Arsenic fixation on iron-hydroxide-rich and plant litter-containing sediments in natural environments

Iron-hydroxide-rich and plant litter-containing sediments from natural sites contaminated with uranium mine tailing leachates were examined for their ability to adsorb arsenic. The samples with high contents of iron hydroxides (Fe_total concentration, >300 g kg⁻¹) exhibited remarkable fixation of arsenic (up to 40 g As kg⁻¹). This value corresponded approximately to the supersaturation point for natural iron hydroxides under the present conditions, and it was significantly lower than the value found for synthetic iron hydroxides. There was a strong correlation (R=0.8999) between the concentration of iron and that of arsenic at low arsenic contents, indicating adsorption on strong binding sites. Although all the samples had noticeable contents of organic carbon (plant litter), calcium, and manganese, no obvious effect of these elements on arsenic fixation could be detected. The amount of iron hydroxides was found the only fixation-controlling parameter immediately below a leaching water source.     

Does Pumping Volume Affect the Concentration of Micropollutants in Groundwater Samples?

Information on concentrations of micropollutants (such as pharmaceuticals, pesticides, and industrial chemicals) in most highly dynamic riverbank filtration (RBF) systems is lacking, in contrast to data on standard chemical parameters. Sampling protocols have thus far been based on the stabilization of standard chemical parameters in relatively pristine environments. To determine whether groundwater samples for micropollutant analysis can be taken at a similar pumping volume as samples for testing standard chemical parameters in both environments, three groundwater monitoring wells in an RBF system were sampled at two points in time (after pumping of 3 well volumes and after pumping of 15 well volumes). Micropollutant concentrations were not significantly different between the two sampling points; therefore, appropriate samples can be drawn after pumping 3 well volumes. For a specific microbiological parameter (leucin incorporation), a statistically significant difference was found.     

Tracing the temporal evolution of soil redistribution rates in an agricultural landscape using 239+240Pu and 10Be

Two principal groups of processes shape mass fluxes from and into a soil: vertical profile development and lateral soil redistribution. Periods having predominantly progressive soil forming processes (soil profile development) alternate with periods having predominantly regressive processes (erosion). As a result, short-term soil redistribution – years to decades – can differ substantially from long-term soil redistribution; i.e. centuries to millennia. However, the quantification of these processes is difficult and consequently their rates are poorly understood. To assess the competing roles of erosion and deposition we determined short- and long-term soil redistribution rates in a formerly glaciated area of the Uckermark, northeast Germany. We compared short-term erosion or accumulation rates using plutonium-239 and -240 (^239+240Pu) and long-term rates using both in situ and meteoric cosmogenic beryllium-10 (¹⁰Be). Three characteristic process domains have been analysed in detail: a flat landscape position having no erosion/deposition, an erosion-dominated mid-slope, and a deposition-dominated lower-slope site. We show that the short-term mass erosion and accumulation rates are about one order of magnitude higher than long-term redistribution rates. Both, in situ and meteoric ¹⁰Be provide comparable results. Depth functions, and therefore not only an average value of the topsoil, give the most meaningful rates. The long-term soil redistribution rates were in the range of −2.1 t ha^-1 yr^-1 (erosion) and +0.26 t ha^-1 yr^-1 (accumulation) whereas the short-term erosion rates indicated strong erosion of up to 25 t ha^-1 yr^-1 and accumulation of 7.6 t ha^-1 yr^-1. Our multi-isotope method identifies periods of erosion and deposition, confirming the ‘time-split approach’ of distinct different phases (progressive/regressive) in soil evolution. With such an approach, temporally-changing processes can be disentangled, which allows the identification of both the dimensions of and the increase in soil erosion due to human influence. © 2019 John Wiley & Sons, Ltd.     

Significance of boulder shape,shoreline configuration and pre-transport setting for the transport of boulders by tsunamis

Research on tsunami-induced coarse-clast transport is a field of rising interest since such deposits have been identified as useful proxies for extreme-wave events (tsunamis, storm waves) that provide crucial information for coastal hazard assessment. Physical experiments are, beside in-situ observations, the foundation of our understanding of how boulders are transported by tsunamis and provide clues to the development of empirical equations and numerical models describing the processes and fundamental mechanics. Nevertheless, investigating tsunami-induced boulder transport is a comparatively young discipline and only a few experimental studies focusing on this topic have been published so far. To improve the knowledge on nearshore tsunami hydrodynamics, physical experiments utilizing real-world boulder shapes have been carried out simulating three different shore types in a wave flume. Crucial insights were gained into boulder transport hydrodynamics and data resulting from the experiments were analysed in an empirical, statistical, quantitative and qualitative manner. The regular cuboid boulder – one of the specific shapes used in the experiments – showed the longest transport distances compared to a complex, natural boulder and a flat cuboid boulder, but also significant fluctuations regarding the total transport distance. The experiments indicate a strong influence of the shore shape on boulder transport behaviour. Experimental setups of increased mean transport distances also led to a higher spreading of results. This spreading was further amplified between the idealized-shaped cuboid and the complex-shaped boulder, which is associated with a lower drag coefficient. Due to the highly sensitive boulder reaction to divergent experimental setups, the need to recognize boundary conditions overcoming commonly considered parameters (e.g. roughness or Flatness Index) in field studies and numerical models is underlined. Beside the strong influence of initial boulder submergence and alignment, both the boulder shape and shore type influence the boulder transport pattern, increasing the total transport distance by more than 350% in some cases. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

The use of numerical modeling to optimize the construction of lined sections for a regionally-significant irrigation canal in Egypt

Environmental Earth Sciences - Water balance is considered as an important tool to assess the amount of water and its availability in a region. The Small Aral Sea is a salt lake in the territory of...     

Trophic position of Calanus finmarchicus (Copepoda, Calanoida) in the Trondheim Fjord

The trophic position of Calanus finmarchicus in the Trondheim Fjord in 2004 was determined through stable isotope analyses. Wild specimens were sampled monthly in the fjord and δ¹³C and δ¹⁵N signatures of the developmental stages from CIII to adults were measured. There were statistically significant differences in the δ¹³C and δ¹⁵N signatures of three identified groups: overwintered parental generation, developing new generation and new generation preparing for overwintering. C. finmarchicus individuals raised in a laboratory on a pure algal diet (Dunaliella tertiolecta and Isochrysis galbana) provided stable isotope signatures for purely herbivorous copepods. With these signatures as comparison, the trophic position of C. finmarchicus in the Trondheim Fjord in 2004 was determined as trophic level 2.4, thus indicating omnivory under natural conditions. Additionally, our data suggest that seasonal differences in the δ¹³C signatures of C. finmarchicus are due to the varying lipid content of the different developmental stages.     

Water Quality Co-Effects of Greenhouse Gas Mitigation in U.S. Agriculture

This study develops first-order estimates of water quality co-effects of terrestrial greenhouse gas (GHG) emission offset strategies in U.S. agriculture by linking a national level agricultural sector model (ASMGHG) to a national level water quality model (NWPCAM). The simulated policy scenario considers GHG mitigation incentive payments of $25 and $50 per tonne, carbon equivalent to landowners for reducing emissions or enhancing the sequestration of GHG through agricultural and land-use practices. ASMGHG projects that these GHG price incentives could induce widespread conversion of agricultural to forested lands, along with alteration of tillage practices, crop mix on land remaining in agriculture, and livestock management. This study focuses on changes in cropland use and management. The results indicate that through agricultural cropland about 60 to 70 million tonnes of carbon equivalent (MMTCE) emissions can be mitigated annually in the U.S. These responses also lead to a 2% increase in aggregate national water quality, with substantial variation across regions. Such GHG mitigation activities are found to reduce annual nitrogen loadings into the Gulf of Mexico by up to one half of the reduction goals established by the national Watershed Nutrient Task Force for addressing the hypoxia problem.     

Behaviour Of An Ultrasonic Anemometer Under Cloudy Conditions

The use of ultrasonic anemometers under cloudy weather conditions is often doubted, even rejected or not discussed in the literature. To investigate the influence of liquid water content on the behaviour of sonic anemometers a small intercomparison experiment using an ultrasonic anemometer, a fast response propeller anemometer, and a Particulate Volume Monitor was performed at the German Environmental Research Station Schneefernerhaus near the top of Mt. Zugspitze. The results obtained under different conditions (dry/cloudy) give no significant hint on such an influence.     

Double-layer structure in the boundary layer over the baltic sea

Double-layered structures found over the Baltic Sea are investigated using radiosoundings and lidar measurements. Situations with double-layer structures are also simulated with the regional model REMO in a realistic manner. The double layer consists of two adjacent well-mixed layers, with a sharp inversion in between.Results from radiosoundings show that the double-layer structure over the Baltic Sea mainly occurs during the autumn with thermally unstable stratification near the surface. The structure is present in about 50 % of the radiosoundings performed during autumn. The presence of the double-layer structure cannot be related to any specific wind direction, wind speed or sea surface temperature.The lidar measurements give a more continuous picture of the time evolution of the double-layer structure, and show that the top of the lower layer is not a rigid lid for vertical transport. Two possible explanations of the double-layer structure are given, (i) the structure is caused by `advection' of land boundary-layer air over the convective marine boundary layer or, (ii) by development of Sc clouds in weak frontal zones connected to low pressure systems. Also the forming of Cu clouds is found to be important for the development of a double-layer structure.