Quantitative Simulation of the Hydrothermal Systems of Crystallizing Magmas on the Basis of Transport Theory and Oxygen Isotope Data: An analysis of the Skaergaard Intrusion

Application of the principles of transport theory to studiesof magma-hydrothermal systems permits quantitative predictionsto be made of the consequences of magma intruding into permeablerocks. Transport processes which redistribute energy, mass,and momentum in these environments can be represented by a setof partial differential equations involving the rate of changeof extensive properties in the system. Numerical approximationand computer evaluation of the transport equations effectivelysimulates the crystallization of magma, cooling of the igneousrocks, advection of chemical components, and chemical and isotopicmass transfer between minerals and aqueous solution. Numerical modeling of the deep portions of the Skaergaard magma-hydrothermalsystem has produced detailed maps of the temperature, pressure,fluid velocity, integrated fluid flux, ¹⁸O-values in rock andfluid, and extent of nonequilibrium exchange reactions betweenfluid and rock as a function of time for a two-dimensional cross-sectionthrough the pluton. An excellent match was made between calculated¹⁸O-values and the measured ¹⁸O-values in the three principalrock units, basalt, gabbro, and gneiss, as well as in xenolithsof roof rocks that are now embedded in Layered Series; the latterwere evidently depleted in ¹⁸O early in the system's coolinghistory, prior to falling to the bottom of the magma chamber.The best match was realized for a system in which the bulk rockpermeabilities were 10^–13 cm² for the intrusion, 10^–11cm² for basalt, and 10^–16 cm² for gneiss; reaction domainsizes were 0.2 cm in the intrusion and gneiss and 0.01 cm inthe basalts, and activation energy for the isotope exchangereaction between fluid and plagioclase was 30 kcal/mole. The calculated thermal history of the Skaergaard system wascharacterized by extensive fluid circulation that was largelyrestricted to the permeable basalts and to regions of the plutonstratigraphically above the basalt-gneiss unconformity. Althoughfluids circulated all around the crystallizing magma, fluidflow paths were deflected around the magma sheet during theinitial 130,000 years. At that time, crystallization of thefinal sheet of magma and fracture of the rock shifted the circulationsystem toward the center of the intrusion, thereby minimizingthe extent of isotope exchange between rocks near the marginof the intrusion at this level. For comparison, similar calculationswere also made for pure conductive cooling; it was found thatthe rate of crystallization of the magma body was not changed.The solidified pluton cooled by a factor of about 2 faster inthe presence of a hydrothermal system. Transport rates of thermal energy out of the intrusion and oflow-¹⁸O fluids into the intrusion controlled the overall isotopeexchange process. During the initial 150,000 years, temperatureswere high and reaction rates were fast; thus, fluids flowinginto the intrusion quickly equilibrated with plagioclase. However,the temperature decreased between 120,000 and 175,000 yearsand caused a decrease in reaction rates and an increase in theequilibrium fractionation factor between plagioclase and fluid.Consequently, during this time period fluids in the intrusiontended to be out of equilibrium with plagioclase. After 175,000years temperatures had decreased sufficiently that reactionrates became insignificant, but convection rates were largeenough to redistribute fluid and enlarge the regions where fluidand plagioclase were out of equilibrium. By 400,000 years, thepluton had cooled to approximately ambient temperatures, andthe final ¹⁸O values were ‘frozen in’. Reactionsbetween hydrothermal fluid and the intrusion occurred over abroad range in temperature, 1000-200 °C, but 75 per centof the fluid circulated through the intrusion while its averagetemperature was >480 °C. This relatively high temperatureis consistent with the observation that only minor amounts ofhydrothermal alteration products were formed in the naturalsystem, even where several per mil shifts in ¹⁸O were detected. The relative quantities of fluid to rock integrated over theentire cooling history were 0.52 for the upper part of intrusion,0.88 for the basalt, 0.003 for the gneiss, and 0.41 for theentire domain. Almost all of the fluid flowed into the intrusionfrom the basalt host rocks that occur adjacent to the side contactsof the intrusion. Convection transferred about 20 per cent ofthe total heat contained in the gabbro upward into the overlyingbasalts; the remaining 80 per cent of the heat was transferredby conduction.     

Evidence for a Picritic, Volatile-rich Magma beneath Mt. Shasta, California

Large, magnesium-rich olivines are plentiful in several Holocenecinder cones within 20 km of Mt. Shasta Summit. Glasses (formerlysilicate melts) included in the olivines are high alumina basalts(tholeiites and olivine tholeiites). In the most magnesian olivinesthe glass inclusions have large vapor bubbles. Surrounding someof the glass inclusions are broad Fe-rich zones and ghost outlines.These facts indicate crystallization of major proportions ofolivine from the initial trapped melts. The initial melts containedan inferred 24 per cent of MgO and were rich in volatiles. Theinferred entrapment temperature of the initial melt is 1410°C. The initial liquid is a possible mantle derived parentof Mt. Shasta basalts and andesites and of some hidden alpineperidotite.     

Gould Pond, Maine: late-glacial transitions from marine to upland environments

Gould Pond sediments are unusual in North America in that they include a continuous record of change from marine to freshwater conditions during the late-glacial period, with a wide array of micro- and macrofossils deposited during a period of high sedimentation rate. Marine waters, much colder than those in the present Gulf of Maine, covered the site at the time of deglaciation (c. 13,200 BP). Plants characteristic of modem tundra grew on nearby uplands. Marine recession, due to isostatic rebound of the land, occurred from c . 12,800–12,200 BP. The lake water was completely freshened by 12,000 BP. A sparse shrub-herb tundra became established around Gould Pond as marine waters receded. Subsequent to 11,300 BP, sedges and other herbs became more abundant, and willow and Dryas less abundant, signifying increased warmth and decreased frost action. At least six tree species, all now common in the area, arrived around Gould Pond between c . 10,800 and 10,500 BP. This rapid transition was coincident with the most rapid major non-anthropogenic change of vegetation at sites across eastern North America during the postglacial period.     

Photointerpretation of Tertiary structures in platform cover strata of interior Oscar II Land, Spitsbergen

A structural map of Oscar II Land compiled using black and white, stereo-pair air photos and other available information sources suggests the existence of three structural zones within the deformed platform cover strata. The western zone consists of basement involved overthrusts of complex geometry in the north large-scale folds of platform cover strata with a stepped, down to the east profile in the south. The central zone consists primarily of folds within Kapp Starostin Fm. and overlying Triassic strata that likely formed above a subhorizontal décollement within Gipshuken Fm. strata. Farther to the east thrusts emplace Permian Kapp Starostin Fm. strata over Triassic strata. This zone probably represents stratigraphic climb of the basal decollement. Conservative estimates of shortening for the central and eastern zones are in the 15-25% range. The contribution of the western zone structures to overall Tertiary shortening depends on the geometry of faults underlying the stepped folds and is uncertain at present.
Changes along strike are in part due to differential levels of erosion and changes in transport direction, but also probably important was variable thickness of the platform cover strata involved (less to the north) and the availability of incompetent horizons along which thrust-fiats could form. Two areas with anomalous structural trends may represent oblique ramps.     

A storm-related origin for the Jurassic Brentskardhaugen Bed of Spitsbergen, Norway

The laterally persistent but thin, Jurassic age (Bathonian-Callovian) Brentskardhaugen bed is poorly sorted (often with mud to cobble size), and is crudely normally and/or reversely graded without internal discontinuities. These traits may indicate a short-lived depositional event, and are inconsistent with an origin as a basal, transgressive gravel lag formed in a terrestrial or shoreline setting. Mega-storm events on a shallow marine shelf with an underlying condensed section may account for the poor sorting, grading, stratigraphic position and remanie character of the bed.     

Analysis of bycatch in the South African midwater trawl fishery for horse mackerel Trachurus capensis based on observer data

The South African midwater trawl fishery targets adult horse mackerel Trachurus capensis. The bulk of the catch is taken by a single freezer-trawler, the biggest fishing vessel operating in South African waters. As fishing takes place off the south coast in ecologically sensitive areas, there are concerns about the potential impacts of this fishing operation on non-target species. Fishing behaviour and bycatch of this fishery from 2004 to 2014 were investigated by analysing observer records with regard to catch composition, volume and temporal and spatial patterns. The midwater trawl fishery was estimated to have caught 25 415 tonnes annually, with a bycatch of 6.9% of the total catch, by weight. There are species overlaps with various fisheries, namely the demersal trawl, small-pelagic, line, shark longline and squid fisheries, yet the total bycatch estimates from this fishery are generally small relative to catches taken in the target fisheries. Bycatch species with the highest average annual catches were chub mackerel Scomber japonicus, redeye roundherring Etrumeus whiteheadi, ribbonfish Lepidopus caudatus and hake Merluccius spp. Large-fauna bycatch species included sunfish Mola mola as well as a number of CITES II- and IUCN-listed species, such as Cape fur seal Arctocephalus pusillus, dusky shark Carcharhinus obscurus, smooth hammerhead shark Sphyrna zygaena and thresher sharks Alopias spp. The 97.9% observer coverage is high and the 6.9% bycatch rate low compared to other South African fisheries; however, due to the large size of the individual hauls (average of 46.3 t), the average sampling rate of 1.56% is low. Our analyses suggest that bycatch in the South African midwater trawl fishery has been lower than in other South African fisheries and similar fisheries elsewhere, but due to the combination of high catch volumes and low sampling rates, estimation errors for rare species are high and there is a substantial risk of incidental unmonitored bycatch of rare large fauna and aggregations of small fauna. This could be mitigated by spatio-temporal management of this fishery, to avoid fishing in high-risk areas, and the introduction of an electronic monitoring programme.     

Multi-stakeholder collaboration yields valuable data for cetacean conservation in Gamba,Gabon

Private industry, the Government of Gabon and two international NGOs collaborated to conduct marine surveys off the coast of Gabon, Central Africa. Surveys addressed multiple objectives of surveillance and monitoring, the documentation of the distribution of and threats to the marine megafauna, and capacity-building among government agents and local early-career scientists. During 22 days of survey effort over a two-year period, observers documented humpback whales Megaptera novaeangliae, bottlenose dolphins Tursiops truncatus, Atlantic humpback dolphins Sousa teuszii and common dolphins Delphinus delphis. Humpback whale presence was limited to the months of July to November. Bottlenose dolphins were present year-round and photo-identification of individuals indicated a closed, resident population, with an abundance estimate of 118 (CV = 21.6%, 95% CI 78–180). Small open-decked fishing vessels with gillnets were observed concentrated around river mouths within 2 km of shore, while commercial trawlers were at least 10 km offshore; all were confirmed to be registered and legal. Observations of marine turtles, flocks of marine birds, and floating logs and other debris were sparse. This multi-stakeholder collaboration to conduct a marine survey can serve as an effective model by which funding and logistic support from private industry paired with technical expertise from NGOs and academic institutions can benefit marine and coastal conservation.     

Isotopic mapping of groundwater perchlorate plumes

Analyses of stable isotope ratios of chlorine and oxygen in perchlorate can, in some cases, be used for mapping and source identification of groundwater perchlorate plumes. This is demonstrated here for large, intersecting perchlorate plumes in groundwater from a region having extensive groundwater perchlorate contamination and a large population dependent on groundwater resources. The region contains both synthetic perchlorate derived from rocket fuel manufacturing and testing activities and agricultural perchlorate derived predominantly from imported Chilean (Atacama) nitrate fertilizer, along with a likely component of indigenous natural background perchlorate from local wet and dry atmospheric deposition. Most samples within each plume reflect either a predominantly synthetic or a predominantly agricultural perchlorate source and there is apparently a minor contribution from the indigenous natural background perchlorate. The existence of isotopically distinct perchlorate plumes in this area is consistent with other lines of evidence, including groundwater levels and flow paths as well as the historical land use and areal distribution of potential perchlorate sources.     

The place of rural, remote and least-wealthy small islands in international water development: the nexus of geography–technology sustainability in Chuuk State, Federated States of Micronesia

Many least-wealthy, rural, remote and resource-poor small island communities are unlikely to benefit from high-profile global water improvement initiatives. Their small landmasses, geologic composition, geography, social and technological isolation, colonial history, and weak educational and financial resources constitute significant barriers to improving access to safe drinking water. This paper discusses the relatively unique position of such island societies in the international community, providing a case study of the Federated States of Micronesia that integrates data and information pertaining to water resources management and governance, spanning from the island village to national scale. A vision is offered regarding the interaction between small island human and biophysical water systems, manifesting ways to pursue water resource development to improve public health which are constructed to be economically, physically and culturally sustainable.