ESR diagram: a method to distinguish vitrinite macerals

It has been found that samples consisting of a homogeneous vitrinite show a good ESR correlation of spin concentration with geothermal parameters and that a graph of ESR line width vs g-value can be useful in the identification of the maceral and the determination of the coalification rank.     

The theory of the nutation for the rigid earth model at the second order

We perform a complete reconstruction of the series of the nutation for a rigid Earth model with the use of the very accurate theories ELP2000 and VSOP82 for the motion of the Moon and the planets respectively, in such a way that all the individual contributions up to 0.005 mas should be taken. This implies the introduction of the planetary effects, of the influence of second-order parts of the potential of the Earth (J3, triaxiality), and some improvements due to an extension of the theory at the second order. All this increase notably the number of coefficients to be taken in account, and modifies also in a significant way the value of some of them.     

From an initial transient-state to a steady-state in metamorphic reactions: An experimental approach in the system dolomite-quartz-H2O

Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H₂O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /L_CaOCaO and b = /L_MgOMgO) but also on the relative rate P = (−2ξ₁ − ξ₂)/(–ξ₁ − 2ξ₂) of competing reactions: Dol + 2Qtz = Di + 2CO₂ (ξ₁) and 2Dol + Qtz = Fo + 2Cal + 2CO₂ (ξ₂). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.     

Metaproteomic characterization of dissolved organic matter in coastal seawater

We performed a comprehensive metaproteomic analysis of the dissolved organic matter (DOM) in Japanese coastal waters using liquid chromatography–tandem mass spectrometry and demonstrated that these proteomes were characterized by proteins with various functions, including metabolic enzymes, membranes, and photosynthetic proteins. The protein sources included cyanobacteria, heterotrophic bacteria, and eukaryotic phytoplankton. Most of the components were similar among samples and also similar to pelagic components. We also observed differences in the compositions of the microbial communities of origin among the different dissolved protein samples and differences in the relative abundance of specific dissolved protein types (e.g., cytoskeletal proteins), possibly indicating potential dynamics in the coastal DOM pool.     

Nutricline shoaling in the eastern Pacific warm pool during the last two glacial maxima

Isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) and alkenones were analyzed in sediment samples retrieved from Ocean Drilling Program Site 1241 covering the last 150000 years to understand the hydrological evolution of the eastern Pacific warm pool (EPWP). GDGT and alkenone concentrations showed higher values in marine isotope stage (MIS)-2 and MIS-6, which suggests the enhancement of primary production at glacial maxima. $ {\text{TEX}}_{86}^{\text{H}} $ - and $ U_{ 3 7^\prime }^{\text{K}} $ -derived temperature depicted different temperature evolutions. $ U_{ 3 7^\prime }^{\text{K}} $ -derived temperature was marked by small variation during the glacial–interglacial cycles, whereas $ {\text{TEX}}_{86}^{\text{H}} $ -derived temperature showed pronounced glacial–interglacial variation that was similar to Mg/Ca-derived temperature records from nearby cores in the EPWP. Given that enhanced primary production during glacial maxima suggests nutricline shoaling, unchanged $ U_{ 3 7^\prime }^{\text{K}} $ over glacial–interglacial cycles can be interpreted as the shift of alkenone production depth. $ {\text{TEX}}_{86}^{\text{H}} $ seems not to be influenced by glacial–interglacial changes in nutricline depths, recording an integrated temperature in surface and thermocline water. The shallow nutricline in the EPWP during glacial maxima most likely reflected the intense formation of Antarctic intermediate water.     

High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010–2011

We measured dissolved isoprene (2-methyl-1,3-butadiene; C₅H₈) concentrations in a broad area of the southern Indian Ocean and in the Indian sector of the Southern Ocean from 35°S to 64°S and from 37°E to 111°E during austral summer 2010–2011. Isoprene concentrations were continuously measured by use of a proton-transfer-reaction mass spectrometer combined with a bubbling-type equilibrator. Concentrations of isoprene and its emission flux throughout the study period ranged from 0.2 to 395 pmol L^?1 and from 181 to 313 nmol m^?2 day^?1, respectively, the averages being generally higher than those of previous studies. Although we found a significant linear positive relationship between isoprene and chlorophyll-a concentrations (r ² = 0.37, n = 36, P < 0.001), the correlation coefficient was lower than previously reported. In contrast, in the high-latitude area (>53°S) we identified a significant negative correlation (r ² = 0.59, n = 1263, P < 0.001) between isoprene and the temperature-normalized partial pressure of carbon dioxide (n-pCO₂), used as an indicator of net community production in this study. This suggests that residence times and factors controlling variations in isoprene and n-pCO₂ are similar within a physically stable water column.     

Large-Eddy Simulation of Pollutant Removal from a Three-Dimensional Street Canyon

Large-eddy simulations were conducted to investigate the mechanism of pollutant removal from a three-dimensional street canyon. Five block configurations with aspect ratios (building height to length) of 1, 2, 4, 8 and $\infty $ were used to create an urban-like array. A pollutant was released from a ground-level line source at the centre of the target canyon floor. For smaller aspect ratios, the relative contribution of the turbulent mass flux to net mass flux at the roof level, which was spatially averaged along the roof-level ventilation area, was closer to unity, indicating that turbulent motions mainly affected pollutant removal from the top of the canyon. As aspect ratio increased, the relative contribution became smaller, owing to strong upwind motions. However, the relative contribution again reached near unity for the infinite aspect ratio (i.e. a two-dimensional street canyon) because of lowered lateral flow convergence. At least 75 % of total emissions from the three-dimensional street canyon were attributable to turbulent motions. Pollutant removal by turbulent motions was related to the coherent structures of low-momentum fluid above the canyons. Though the coherent structure size of the low-momentum fluid differed, the positions of low-momentum fluid largely corresponded to instantaneous high concentrations of pollutant above the target canyon, irrespective of canyon geometry.     

Transient crater growth in granular targets: An experimental study of low velocity impacts into glass sphere targets

We experimentally studied the formation and collapse processes of transient craters. Polycarbonate projectiles with mass of 0.49 g were impacted into the soda-lime glass sphere target (mean diameters of glass spheres are ∼36, 72, and 220 μm, respectively) using a single-stage light-gas gun. Impact velocity ranged from 11 to 329 m s⁻¹. We found that the transient crater collapses even at laboratory scales. The shape (diameter and depth) of the transient crater differs from that of the final crater. The depth-rim diameter ratios of the final and transient craters are 0.11-0.14 and 0.26-0.27, respectively. The rim diameter of both the transient and final crater depends on target material properties; however, the ratio of final to transient crater diameter does not. This suggests that target material properties affect the formation process of transient craters even in the gravity regime, and must be taken into account when scaling experimental results to planetary scales. By observing impacts into glass sphere targets, we show that although the early stage of the excavation flow does not depend on the target material properties, the radial expansion of the cavity after the end of vertical expansion does. This suggests that the effect of target material properties is specifically important in the later part of the crater excavation and collapse.     

Solid‐state 13C NMR characterization of insoluble organic matter from Antarctic CM2 chondrites: Evaluation of the meteoritic alteration level

Abstract— Chemical structures of the insoluble organic matter (IOM) from the Antarctic CM2 chondrites (Yamato [Y‐] 791198, 793321; Belgica [B‐] 7904; Asuka [A‐] 881280, 881334) and the Murchison meteorite were analyzed by solid‐state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Different types of carbons were characterized, such as aliphatic carbon (Ali‐C), aliphatic carbon linked to hetero atom (Hetero‐Ali‐C), aromatic carbon (Aro‐C), carboxyls (COOR), and carbonyls (C=O). The spectra of the IOM from Murchison and Y‐791198 showed two major peaks: Ali‐C and Aro‐C, while the spectra from the other meteorites showed only one major peak of Aro‐C. Carbon distribution was determined both by manual integration and deconvolution. For most IOM, the Aro‐C was the most abundant (49.8–67.8%) of all carbon types. When the ratios of Ali‐C to Aro‐C (Ali/Aro) were plotted with the atomic hydrogen to carbon ratio (H/C), a correlation was observed. If we use the H/C as a parameter for the thermal alteration event on the meteorite parent body, this result shows a different extent of thermal alteration. In addition, IOM with a lower Ali/Aro showed a lower ratio of Ali‐C to COOR plus C=O (Ali / (COOR + C=O)). This result suggests that the ratio of CO moieties to aliphatic carbon in IOM might reflect chemical oxidation that was involved in hydrothermal alteration.     

VIDEO AND PHOTOGRAPHIC SPECTROSCOPY OF 1998 AND 2001 LEONID PERSISTENT TRAINS FROM 300 TO 930 nm

Spectra of persistent meteor trains were observed at wavelength between 300 and 930 nm. Two obtained train spectra during the 1998 and 2001 Leonid meteor showers are reported here. During the 1998 Leonids, one train was detected by a photographic camera with a spectrograph covering 370–640 nm region. On the other hand, during the 2001 Leonids, video observations were carried out using image intensified cameras in ultraviolet (UV), visible and near infrared (near-IR) wavelengths. Temperatures in persistent trains have been measured by atmospheric O₂ A(0,1) band at the wavelength near 864.5 nm. From a video spectrum obtained just 7 s after parent fireball’s flare, a rotational temperature of 250 K at altitude of 88.0±0.5 km was estimated. We can say that the cooling time scale of train strongly depends on the initial mass of its fireball at least for Leonids. Based on cooling constant calculated from our results, we estimated a temperature of ∼ ∼130 K as a final exothermic temperature at early stage of persistent trains.