Neodymium isotopic variations in Northwest Pacific waters

Four vertical profiles of the concentration and isotopic composition of Nd in seawater were obtained in the western North Pacific. Two profiles from the Kuroshio Current regime showed congruently that although the Nd concentration increases gradually with depth, its isotopic composition varies significantly with depth depending upon the water mass occupying the water column. The high-salinity Kuroshio waters originating from the North Pacific Tropical Water (NPTW) carry the least radiogenic Nd (?_Nd = −7.4 to −8.7) to this region at ∼250 m from the western margin continental shelves, most likely from the East China Sea. The Nd isotopic compositions in the North Pacific Intermediate Water (NPIW) that occurs at 600 to 1000 m in the subtropical region are fairly uniform at ?_Nd = −3.7. The profile data from the ∼38° to 40°N Kuroshio/Oyashio mixed water region off Sanriku of Honshu, Japan, also suggest that the newest NPIW with ?_Nd = −3.2 is formed there by the mixing of various source waters, and the radiogenic component of Nd is derived mainly from the Oyashio waters.In the Pacific Deep Water (PDW) below ∼1000 m, the Nd isotopic composition is neither vertically nor horizontally homogeneous, suggesting that it serves as a useful tracer for sluggish deep water circulation as well. Two profiles from the Izu-Ogasawara Trench showed a minimum ?_Nd value at ∼2000 m, suggesting that there exists a horizontal advective flow in the vicinity of Honshu, Japan. There is some evidence from other chemical properties to support this observation. The waters below 4000 m including those within the trench in the subtropical region have ?_Nd values of around −5, suggesting that the deep waters are fed from the south along the western boundary, ultimately from the Antarctic Bottom Water (AABW) in the South Pacific. This extends up to ∼40°N along the Japanese Islands. In the subarctic region (>∼42°N), the waters have more radiogenic Nd with ?_Nd > −4.0 throughout the water column, presumably due to the supply of Nd by weathering in such igneous provinces as the Kuril-Kamchatska-Aleutian Island chain. The lateral inhomogeneity of the Nd isotopic composition in PDW suggests that there may be different circulation and mixing regimes in the North Pacific Basin.     

Formation and shortening deformation of a back-arc rift basin revealed by deep seismic profiling, central Japan

The northern Fossa Magna (NFM) basin is a Miocene rift system produced in the final stages of the opening of the Sea of Japan. It divides the major structure of Japan into two regions, with north-trending geological structures to the NE of the basin and EW trending structures to the west of the basin. The Itoigawa-Shizuoka Tectonic Line (ISTL) bounds the western part of the northern Fossa Magna and forms an active fault system that displays one of the largest slip rates (4–9 mm/year) in the Japanese islands. Deep seismic reflection and refraction/wide-angle reflection profiling were undertaken in 2002 across the northern part of ISTL in order to delineate structures in the crust, and the deep geometry of the active fault systems. The seismic images are interpreted based on the pattern of reflectors, the surface geology and velocities derived from refraction analysis. The 68-km-long seismic section suggests that the Miocene NFM basin was formed by an east dipping normal fault with a shallow flat segment to 6 km depth and a deeper ramp penetrating to 15 km depth. This low-angle normal fault originated as a comparatively shallow brittle/ductile detachment in a high thermal regime present in the Miocene. The NFM basin was filled by a thick (>6 km) accumulation of sediments. Shortening since the late Neogene is accommodated along NS to NE–SE trending thrust faults that previously accommodated extension and produce fault-related folds on their hanging wall. Based on our balanced geologic cross-section, the total amount of Miocene extension is ca. 42 km and the total amount of late Neogene to Quaternary shortening is ca. 23 km.     

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Quantitative assessment on the influence of heavy rainfall on the crystalline schist landslide by monitoring system -case study on Zentoku landslide, Japan

On Shikoku Island, which is one of the four main islands of Japan, a large number of large-scale crystalline schist landslides have been revealed and are being monitored by an observation system. Seasonal heavy rainfall is the most active meteorological factor that can threaten the stability of this kind of site-specific landslide. In this paper, on the basis of the study of the rainfall-related behavior of a typical crystalline schist landslide, the Zentoku landslide, by analyzing the precisely and continuously observed piezometric and movement data, a method was developed to quantitatively assess the effect of heavy rainfall on a large-scale landslide. The results indicated that heavy rainfall-induced landslide displacement shows good correlation with the variation of groundwater levels. Variations of groundwater level have been simulated with the use of a tank model. The simulation using this model permits the change in water levels for future rainfall events to be predicted. By combining the predicted results with the empirical relation between displacements and water levels, rainfall-induced landslide movement during extreme rainfall events can be estimated in advance. The effect of heavy rainfall on sliding behavior can be quantified in terms of the change in displacement. Thus warning information or advisories for the local residents can be provided.     

Geochemical fixation of rare earth elements into secondary minerals in sandstones beneath a natural fission reactor at Bangombé, Gabon

To study geochemical processes for migration and fixation of fissiogenic rare earth elements (REE) in association with uranium dissolution, in situ isotopic analyses using an ion microprobe were performed on U- and REE-bearing secondary minerals, such as coffinite, françoisite, uraniferous goethite, and uraninite found in a sandstone layer 30 to 110 cm beneath a natural fission reactor at Bangombé, Gabon. Phosphate minerals such as phosphatian coffinite and françoisite with depleted ²³⁵U (²³⁵U/²³⁸U = 0.00609 to 0.00638) contained large amount of fissiogenic light REE, while micro-sized uraninite grains in a solid bitumen aggregate have normal U isotopic values (²³⁵U/²³⁸U = 0.00725) and small amount of fissiogenic REE components. The proportions of fissiogenic and non-fissiogenic REE components in four samples from the core of BAX03 vary in depth ranging from 30 cm to 130 cm beneath the reactor, which suggests mixing between fissiogenic isotopes from the reactor and non-fissiogenic isotopes from original minerals in the sandstone. Significant chemical fractionation was observed between Ce and the other REE in the secondary minerals, which shows evidence of an oxidizing atmosphere during their formation. Pb-isotopic analyses of individual minerals do not directly provide chronological information because of the disturbance of U-Pb decay system due to recent geologic alteration. However, systematic Pb-isotopic results from all of the minerals reveal the mobilization of fissiogenic isotopes, Pb and U from the reactor in association with dolerite dyke intrusion ∼0.798 Ga ago and the formation of the secondary minerals by mixing event between 2.05 Ga-old original minerals and reactor materials due to recent alteration.     

U-Pb and Pb-Pb ages of zircons from basaltic eucrites: Implications for early basaltic volcanism on the eucrite parent body

We have undertaken petrologic and SHRIMP U-Th-Pb isotopic studies on zircons from basaltic eucrites (Yamato [Y]-75011, Y-792510, Asuka [A]-881388, A-881467 and Padvarninkai) with different thermal and shock histories. Eucritic zircons are associated with ilmenite in most cases and have subhedral shapes in unmetamorphosed and metamorphosed eucrites. Some zircons in highly metamorphosed eucrites with granulitic texture occur alone in pyroxene, and typically have rounded to subrounded shapes due to recrystallization. Superchondritic Zr/Hf ratios of eucritic zircons indicate that they crystallized from incompatible element-rich melts after crystallization of ilmenite. Concentrations of uranium and thorium in zircons in the unmetamorphosed eucrite Y-75011 are higher than those in metamorphosed eucrites.The U-Pb systems of eucritic zircons are almost concordant but some zircon grains show reverse discordance. Radiogenic lead-loss up to 48% from zircons is observed in the shock-melted eucrite Padvarninkai. The ²⁰⁷Pb-²⁰⁶Pb ages of zircon in Y-75011 (4550 ± 9 Ma, n = 5) are nearly identical, within analytical uncertainty, to the ages of zircons from the metamorphosed eucrite Y-792510 (4545 ± 15 Ma, n = 13), the highly metamorphosed eucrites A-881388 (4555 ± 54 Ma, n = 5) and A-881467 (4558 ± 13 Ma, n = 8), and the shock-melted eucrite Padvarninkai (4555 ± 13 Ma, n = 18). The averaged ²⁰⁷Pb-²⁰⁶Pb age of zircon from five eucrites analyzed in this study is 4554 ± 7 Ma (95% confidence limits, n = 49), indistinguishable from the averaged U-Pb age (4552 ± 9 Ma) of the same samples. Because of the high closure temperature of lead in zircon (T_closure = ∼1050°C with a cooling rate of 0.2°C/yr), the ²⁰⁷Pb-²⁰⁶Pb ages of eucritic zircon do not represent metamorphic ages but crystallization ages of extrusive lavas.This fact strongly suggests that volcanism of the eucrite parent body occurred at a very early stage of the Solar System history, 7-20 Ma after CAI formation (4567.2 ± 0.6 Ma), thus basaltic eucrites crystallized from parental magmas within a short interval following the differentiation of their parent body. The U-Pb ages of eucritic zircons are older than the U-Pb, Sm-Nd and Rb-Sr ages of some basaltic eucrites, which is consistent with differences in closure temperatures of each isotopic system, and suggests that thermal and shock metamorphism affected the isotopic systems of pyroxene, plagioclase and phosphates.     

Variations of Kuroshio geostrophic transport south of Japan estimated from long-term IES observations

Two inverted echo sounders were maintained on coastal and offshore sides of the Kuroshio south of Japan from October 1993 to July 2004. Applying the gravest empirical mode method, we obtained a time series of geostrophic transport. Estimated transports generally agree well with geostrophic transports estimated from hydrography. Their agreement with the hydrographic transports is better than that of transports estimated from satellite altimetry data. The geostrophic transport is expressed as the surface transport per unit depth multiplied by the equivalent depth. The geostrophic transport varies mostly with the surface transport and fractionally with the equivalent depth. Seasonal variation of the geostrophic transport has a minimum in March and a maximum in September, with a range of about one fifth of the total transport.     

MOS-1/1b MESSR Observations of the Antarctic Sea Ice: Ice Bands and Ice Streamers

Meso- or submeso-scale features of the Antarctic sea ice are investigated using the MOS-1/1b MESSR Images (spatial resolution of approximately 50 m) received at Syowa Station. Particular attention is paid to the ice bands and ice streamers in coastal polynyas. In the Antarctic Ocean, ice bands can be often seen not only at the ice edge but also in the ice interior zone throughout the year and they extend for hundreds of kilometers in the latitudinal direction. It is found that the width and spacing of ice bands tend to decrease from winter to summer. The width of ice band is about 2–6 km in August and September, and 0.1–0.7 km in December. The spacing of ice bands is about 3–10 km in August and September, and 0.1–2 km in December. In coastal polynyas, ice streamers, which are composed of new ice, are sometimes observed. In general, the row of the streamers is spaced at 0.5–2 km with a width of 0.1–1.0 km.     

The Current System in the Yellow and East China Seas

During the 1990s, our knowledge and understanding of the current system in the Yellow and East China Seas have grown significantly due primarily to new technologies for measuring surface currents and making high-resolution three-dimensional numerical model calculations. One of the most important new findings in this decade is direct evidence of the northward current west of Kyushu provided by satellite-tracked surface drifters. In the East China Sea shelf region, these recent studies indicate that in winter the Tsushima Warm Current has a single source, the Kuroshio Branch Current in the west of Kyushu, which transports a mixture of Kuroshio Water and Changjiang River Diluted Water northward. In summer the surface Tsushima Warm Current has multiple sources, i.e., the Taiwan Warm Current, the Kuroshio Branch Current to the north of Taiwan, and the Kuroshio Branch Current west of Kyushu. The summer surface circulation pattern in the East China Sea shelf region changes year-to-year corresponding to interannual variations in Changjiang River discharge. Questions concerning the Yellow Sea Warm Current, the Chinese Coastal Current in the Yellow Sea, the current field southwest of Kyushu, and the deep circulation in the Okinawa Trough remain to be addressed in the next decade. This revised version was published online in August 2006 with corrections to the Cover Date.