Solar Energetic Particles and Associated EIT Disturbances in Solar Cycle 23

We explore the link between solar energetic particles (SEPs) observed at 1 AU and large-scale disturbances propagating in the solar corona, named after the Extreme ultraviolet Imaging Telescope (EIT) as EIT waves, which trace the lateral expansion of a coronal mass ejection (CME). A comprehensive search for SOHO/EIT waves was carried out for 179 SEP events during Solar Cycle 23 (1997?–?2006). 87 % of the SEP events were found to be accompanied by EIT waves. In order to test if the EIT waves play a role in the SEP acceleration, we compared their extrapolated arrival time at the footpoint of the Parker spiral with the particle onset in the 26 eastern SEP events that had no direct magnetic connection to the Earth. We find that the onset of proton events was generally consistent with this scenario. However, in a number of cases the first near-relativistic electrons were detected too early. Furthermore, the electrons had in general only weakly anisotropic pitch-angle distributions. This poses a problem for the idea that the SEPs were accelerated by the EIT wave or in any other spatially confined region in the low corona. The presence of weak electron anisotropies in SEP events from the eastern hemisphere suggests that transport processes in interplanetary space, including cross-field diffusion, play a role in giving the SEPs access to a broad range of helio-longitudes.     

Long-term variations in the microwave brightness temperature of the Uranus atmosphere

We present a self-consistent, 36-year record of the disk-averaged radio brightness of Uranus at wavelengths near 3.5 cm. It covers nearly half a uranian year, and includes both equatorial and polar viewing geometries (corresponding to equinox and solstice, respectively). We find large (greater than 30 K) changes over this time span. In agreement with analyses made of more limited microwave data sets, our observations suggest the changes are not caused by geometric effects alone, and that temporal variations may exist in the deep uranian troposphere down to pressures of tens of bars. Our data also support an earlier suggestion that a rapid, planetary-scale change may have occurred in late 1993 and early 1994. The seasonal record presented here will be useful for constraining dynamical models of the deep atmosphere, and for interpreting observations made during Uranus' 2007 equinox passage. As part of a multi-wavelength observing campaign for this event, the Goldstone-Apple Valley Radio Telescope (GAVRT) project will continue to make frequent, single-dish observations near 3.5 cm.     

Constraints on the composition of the Venus atmosphere from microwave measurements near 1.35 cm wavelength

The determination of the brightness temperature of Venus near 1.35 cm wavelength is reviewed. The observed brightness temperature is compared with models for the microwave emission based on the physical and chemical structure of the atmosphere as obtained from spacecraft. Upper limits are set on the concentrations of microwave-absorbing minor constituents. In particular, upper limits are determined for SO₂ (180 ppm) and H₂O (0.3%) for a mixing-ratio profile that is uniformly mixed up to the cloud bottom at 50 km and is rapidly depleted ($\text{scale height}\text{? 1}\text{km}\text{)}$ at higher altitudes. The total optical depth of the cloud region at or above 50 km is <0.17 at 1.35 cm wavelength. The SO₂ upper limit is only in marginal agreement with the spacecraft results, and it may be that the latter have been overestimated, or that the distribution of SO₂ is more complex than given by the uniform mixing model.     

NMR Measurements in Carbonate Rocks: Problems and an Approach to a Solution

Carbonate rocks are well known for their complex petrophysical behavior where, in contrast to siliciclastic rocks, different parameters, including porosity and permeability, usually are not directly related. This behavior is the result of thorough reorganization of porosity during diagenesis, and it turns prediction of reservoir quality of carbonate rocks into a challenge. The study presented here deals with the problem of utilizing NMR techniques in prediction of petrophysical properties in carbonates.We employ a visual porosity classification as a priori knowledge for better interpreting NMR data for prediction purposes. This allows for choice of suitable T₂ cutoff values to differentiate movable from bound fluids adapted for the specific carbonate rock, thus resulting in better interpretation of NMR data. The approach of using a genetic pore type classification for adapting the conventional method for T₂ cutoff determination, which originally was developed for siliciclastic rocks, is promising. Similarly, for permeability determination on the basis of NMR measurements, the classification of carbonate rocks based on porosity types also shows potential. The approach implemented here has the promise to provide a basis of standardized interpretation of NMR data from carbonate rocks.Acknowledgment We are grateful to Baker Hughes INTEQ, Celle, for permission to publish the results of this work. This study was part of I.S.s Masters Thesis at Hannover University that was carried out in collaboration with Baker Hughes INTEQ, Celle, Germany. We appreciate comments of an anonymous referee and PAGEOPH editor Brian J. Mitchell.     

Venus I. Carbon monoxide distribution and molecular-line searches

An observational program to study variations of the vertical distribution of CO in the Venus atmosphere is presented. Measurements of the J = 0 → 1 absorption line at 2.6 mm wavelength are reported for two phase angles in 1977, one near eastern elongation (Feb.) and the other near inferior conjunction (Apr.). The two spectra are significantly different, with the April absorption line being narrower and deeper. The results of numerical inversion calculations show that the CO mixing ratio increases a factor of ～ 100 between 78 and 100 km and that the CO abundance above ～ 100 km is greatest on the night-side hemisphere. These conclusions are in qualitative agreement with theoretical models. In addition to the CO observations, a search for other molecules was made to provide further information on the composition of the Venus middle atmosphere. The J = 0 → 1 transition of ¹³CO was detected and upper limits were derived for nine other molecules.     

Land cover change over the last three centuries due to human activities: The availability of new global data sets

Land use and land cover change is an important driver of global change (Turner et al., 1993). It is recognized that land use change has important consequences for global and regional climates, the global biogeochemical cycles such as carbon, nitrogen, and water, biodiversity, etc. Nevertheless, there have been relatively few comprehensive studies of global, long-term historical changes in land cover due to land use. In this paper, we review the development of global scale data sets of land use and land cover change. Furthermore, we assess the differences between two recently developed global data sets of historical land cover change due to land use. Based on historical statistical inventories (e.g. census data, tax records, land surveys, historical geography estimates, etc) and applying different spatial analysis techniques, changes in agricultural land cover (croplands, pastures) were reconstructed for the last 300 years. The two data sets indicate that cropland areas expanded from 3–4 million km² in 1700 to 15–18 million km² in 1990 (mostly at the expense of forests), while grazing land area expanded from 5 million km² in 1700 to 31 million km² in 1990 (mostly at the expense of natural grasslands). The data sets disagree most over Latin America and Oceania, and agree best over North America. Major differences in the two data sets can be explained by the use of a fractional versus Boolean approach, different modelling assumptions, and inventory data sets.     

Environmental changes in northern New Zealand since the Middle Holocene inferred from stable isotope records (δ15N, δ13C) of Lake Pupuke

Maar lakes in the Auckland Volcanic Field are important high-resolution archives of Holocene environmental change in the Southern Hemisphere mid-latitudes. Stable carbon and nitrogen isotope analyses were applied on bulk organic matter and the green alga Botryococcus from a sediment core from Lake Pupuke (Auckland, North Island, New Zealand) spanning the period since 7,165?cal.?year BP. The origin of organic matter was established using total-organic?Ccarbon-to-nitrogen ratios (TOC/TN) as well as organic carbon (??¹³C_OM) and nitrogen (??¹⁵N) isotope composition of potential modern sources. This approach demonstrated that the contribution of allochthonous organic matter to the lake sediment was negligible for most of the record. The sedimentary TOC/TN ratios that are higher than Redfield ratio (i.e. >7) are attributed to N-limiting conditions throughout the record. Variations of nitrogen and carbon isotopes during the last 7,165?years are interpreted as changes in the dominant processes in the lake. While epilimnetic primary productivity controlled isotope composition before 6,600?cal.?year BP, microbial processes, especially denitrification and methane oxidation, caused overall shifts of the ??¹⁵N and ??¹³C values since the Mid-Holocene. Comparisons with climate reconstructions from the Northern Island suggest that changes in the wind-induced lake overturn and a shift to more pronounced seasonality were the most likely causes for lake-internal changes since 6,600?cal.?year BP.     

Meteorologically consistent bias correction of climate time series for agricultural models

Conventional bias correction of simulated climate time series for impact models is done separately for climate variables and hence leads to inconsistencies between them. However, agricultural models mostly use several variables, and meteorological consistency is essential. The present work points out meteorological inconsistency due to quantile mapping and describes a new method of consistent bias correction by an optimization approach. Time series of hourly precipitation and global radiation from the regional model REMO5.7 (Run UBA C20/A1B_1) were corrected with site observations from the German Meteorological Service. The results urge to check conventionally corrected series for consistency before using them for multidimensional models. Here, quantile mapping resulted in underestimation of diffuse radiation at hours with precipitation. This deficit was minimized by the developed procedure.     

The fast Ice Nucleus chamber FINCH

We present first results of our new developed Ice Nucleus (IN) counter FINCH from the sixth Cloud and Aerosol Characterization Experiment (CLACE 6) campaign at Jungfraujoch station, 3571 m asl. Measurements were made at the total and the ICE CVI inlet. Laboratory measurements of ice onset temperatures by FINCH are compared to those of the static diffusion chamber FRIDGE (FRankfurt Ice Deposition Freezing Experiment). Within the errors of both new instruments the results compare well to published data.     

Fe-Ni-Co-O-S Phase Relations in Peridotite-Seawater Interactions

Serpentinization of abyssal peridotites is known to produceextremely reducing conditions as a result of dihydrogen (H₂,aq)release upon oxidation of ferrous iron in primary phases toferric iron in secondary minerals by H₂O. We have compiled andevaluated thermodynamic data for Fe–Ni–Co–O–Sphases and computed phase relations in fO₂,g–fS₂,g andaH₂,aq–aH₂S,aq diagrams for temperatures between 150 and400°C at 50 MPa. We use the relations and compositions ofFe–Ni–Co–O–S phases to trace changesin oxygen and sulfur fugacities during progressive serpentinizationand steatitization of peridotites from the Mid-Atlantic Ridgein the 15°20'N Fracture Zone area (Ocean Drilling ProgramLeg 209). Petrographic observations suggest a systematic changefrom awaruite–magnetite–pentlandite and heazlewoodite–magnetite–pentlanditeassemblages forming in the early stages of serpentinizationto millerite–pyrite–polydymite-dominated assemblagesin steatized rocks. Awaruite is observed in all brucite-bearingpartly serpentinized rocks. Apparently, buffering of silicaactivities to low values by the presence of brucite facilitatesthe formation of large amounts of hydrogen, which leads to theformation of awaruite. Associated with the prominent desulfurizationof pentlandite, sulfide is removed from the rock during theinitial stage of serpentinization. In contrast, steatitizationindicates increased silica activities and that high-sulfur-fugacitysulfides, such as polydymite and pyrite–vaesite solidsolution, form as the reducing capacity of the peridotite isexhausted and H₂ activities drop. Under these conditions, sulfideswill not desulfurize but precipitate and the sulfur contentof the rock increases. The co-evolution of fO₂,g–fS₂,gin the system follows an isopotential of H₂S,aq, indicatingthat H₂S in vent fluids is buffered. In contrast, H₂ in ventfluids is not buffered by Fe–Ni–Co–O–Sphases, which merely monitor the evolution of H₂ activitiesin the fluids in the course of progressive rock alteration.The co-occurrence of pentlandite–awaruite–magnetiteindicates H₂,aq activities in the interacting fluids near thestability limit of water. The presence of a hydrogen gas phasewould add to the catalyzing capacity of awaruite and would facilitatethe abiotic formation of organic compounds. KEY WORDS: serpentinization; ODP Expedition 209; sulfide; oxygen fugacity; sulfur fugacity; hydrothermal system; metasomatism; Mid-Atlantic Ridge