Seasonal variation of bromocarbons at Hateruma Island,Japan: implications for global sources

High-frequency measurements of dibromomethane (CH₂Br₂) and bromoform (CHBr₃) at Hateruma Island, in the subtropical East China Sea, were performed using automated preconcentration gas chromatography/mass spectrometry. Their baseline concentrations, found in air masses from the Pacific Ocean, were 0.65 and 0.26 ppt, respectively, in summer and 1.08 and 0.87 ppt, respectively, in winter. Air masses transported from Southeast Asia were rich in bromocarbons, suggesting strong emissions in this area. The passage of cold fronts from the Asian continent was associated with sharp increases in observed concentrations of bromocarbons derived from coastal regions of the continent. Comparison of the relationships between [CH₂Br₂]/[CHBr₃] and [CHBr₃] in the Hateruma Island data with those in monthly mean data from 14 globally distributed U.S. National Oceanic and Atmospheric Administration ground stations suggested that these gases are produced primarily from a common process on a global scale.     

Frequency-dependence of velocity and attenuation of elastic waves in granite under uniaxial compression

Velocity as well as attenuation factorQ ^–1 ofP-wave in a dry granitic rock sample under uniaxial compressions were measured in the range of frequency between 100 kHz and 710 kHz by using the pulse transmission technique. Above the stress of 0.5 _f , where _f is the fracture stress, theP-wave velocity decreases with increasing axial stress, whereasQ ^–1 increases. Particularly, the change ofQ ^–1 is greater for high frequency than for low frequency. At a given stress level, the higher the frequency, the higher theP-wave velocity and the largerQ ^–1. This result means that the velocity decrease with increasing stress is smaller for higher frequency. Because of this frequency-dependence of velocity decrease, theP-wave in the rock under dilatant state shows dispersion. The body wave dispersion is more remarkable at higher stress, and is not found in a homogeneous material with no cracks. Thus the disperison is attributed to the generation of cracks. When the frequency-dependence ofQ ^–1 is approximated asf ⁿ in the present frequency range, the exponentn takes a value from 0.63 to 0.77.     

Wind-dependent formation of phytoplankton spring bloom in Otsuchi Bay,a ria in Sanriku,Japan

Spring blooms of phytoplankton composed of centric diatoms developed in late February, March, and April in Otsuchi Bay on Sanriku ria coast, Japan. During this period, associated with prolonged seasonal west wind (>1 day), intense exchange of waters occurred between inside and outside the bay: outflow of nearsurface brackish water over inflow of oceanic water at depth. This circulation interrupted formation of the blooms, and transported phytoplankton populations seaward. By such water movements, a significant amount of nutrients in the bay was carried out, otherwise replenished into the bay, depending on water masses located outside the bay. Owing to irregular features of wind events, a bloom lasted from several days to a week. From February to April, supply of nutrients seemed to be replete except for the latter half of the bloom period, and estimates of the critical depth exceeded the depth of the bottom consistently. Thus, net growth of phytoplankton was expected throughout the observation period, and potentially blooms could be formed. However, the blooms were only formed under calm weather. We hypothesize that the exchange of waters dilutes populations in the bay, and that formation of the bloom, that is, accumulation of biomass depends on a balance between the growth of phytoplankton and the dilution of bay water.     

Seagrasses from the Nansei Islands, Southern Japanese Archipelago: species composition, distribution and biogeography

The Nansei Islands in the southern Japanese Archipelago have 15 taxa of seagrasses from seven genera within three families. Seagrasses in this region grow on coral sands or coral debris in shallow reefs and on sandy or muddy substrata in the shallow areas of bays and inlets. Certain Halophila species grow in deep water off some islands. Enhalus acoroides only reaches to Ishigaki I. with winter sea water temperature (WST) at 23 °C, while Okinawa I. (WST at 21.6 °C) is the northern biogeographic limit for Halophila decipiens, H. okinawensis, H. major and H. gaudichaudii. Amami‐oshima I. (WST at 20.7 °C) is the northern border for Thalassia hemprichii, H. minor, H. ovalis, Cymodocea serrulata, Cymodocea rotundata, Syringodium isoetifolium, Halodule uninervis and Halodule pinifolia. Halophila mikii the sole seagrass collected from Yakushima I. (WST at 19.3 °C), is of volcanic origin. The distribution of tropical seagrasses in the Nansei Islands is clearly associated with the warm Kuroshio Current, WST and habitat availability. Zostera japonica is the only temperate species occurring in the region. Meadows of Z. japonica, H. ovalis and Halodule pinifolia have disappeared from certain localities in the Archipelago, due probably to human activities and natural siltation.     

Chemistry and isotope ratios of sulfur in basalts and volcanic gases at Kilauea volcano,Hawaii

Eighteen basalts and some volcanic gases from the submarine and subaerial parts of Kilauea volcano were analyzed for the concentration and isotope ratios of sulfur. By means of a newly developed technique, sulfide and sulfate sulfur in the basalts were separately but simultaneously determined. The submarine basalt has 700 ± 100 ppm total sulfur with δ³⁴S_Σs of $\text{0.7 ± 0.1 ‰}$. The sulfate/sulfide molar ratio ranges from 0.15 to 0.56 and the fractionation factor between sulfate and sulfide is $\text{+7.5 ± 1.5‰}$. On the other hand, the concentration and δ³⁴S_Σs values of the total sulfur in the subaerial basalt are reduced to 150 ± 50 ppm and $\text{?0.8 ± 0.2‰}$, respectively. The sulfate to sulfide ratio and the fractionation factor between them are also smaller, 0.01 to 0.25 and +3.0‰, respectively. Chemical and isotopic evidence strongly suggests that sulfate and sulfide in the submarine basalt are in chemical and isotopic equilibria with each other at magmatic conditions. Their relative abundance and the isotope fractionation factors may be used to estimate the $\text{?o}{}_2$ and temperature of these basalts at the time of their extrusion onto the sea floor. The observed change in sulfur chemistry and isotopic ratios from the submarine to subaerial basalts can be interpreted as degassing of the SO₂ from basalt thereby depleting sulfate and ³⁴S in basalt.The volcanic sulfur gases, predominantly SO₂, from the 1971 and 1974 fissures in Kilauea Crater have δ³⁴S values of 0.8 to 0.9%., slightly heavier than the total sulfur in the submarine basalts and definitely heavier than the subaerial basalts, in accord with the above model. However, the δ³⁴S value of sulfur gases (largely SO₂) from Sulfur Bank is 8.0%., implying a secondary origin of the sulfur. The δ³⁴S values of native sulfur deposits at various sites of Kilauea and Mauna Loa volcanos, sulfate ions of four deep wells and hydrogen sulfide from a geothermal well along the east rift zone are also reported. The high δ³⁴S values (+5 to +6%._o) found for the hydrogen sulfide might be an indication of hot basaltseawater reaction beneath the east rift zone.     

Measurement of elastic properties of single-crystal CaO up to 1200 K

The elastic moduli of a single-crystal calcium oxide, CaO, are measured in the temperature range from 300 to 1200 K (1.8 times of the Debye temperature) by the resonant sphere technique (RST). The lowest 18 modes are identified in the frequency range from 0.6 to 1.4 MHz for the vibrating spherical specimen, which is 5.6564 mm in diameter and 3.3493 g/cm³ in density at room temperature, and the resonant frequencies are traced as a function of temperature. The adiabatic elastic moduli are determined in the present temperature range from the observed frequencies by inversion calculations. Most of the elastic moduli, except forC ₁₂ modulus, decrease as temperature increases. The temperature curves ofC _s andC ₄₄ moduli cross at 372 K. This means that the CaO specimen has an isotropic elasticity at the temperature. The temperature derivatives (?C ₁₁/?T) _P and (?C _s/?T) _P become slightly less negative with temperature increase and (?C _s /?T) _P and (?C ₄₄/?T) _P are almost constant. Combining the present elastic data with thermal expansion and specimen heat capacity data of CaO, we present the temperature dependence of thermodynamic parameters important in the studies of earth's interior.     

Meteoric hydrothermal origin of calcites in “Green Tuff” formations,Miocene age,Japan

Oxygen and carbon isotope compositions were determined for calcites from the Green Tuff formations of Miocene age in Japan. Values of ¹⁸O from 24 calcites in altered rocks from 5 districts range from –2 to +16_SMOW, in most cases from 0 to +8_SMOW. The low ¹⁸O values rule out the possibility of their low-temperature origin or any significant contribution of magmatic fluid in the calcite precipitation. These values, coupled with their mineral assemblages, suggest that the calcites formed from meteoric hydrothermal solutions which caused propylitic alteration after the submarine strata became emergent.Values of ¹³C from the calcites show a wide variation from –17 to 0_PDB. Calcites from different districts have different ranges of ¹³C values, indicating that there was no homogeneous reservoir of carbon at the time the calcite formed, and that the carbon had local sources. Carbon isotopic compositions of calcite within ore deposits in the Green Tuff formations range from –19 to 0_PDB, similar to those of calcite in the altered rocks in the same district, suggesting that the carbon in ore calcites was likely supplied from the surrounding rocks through activity of meteoric hydrothermal solutions.     

Physical properties of the outflow sources in taurus

We have searched for CO outflows in eight embedded IRAS sources located in the Taurus molecular cloud using the 45m telescope of Nobeyama Radio Observatory. We have detected CO wing emission in four of these sources. CO outflow associated with TMC1A (04365+2535) is strong and spatially compact (radius 0.04 pc). The dynamical timescale of 2.5 × 10³ yr suggests this outflow is the youngest one in Taurus.We have combined our data with previously published survey data and have analyzed the physical properties of the outflow sources. We found that 12 out of 16 embedded sources ( 75 %) have CO outflows associated with them; this indicates that almost all stars experience a phase of molecular outflow in their embedded stage. The IRAS color of the outflow sources suggests that the outflows appear in considerably early phase of the evolution of YSOs, that is, as early as YSOs became observable with IRAS and that visible outflow sources are in a transient phase of evolution between embedded sources and visible T Tauri stars without outflow. Visible outflow sources are systematically more luminous than visible no-outflow sources, while embedded outflow sources have comparable luminosities with visible no-outflow sources. Such luminosity function suggests that the YSOs with outflow undergo mass accretion and increase their stellar mass as they progress from embedded sources to visible outflow sources. Typical mass accretion rate derived from the bolometric luminosity is 2 ×10^–6 M _yr ^–1. The timescale for mass accretion to acquire typical stellar mass, 0.5 – 0.8M , is 2.5 – 4 × 10⁵ yr.     

Full-scale structural monitoring using an integrated GPS and accelerometer system

Accurate in situ measurement of the full-scale structural responses, especially tall buildings, under severe loading conditions is an important requirement for validating their design, evaluating their construction as well as facilitating their maintenance. Traditionally such response has been measured using accelerometers. However, it is impossible to measure the static and quasi-static components of motion with acceleration sensors. An integrated system comprising of RTK-GPS and accelerometers has been developed with the objective of assessing full-scale structural responses by exploiting the complementary characteristics of GPS and accelerometer sensors. The data used in this paper were obtained from GPS and accelerometer sensors installed on a 108-m-high steel tower in Tokyo, together with other sensors such as anemometer and strain gauge. The seismic and wind-induced responses of the tower were analyzed using the Fast Fourier Transformation (FFT) and compared to results from finite element modeling (FEM). In order to study the system reliability, the correlated signals were extracted by applying a digital filtering technique. Then the filtered data sets were converted to displacement (in the case of accelerometer data) and acceleration (in the case of GPS data) through double integration and double differentiation, respectively, for the purpose of direct comparison and to further fuse data from the two different sensors. The results agree with each other very well, although the static and quasi-static components are missing from the accelerometer-derived results. The redundancy of the monitoring system therefore has been achieved.