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151.
Uno S Tanaka H Miki S Kokushi E Ito K Yamamoto M Koyama J 《Marine pollution bulletin》2011,63(5-12):477-481
This paper reports for the first time the detection and occurrence of nitroarenes (NPAHs) in marine organisms. Mussels and oysters collected from Osaka Bay, Japan, had total NPAHs concentrations that ranged from 2380 to 24,688 pg/g dry and 2672 to 25,961 pg/g dry, respectively. Relatively higher concentrations were detected in sampling sites located near the central district and suburbs of Osaka City implying that the most probable sources of NPAHs in the two bivalves are exhaust gases and smokes emitted by automobiles and industrial plants. Bivalves had relatively higher residues of 1-nitronaphthalene, 2-nitronaphthalene, 3-nitrophenanthrene, and 9-nitrophenanthrenes. Residues of 2-nitrofluorene, 1-nitropyrene, 4-nitropyrenes, and 6-nitrochrysene were much lower compared to nitronaphthalenes and nitrophenanthrenes. Inter-species differences was only observed for 2-nitronaphthalene with oysters exhibiting significantly higher residues than mussels. 相似文献
152.
Interpretation of undisturbed hydrogeochemical conditions in Neogene sediments of the Horonobe area, Hokkaido, Japan 总被引:1,自引:0,他引:1
Empirical, geostatistical and geochemical modeling techniques were used to determine whether chemical, isotopic and mineralogical data collected in surface-based borehole investigations at the Horonobe Underground Research Laboratory (URL) site in Hokkaido, Japan were representative of the natural environment before it was disturbed by borehole drilling, hydraulic testing and sampling. Water samples collected either by pumping groundwaters to the surface from borehole sections that had been isolated by inflatable packers or by squeezing porewaters from drillcores sampled from the same borehole and sampling depth were found to be similar in certain respects (mNa+, mCl−, δ18O and δD) but not others (mSO42−, mCa2+, mMg2+ and mK+). The inconsistencies suggest that a majority of the porewater samples were contaminated as a result of pyrite oxidation and dissolution of carbonate minerals during sampling, storage and/or squeezing of the drillcores. Multivariate geostatistical analyses support this hypothesis, and further suggest that uncontaminated porewaters and groundwaters can be divided into three representative groups: a low salinity, low δ18O and low δD group; a moderate salinity, low Ca-Mg group; and a high salinity, high K and moderate Ca-Mg group. The groundwaters also contain high concentrations of dissolved gases, including CH4(g), CO2(g), H2S(g) and various hydrocarbons, which exsolve from the groundwaters as they are pumped to the surface for sampling. The effects of such degassing on the chemistry of groundwater samples was evaluated by using a reaction-path model to simulate the titration of gases collected at the surface back into the samples. Results suggest that undisturbed groundwaters are slightly more acidic than their sampled counterparts, and contain roughly equivalent activities of dissolved CH4(aq) and carbonate species. Redox potentials calculated using the corrected groundwater compositions and assuming equilibrium for the CH4(aq)/CO2(aq) redox couple are significantly more negative than those determined in situ in one borehole using a downhole chemical probe, and those that can be inferred from the ubiquitous presence of small amounts of framboidal pyrite and siderite in siliceous biogenic sediments of the Horonobe area. The empirical, geostatistical and geochemical modeling techniques considered in this study can be adapted for use in characterizing the hydrogeochemical environment of a site that will eventually be selected to host a geologic repository for high-level nuclear waste in Japan. 相似文献
153.
The Sm and Gd isotopic compositions of silicates from six mesosiderites (Dalgaranga, Estherville, Morristown, Northwest Africa (NWA) 1242, NWA 2932, and Vaca Muerta) and one iron meteorite (Udei Station) were determined to elucidate the cosmic-ray exposure records. All seven samples showed significant 150Sm/149Sm and 158Gd/157Gd isotopic shifts from neutron capture reactions corresponding to neutron fluences of (1.3-21.8) × 1015 n cm−2. In particular, Vaca Muerta showed a significantly higher neutron fluences than the other six samples. The parameter for the degree of neutron thermalization (εSm/εGd) also showed a significant difference between Vaca Muerta (0.76) and the other samples (0.93-1.20). These results suggest a two-stage irradiation of the Vaca Muerta silicates in the parent body (>50 Ma) before formation of the mesosiderite and during its transit to Earth (138 Ma). This is consistent with the 81Kr-Kr cosmic-ray exposure age data of a Vaca Muerta pebble from a previous noble gas isotopic study. 相似文献
154.
Makoto Yamada Shinji Ohsawa Kohei Kazahaya Masaya Yasuhara Hiroshi Takahashi Kazuhiro Amita Hideo Mawatari Shin Yoshikawa 《Journal of Geochemical Exploration》2011
To understand deep groundwater flow systems and their interaction with CO2 emanated from magma at depth in a volcanic edifice, deep groundwater samples were collected from hot spring wells in the Aso volcanic area for hydrogen, oxygen and carbon isotope analyses and measurements of the stable carbon isotope ratios and concentrations of dissolved inorganic carbon (DIC). Relations between the stable carbon isotope ratio (δ13CDIC) and DIC concentrations of the sampled waters show that magma-derived CO2 mixed into the deep groundwater. Furthermore, groundwaters of deeper areas, except samples from fumarolic areas, show higher δ13CDIC values. The waters' stable hydrogen and oxygen isotope ratios (δD and δ18O) reflect the meteoric-water origin of that region's deep groundwater. A negative correlation was found between the altitude of the well bottom and the altitude of groundwater recharge as calculated using the equation of the recharge-water line and δD value. This applies especially in the Aso-dani area, where deeper groundwater correlates with higher recharge. Groundwater recharged at high altitude has higher δ13CDIC of than groundwater recharged at low altitude, strongly suggesting that magmatic CO2 is present to a much greater degree in deeper groundwater. These results indicate that magmatic CO2 mixes into deeper groundwater flowing nearer the magma conduit or chamber. 相似文献
155.
Alexandre Forest Jean-Éric Tremblay Yves Gratton Johannie Martin Jonathan Gagnon Gérald Darnis Makoto Sampei Louis Fortier Mathieu Ardyna Michel Gosselin Hiroshi Hattori Dan Nguyen Roxane Maranger Dolors Vaqué Cèlia Marrasé Carlos Pedrós-Alió Amélie Sallon Christine Michel Colleen Kellogg Jody Deming Elizabeth Shadwick Helmuth Thomas Heike Link Philippe Archambault Dieter Piepenburg 《Progress in Oceanography》2011,91(4):410-436
Major pathways of biogenic carbon (C) flow are resolved for the planktonic food web of the flaw lead polynya system of the Amundsen Gulf (southeast Beaufort Sea, Arctic Ocean) in spring-summer 2008. This period was relevant to study the effect of climate change on Arctic marine ecosystems as it was characterized by unusually low ice cover and warm sea surface temperature. Our synthesis relied on a mass balance estimate of gross primary production (GPP) of 52.5 ± 12.5 g C m−2 calculated using the drawdown of nitrate and dissolved inorganic C, and a seasonal f-ratio of 0.64. Based on chlorophyll a biomass, we estimated that GPP was dominated by phytoplankton (93.6%) over ice algae (6.4%) and by large cells (>5 μm, 67.6%) over small cells (<5 μm, 32.4%). Ancillary in situ data on bacterial production, zooplankton biomass and respiration, herbivory, bacterivory, vertical particle fluxes, pools of particulate and dissolved organic carbon (POC, DOC), net community production (NCP), as well as selected variables from the literature were used to evaluate the fate of size-fractionated GPP in the ecosystem. The structure and functioning of the planktonic food web was elucidated through inverse analysis using the mean GPP and the 95% confidence limits of every other field measurement as lower and upper constraints. The model computed a net primary production of 49.2 g C m−2, which was directly channeled toward dominant calanoid copepods (i.e. Calanus hyperboreus 20%, Calanus glacialis 10%, and Metridia longa 10%), other mesozooplankton (12%), microzooplankton (14%), detrital POC (18%), and DOC (16%). Bacteria required 29.9 g C m−2, a demand met entirely by the DOC derived from local biological activities. The ultimate C outflow comprised respiration fluxes (82% of the initial GPP), a small sedimentation (3%), and a modest residual C flow (15%) resulting from NCP, dilution and accumulation. The sinking C flux at the model limit depth (395 m) supplied 60% of the estimated benthic C demand (2.8 g C m−2), suggesting that the benthos relied partly on other C sources within the bottom boundary layer to fuel its activity. In summary, our results illustrate that the ongoing decline in Arctic sea ice promotes the growth of pelagic communities in the Amundsen Gulf, which benefited from a ∼80% increase in GPP in spring-summer 2008 when compared to 2004 – a year of average ice conditions and relatively low GPP. However, 53% of the secondary production was generated within the microbial food web, the net ecological efficiency of zooplankton populations was not particularly high (13.4%), and the quantity of biogenic C available for trophic export remained low (6.6 g C m−2). Hence it is unlikely that the increase in lower food web productivity, such as the one observed in our study, could support new harvestable fishery resources in the offshore Beaufort Sea domain. 相似文献
156.
Motoyoshi Oda Shun Chiyonobu Masayuki Torii Takashi Otomo Jumpei Morimoto Yuri Satou Hiroshi Ishikawa Matsuaki Ashikawa Osamu Tominaga 《Journal of Asian Earth Sciences》2011,40(1):84-97
An integrated magnetobiochronology of the Miyazaki Pliocene–Pleistocene succession in the Miyazaki area, southwest Japan, was established using planktic foraminiferal and calcareous nannofossil biostratigraphy together with paleomagnetic data. The upper Miyazaki succession in the northern Miyazaki region can be divided into the Takanabe, Hisamine (redefined), and Higoyashiki (new) Formations, in ascending order. A depositional hiatus between the Hisamine Formation and the Takanabe and/or older formations was also identified based on integrated magnetobiostratigraphy from five sections including the Nagatani River (NGT) section through the uppermost Miyazaki succession. The hiatus, herein called the Hisamine unconformity, is equivalent to the Kurotaki unconformity between the Miura and Kazusa groups of the Boso Peninsula in central Japan. The depositional hiatus recognised in the lower Pleistocene of Pacific coastal areas in southwestern and central Japan may have resulted from tectonic activity associated with a change in the subduction direction of the Philippine Sea plate, which commenced prior to ca. 2.2 Ma. The youngest unit just below the hiatus is the upper part of the Takanabe Formation in the NGT section. The NGT section represents the continuous Late Pliocene to earliest Pleistocene sequence including the Gauss/Matuyama boundary and is here proposed as the type section for the Pliocene/Pleistocene boundary in Japan, which the IUGS ratified as the base of the Gelasian in 2009. 相似文献
157.
Ariake Bay, Kyushu Island, has recently exhibited environmental degradation in the form of red tides and anoxic bottom water.
To determine the characteristics and regional classification of the copepod community, zooplankton surveys were made throughout
the bay in three cruises each in October 2004, January 2005 and March 2009 by vertical tows of a 0.1-mm-mesh plankton net.
Oithona davisae was the most abundant in January and March, and Microsetella norvegica in October. Cluster analysis revealed that the copepod community from each cruise was generally separated into the inner
to eastern-middle region and the western-middle to mouth region. A SIMPER analysis revealed that dissimilarity between the
groups and similarity within each group were mainly due to the dominant species, but the similarities within the outer-region
group in January and March were mostly contributed by Paracalanus parvus s.l. A non-metric multidimensional scaling with bubble plots of environmental variables and a BIOENV analysis showed that
transparency was more different between the two groups than temperature and salinity. As compared with two similarly sized,
eutrophic bays (Tokyo and Osaka Bays), Ariake Bay differs from Tokyo Bay in the dominance of M. norvegica and from Osaka Bay in the high abundance of O. davisae even in the colder season. The dominant species and the regional classification of the copepod community in the bay were
similar to those in the studies in the 1970s, suggesting that the copepod community has not notably changed during the last
3 decades. 相似文献
158.
Eko Siswanto Junwu Tang Hisashi Yamaguchi Yu-Hwan Ahn Joji Ishizaka Sinjae Yoo Sang-Woo Kim Yoko Kiyomoto Keiko Yamada Connie Chiang Hiroshi Kawamura 《Journal of Oceanography》2011,67(5):627-650
A bio-optical dataset collected during the 1998?C2007 period in the Yellow and East China Seas (YECS) was used to provide alternative empirical ocean-color algorithms in the retrieval of chlorophyll-a (Chl-a), total suspended matter (TSM), and colored dissolved organic matter (CDOM) absorption coefficients at 440 nm (ag440). Assuming that remote-sensing reflectance (Rrs) could be retrieved accurately, empirical algorithms for TChl (regionally tuned Tassan??s Chl-a algorithm) in case-1 waters (TChl2i in case-2 waters), TTSM (regionally tuned Tassan??s TSM algorithm), and Tag440 or Cag440 (regionally tuned Tassan??s or Carder??s ag440 algorithm) were able to retrieve Chl-a, TSM, and ag440 with uncertainties as high as 35, 46, and 35%, respectively. Applying the standard SeaWiFS Rrs, TChl was not viable in the eastern part of the YECS, which was associated with an inaccurate SeaWiFS Rrs retrieval because of improper atmospheric correction. TChl behaved better than other algorithms in the turbid case-2 waters, although overestimation was still observed. To retrieve more reliable Chl-a estimates with standard SeaWiFS Rrs in turbid water (a proxy for case-2 waters), we modified TChl for data with SeaWiFS normalized water-leaving radiance at 555 nm (nLw555) > 2 mW cm?2 ??m?1 sr?1 (TChl2s). Finally, with standard SeaWiFS Rrs, we recommend switching algorithms from TChl2s (for case-2 waters) to MOCChl (SeaWiFS-modified NASA OC4v4 standard algorithm for case-1 waters) for retrieving Chl-a, which resulted in uncertainties as high as 49%. To retrieve TSM and ag440 using SeaWiFS Rrs, we recommend empirical algorithms for TTSM (pre-SeaWiFS-modified form) and MTag440 or MCag440 (SeaWiFS Rrs-modified forms of Tag440 or Cag440). These could retrieve with uncertainties as high as 82 and 52%, respectively. 相似文献
159.
Hiroaki Todo Koji Yamamoto Mamoru Mimura Susumu Yasuda 《Geotechnical and Geological Engineering》2013,31(3):941-963
On October 15, 2010, the Japanese Geotechnical Society (JGS) announced the public release of ‘Nation-wide Electronic Geotechnical Database Systems,’ which provides geotechnical information to the public on the internet. The information the system provides is a collection of ground models at 250 m by 250 m in plan built by using data from various geotechnical information databases. The paper first describes historical development of the geotechnical information databases in Japan, and introduces a 5-year project, ‘Integrated Geophysical and Geological Information Database in Japan,’ led by the National Research Institute for Earth Science and Disaster Prevention (NIED), and participated by the JGS. The paper then presents the JGS’ ‘Nation-wide Electronic Geotechnical Database Systems,’ and describes why such system was proposed and built, followed by the presentation of the examples for possible application of the system. 相似文献
160.