used to concentrate trace metals from stored, acidified seawater samples collected from Jellyfish Lake, an anoxic marine lake in the Palau Islands. The Mn, Fe, and Zn profiles determined from the 8-HOQ resin extraction were similar to those determined using Chelex-100 resin. The Zn and Cd profiles did not exhibit removal by sulfide “stripping” in contrast to other anoxic marine basins. The profiles of Co and Ni also exhibited elevated concentrations in the anoxic hypolimnion. The solution speciation and saturation states for the metals were calculated using revised metal-bisulfide stability constants. The calculations suggest that the MS(HS)⁻ species dominates the solution speciation for Mn, Co, Ni, Zn, Cd, and Pb. Cu(I) is modeled as the CuS⁻ or Cu(HS)₂⁻ species, while Fe(II) behaves as the free Fe²⁺ cation. The Mn, Co, Ni, Cu and Cd concentrations appeared to be at least 10-fold undersaturated, while the Fe(II), Zn, and Pb concentrations were close to saturation with respect to their metal sulfides.     

A symplectic integrator for the symmetry reduced and regularised planar 3-body problem with vanishing angular momentum

We construct an explicit reversible symplectic integrator for the planar 3-body problem with zero angular momentum. We start with a Hamiltonian of the planar 3-body problem that is globally regularised and fully symmetry reduced. This Hamiltonian is a sum of 10 polynomials each of which can be integrated exactly, and hence a symplectic integrator is constructed. The performance of the integrator is examined with three numerical examples: The figure eight, the Pythagorean orbit, and a periodic collision orbit.     

Inter-annual water mass variations from GRACE in central Siberia

Our study analyses satellite and land-based observations of the Yakutsk region centred at the Lena watershed, an area characterised mainly by continuous permafrost. Using monthly solutions of the Gravity Recovery And Climate Experiment satellite mission, we detect a mass increase over central Siberia from 2002 to 2007 which reverses into a mass decrease between 2007 and 2011. No significant mass trend is visible for the whole observation period. To further quantify this behaviour, different mass signal components are studied in detail: (1) inter-annual variation in the atmospheric mass, (2) a possible effect of glacial isostatic adjustment (GIA), and (3) hydrological mass variations. In standard processing the atmospheric mass signal is reduced based on the data from numerical weather prediction models. We use surface pressure observations in order to validate this atmospheric reduction. On inter-annual time scale the difference between the atmospheric mass signal from model prediction and from surface pressure observation is $<$ 4 mm in equivalent water height. The effect of GIA on the mass signal over Siberia is calculated using a global ice model and a spherically symmetric, compressible, Maxwell-viscoelastic earth model. The calculation shows that for the investigated area any effect of GIA can be ruled out. Hence, the main part of the signal can be attributed to hydrological mass variations. We briefly discuss potential hydrological effects such as changes in precipitation, river discharge, surface and subsurface water storage.     

The regional pressure impact of CO<Subscript>2</Subscript> storage: a showcase study from the North German Basin

A regional scale, showcase saline aquifer CO₂ storage model from the North German Basin is presented, predicting the regional pressure impact of a small industrial scale CO₂ storage operation on its surroundings. The intention of the model is to bridge the gap between generic and site-specific, studying the role of fluid flow boundary conditions and petrophysical parameters typically found in the North German Basin. The numerical simulation has been carried out using two different numerical simulators, whose results matched well. The most important system parameters proved to be the model’s hydrological boundary conditions, rock compressibility, and permeability. In open boundary aquifers, injection-induced overpressures dissipate back to hydrostatic level within a few years. If a geological flow barrier is present on at least one side of the aquifer, pressure dissipation is seriously retarded. In fully closed compartments, overpressures can never fully dissipate, but equilibrate to a compartment-wide remnant overpressure. At greater distances to the injection well, maximum fluid pressures are in the range of a few bar only, and reached several years to decades after the end of the actual injection period. This is important in terms of long-term safety and monitoring considerations. Regional pressure increase impacts the storage capacities of neighbouring sites within hydraulically connected units. It can be concluded that storage capacities may be seriously over- or underestimated when the focus is on a single individual storage site. It is thus necessary to assess the joint storage capacities and pressure limitations of potential sites within the same hydraulic unit.     

Spatio-temporal dynamics in the flood exposure due to land use changes in the Alpine Lech Valley in Tyrol (Austria)

Flood risk is expected to increase in many regions of the world in the next decades with rising flood losses as a consequence. First and foremost, it can be attributed to the expansion of settlement and industrial areas into flood plains and the resulting accumulation of assets. For a future-oriented and a more robust flood risk management, it is therefore of importance not only to estimate potential impacts of climate change on the flood hazard, but also to analyze the spatio-temporal dynamics of flood exposure due to land use changes. In this study, carried out in the Alpine Lech Valley in Tyrol (Austria), various land use scenarios until 2030 were developed by means of a spatially explicit land use model, national spatial planning scenarios and current spatial policies. The combination of the simulated land use patterns with different inundation scenarios enabled us to derive statements about possible future changes in flood-exposed built-up areas. The results indicate that the potential assets at risk depend very much on the selected socioeconomic scenario. The important conditions affecting the potential assets at risk that differ between the scenarios are the demand for new built-up areas as well as on the types of conversions allowed to provide the necessary areas at certain locations. The range of potential changes in flood-exposed residential areas varies from no further change in the most moderate scenario ‘Overall Risk’ to 119 % increase in the most extreme scenario ‘Overall Growth’ (under current spatial policy) and 159 % increase when disregarding current building restrictions.     

Sensitivity of coastal polynyas and high-salinity shelf water production in the Ross Sea,Antarctica, to the atmospheric forcing

Coastal polynyas around Antarctica are the place of intense air–sea exchanges which eventually lead to the formation of high-salinity shelf waters (HSSW) over continental shelves. Here, the influence of atmospheric forcing on coastal polynyas in the Ross Sea is studied by contrasting the response of a regional ocean/sea-ice circulation model to two different atmospheric forcing sets. A first forcing (DFS3) is based on ERA40 atmospheric surface variables and satellite products. A second forcing (MAR) is produced on the basis of ERA40 with a dynamical downscaling procedure. As compared to DFS3, MAR forcing is shown to improve substantially the representation of small-scale patterns of coastal winds with stronger katabatic winds along the coast. The response of the ocean/sea-ice model to the two forcing sets shows that the MAR forcing improves substantially the geographical distribution of polynyas in the Ross Sea. With the MAR forcing, the polynya season is also shown to last longer with a greater ice-production rate. As a consequence, a greater flow of dense water out of the polynyas is found with the MAR forcing and the properties of HSSW are notably improved as compared to the DFS3 forcing. The factors contributing to the activity of Terra Nova Bay and Ross Ice Shelf polynyas in the model are studied in detail. The general picture that emerges from our simulations is that the properties of HSSW are mostly set by brine rejection when the polynya season resume. We found that coastal polynyas in the Ross Sea export about 0.4 Sv of HSSW which then flows along three separate channels over the Ross Shelf. A 6-month time lag is observed between the peak of activity of polynyas and the maximum transport across the sills in the channels with a maximum transport of about 1 Sv in February. This lag corresponds to the time it takes to the newly formed HSSW to spread from the polynya to the sills (at a speed of nearly 2 cm s⁻¹).     

Modelling biofilm growth in the presence of carbon dioxide and water flow in the subsurface

The concentration of greenhouse gases – particularly carbon dioxide (CO₂) – in the atmosphere has been on the rise in the past decades. One of the methods which have been proposed to help reduce anthropogenic CO₂ emissions is the capture of CO₂from large, stationary point sources and storage in deep geological formations. The caprock is an impermeable geological layer which prevents the leakage of stored CO₂, and its integrity is of utmost importance for storage security. Due to the high pressure build-up during injection, the caprock in the vicinity of the well is particularly at risk of fracturing. Biofilms could be used as biobarriers which help prevent the leakage of CO₂ through the caprock in injection well vicinity by blocking leakage pathways. The biofilm could also protect well cement from corrosion by CO₂-rich brine.     

Combined fitting of Ulysses/COMPTEL GRB spectra

This paper describes a comparison of observations of the HH 30 jet/counterjet system and theoretical models of jets propagating in a strongly stratified medium. We find that the observed westward bending of the HH 30 jet and counterjet can be explained as the result of a plane-parallel pressure stratification of the surrounding environment. This model predicts specific properties for the kinematics of the outflow, that could be straight-forwardly checked with future spectroscopic and proper motion studies of HH 30.