Four lunar mare meteorites: Crystallization trends of pyroxenes and spinels

Abstract— We studied crystallization trends of pyroxene and spinel in four Antarctic meteorites known to be derived from mare regions of the Moon: Y-793169 and A-881757 (YA meteorites) are unbrecciated igneous basalts, EET 87521 is a fragmental breccia, and Y-793274 is a regolith breccia. All have relatively low bulkrock TiO₂ content, and the YA meteorites are uncommonly ancient. Our electron probe microanalysis (EPMA) data indicate that the YA meteorites and the dominant mare components of Y-793274 and EET 87521 conform to a general trend for Ti-poor (low-Ti and very low-Ti) mare basalts. Their pyroxenes show a strong correlation between Fe/(Fe + Mg) (Fe#) and Ti/(Ti + Cr) (Ti#), both ratios typically increasing from core to rim. These trends presumably reflect local crystallization differentiation of interstitial melt. Previous studies (M. J. Drake and coworkers) have suggested that the detailed configurations of such Fe# vs. Ti# trends may reflect the bulk TiO₂ contents of the parent magmas (basalts). As a more systematic approach to this problem, we plot bulk-rock TiO₂ as a function of the Fe# = 0.50 intercept of each rock's pyroxene Fe# vs. Ti# trend. We call this intercept the Fe#-normalized Ti#. Based on our data for EET 87521, the YA meteorites, and Apollo 12 basalts 12031 and 12064, plus literature data for several other Ti-poor mare basalts, we find a strong correlation between Fe#-normalized Ti# and the bulk TiO₂ content of the parent basalt. This correlation confirms that fragmental breccia EET 87521 is nearly pure very low-Ti (VLT) basalt and that the YA meteorites, for which bulk-rock TiO₂ results scatter due to unusually coarse grain size (A-881757) or scarcity of available sample (Y-793169), are pieces of an uncommonly Ti-poor, but not quite VLT, variety of low-Ti mare basalt. Extrapolating from this correlation, the dominant mare component of regolith breccia Y-793274 is probably of VLT affinity. Besides the normal mare pyroxene trend of strong correlation between Fe# and Ti#, Y-793274 includes two additional pyroxene compositional trends, both showing a wide range of Ti# despite relatively constant (and low, by mare standards) Fe#. The most magnesian of these trends consists of a single clast with a mode of orthopyroxene + MgO-rich ilmenite. These two trends are of uncertain origin. Possibly one or both represents the highland component of this regolith breccia, although, unlike most highland pyroxenes, these appear relatively unaltered by impact brecciation and metamorphism. Compositions of spinels in the coarse-grained A-881757 show an extraordinary distribution: chromite and ulvöspinel components vary among grains but are nearly constant within grains. Despite its old age and unusually coarse grain sizes, mineralogical evidence (i.e., heterogeneity within both pyroxene and spinel; typical pyroxene exsolution scale very coarse by mare standards but exceeded by the pyroxenes of EET 87521 and Y-793274) indicates that A-881757 was cooled only slightly more slowly than typical mare basalts and may have formed near the center of an uncommonly thick lava flow. Both of the VLT basaltic lunar meteorite breccias, EET 87521 and Y-793274, are composed dominantly of pyroxenes with exsolution coarser than normal for mare basalts. Possibly VLT basalt flows tend to be systematically thicker, and thus more slowly cooled, than more Ti-rich flows.     

Crustal movement along a collision boundary of plates (case of eastern Taiwan)

Recent crustal movements in eastern Taiwan were investigated based on geodetic and seismological data as a case study of the tectonics along a colliding plate boundary. Secular horizontal strain along the Longitudinal Valley, a probable arc-continent collision boundary between the Philippine Sea and Eurasion plates, is compressive with a large rate of 2 microstrains/year, and the maximum compression axis trends in NW-SE direction. This means that nearly two-thirds of the convergence rate between the two plates is consumed in the narrow zone along the valley and confirms the view that the valley is the plate boundary between the two. The amount of uplift in the Central Range, deduced from trigonometric leveling, reaches more than one meter during the past 60 years. Such active orogeny is caused by the high strain rate in this area. Horizontal displacement of the Coastal Range, a leading edge of the Philippine Sea plate, has a left-lateral component, suggesting that the boundary is a region of oblique collision and the range moves toward the north, producing subduction of the Philippine Sea plate off the Coast of northeastern Taiwan.An extensional strain pattern is found northeastern Taiwan near Hualien, in northern Taiwan near Ilan, and in southeastern Taiwan south Taitung. In northeastern Taiwan, the direction of the maximum extension axis is nearly parallel to the isodipth contours of deep-focus earthquakes that occurred under the southern part of the Ryukyu Trench. From a model calculation using a finite-element method, this pattern of strain is interpreted as an edge effect of the collision-subduction junction in northeastern Taiwan. The direction of the maximum extension in northern Taiwan forms high angles with the direction of the tectonic line near Ilan stretching from the Okinawa Trough. This fact is harmonious with the view that the Okinawa Trough is spreading. Extensional strain observed in southeastern Taiwan may be related to the eastward subduction since the area is situated on a transition zone, from collision to subduction.     

Ar‐Ar and I‐Xe ages and the thermal history of IAB meteorites

Abstract— Studies of several samples of the large Caddo County IAB iron meteorite reveal andesitic material enriched in Si, Na, Al, and Ca, which is essentially unique among meteorites. This material is believed to have formed from a chondritic source by partial melting and to have further segregated by grain coarsening. Such an origin implies extended metamorphism of the IAB parent body. New ³⁹Ar‐⁴⁰Ar ages for silicate from three different Caddo samples are consistent with a common age of 4.50‐4.51 Gyr. Less well‐defined Ar‐Ar degassing ages for inclusions from two other IABs, EET (Elephant Moraine) 83333 and Udei Station, are ?4.32 Gyr, whereas the age for Campo del Cielo varies considerably over about 3.23‐4.56 Gyr. New ¹²⁹I‐¹²⁹Xe ages for Caddo County and EET 83333 are 4557.9 ± 0.1 Myr and 4557–4560 Myr, respectively, relative to an age of 4562.3 Myr for Shallowater. Considering all reported Ar‐Ar degassing ages for IABs and related winonaites, the range is ?4.32‐4.53 Gyr, but several IABs give similar Ar ages of 4.50‐4.52 Gyr. We interpret these older Ar ages to represent cooling after the time of last significant metamorphism on the parent body and the younger ages to represent later ⁴⁰Ar diffusion loss. The older Ar‐Ar ages for IABs are similar to Sm‐Nd and Rb‐Sr isochron ages reported in the literature for Caddo County. Considering the possibility that IAB parent body formation was followed by impact disruption, reassembly, and metamorphism (e.g., Benedix et al. 2000), the Ar‐Ar ages and IAB cooling rates deduced from Ni concentration profiles in IAB metal (Herpfer et al. 1994) are consistent if the time of the postassembly metamorphism was as late as about 4.53 Gyr ago. However, I‐Xe ages reported for some IABs define much older ages of about 4558–4566 Myr, which cannot easily be reconciled with the much younger Ar‐Ar and Sm‐Nd ages. An explanation for the difference in radiometric ages of IABs may reside in combinations of the following: a) I‐Xe ages have very high closure temperatures and were not reset during metamorphism about 4.53 Gyr ago; b) a bias exists in the ⁴⁰K decay constants which makes these Ar‐Ar ages approximately 30 Myr too young; c) the reported Sm‐Nd and Rb‐Sr ages for Caddo are in error by amounts equal to or exceeding their reported 2‐sigma uncertainties; and d) about 30 Myr after the initial heating that produced differentiation of Caddo silicate and mixing of silicate and metal, a mild metamorphism of the IAB parent body reset the Ar‐Ar ages.     

A scheme to treat the singularity in global seismic wavefield simulation using pseudospectral method with staggered grids

The pseudospectral method has been applied to the simulation of seismic wave propagation in 2-D global Earth model. When a whole Earth model is considered, the center of the Earth is included in the model and then singularity arises at the center of the Earth where <i<r</i<=0 since the 1/<i<r</i< term appears in the wave equations. In this paper, we extended the global seismic wavefield simulation algorithm for regular grid mesh to staggered grid configuration and developed a scheme to solve the numerical problems associated with the above singularity for a 2-D global Earth model defined on staggered grid using pseudospectral method. This scheme uses a coordinate transformation at the center of the model, in which the field variables at the center are calculated in Cartesian coordinates from the values on the grids around the center. It allows wave propagation through the center and hence the wavefield at the center can be stably calculated. Validity and accuracy of the scheme was tested by compared with the discrete wavenumber method. This scheme could also be suitable for other numerical methods or models parameterized in cylindrical or spherical coordinates when singularity arises at the center of the model.     

Increases of wet deposition at remote sites in Japan from 1991 to 2009

Temporal trends in wet deposition of major ions were explored at nationwide remote sites in Japan from April 1991 to March 2009 by using the seasonal Kendall slope estimator and the nonparametric seasonal Kendall test. For the trend analysis, datasets from eight remote sites (Rishiri, Echizenmisaki, Oki, Ogasawara, Shionomisaki, Goto, Yakushima, and Amami) were selected from the Japanese Acid Deposition Survey (JADS) conducted by the Ministry of the Environment. Deposition of H⁺ has been increasing at remote sites in Japan on a national scale. Significant (p????0.05) increases in H⁺ deposition were detected with changes of +3?C+9?%?year^?1 at seven sites, while insignificant increases were observed at one site. Depositions of non-sea salt (nss)-SO ₄ ^2? and NO ₃ ^? significantly increased at four and six sites, respectively, with changes of +1?C+3?%?year^?1. Significant increases in precipitation at four sites would have contributed to the increase in depositions of H⁺, nss-SO ₄ ^2? , and NO ₃ ^? . The emission trends of SO₂ and NO_x did not corresponded to the deposition trends of nss-SO ₄ ^2? and NO ₃ ^? . The different trends indicated that temporal variation of precipitation amount trend dominated the deposition trends.     

Origin of a magnetic lineation on Kyushu Island, Japan

Abstract Several linear magnetic anomalies over continental crust have been identified in and around the Japanese Islands. The anomalies are probably related to island arc tectonic structures, but identifying specific sources has been difficult. Several deep holes were drilled in and around Aso caldera, where a linear anomaly occurs along an active fault. One drillhole located on the linear anomaly encountered a zone of highly magnetized and altered basement rocks at least 100 m thick at a depth of ∼1000 m. The other hole was located away from the anomaly and did not encounter any high-magnetic zones. Rocks from the zone have exceptionally strong remanent magnetization (several tens of A/m) sub-parallel to the present field. AF demagnetization experiments indicated that the magnetization is hard and stable. Magnetic modeling indicates that the linear anomaly is caused mainly by this layer. Microscopic examination of core samples shows that the highly magnetized zone includes secondary magnetic minerals and abundant hydrothermal alterations. Temperatures determined by fluid inclusions and down-hole temperatures show that the temperature of the highly magnetized zone was elevated in the past relative to surrounding rocks. The high temperature could destroy primary magnetic minerals and replace them with secondary magnetic minerals. Thus, the past hydrothermal system may have enhanced thermo-chemical remanent magnetization. The results can produce a model indicating that there was a past hydrothermal system related to the tectonic structure.     

Effect of topography and subsurface inhomogeneity on seismic rayleigh waves

The effect of topography and subsurface inhomogeneity on surface motion is investigated in the case of Rayleigh waves. In the previous paper, the same effect was investigated in the case of SV waves. Several types of topography, such as cliffs both with and without a soft layer at the foot of the slope, are considered. Computations are made using a new hybrid method combining a particle model with a finite element method. In cases of harmonic Rayleigh waves, surface motions with amplitudes as large as 1.5 to 5 times the horizontal surface displacement of the incident Rayleigh waves are produced near the slope and the sloping interface. When a Rayleigh wave propagating through a hard single-layered ground encounters a sloping interface where hard ground and soft ground make contact with each other, Rayleigh waves having two different, phase velocities are produced and they correspond to the fundamental mode, and the first mode determined by Haskell's method. In addition, the transient response when Rayleigh waves propagate through the cliff is also simulated. Assuming the vertical component of the Tokachi-oki Earthquake (1968) measured on the surface to be a Rayleigh wave, the incident Rayleigh wave can be obtained by a Fourier synthesis of eigenfunctions of Rayleigh waves.     

Short-term variation in copepod community and physical environment in the waters adjacent to the Kuroshio Current

A continuous survey examined short-term variations in the zooplankton community and physical ocean environment from the northeastern Izu Islands to Boso Peninsula in Japan. High copepod abundance and small upwellings in the surface layer and salinity minimum layer in the subsurface were observed on the north side of coastal fronts in the westernmost transect, moving southward as the Kuroshio Current left the Boso Peninsula. Thus, the salinity minimum layer might be a key factor forming upwelling and the fronts, leading to large abundance of coastal copepods off the northeastern Izu Islands. A community structure analysis of calanoid copepods revealed an intermediate belt assemblage between coastal and offshore (Kuroshio) assemblages. Copepod abundance was remarkably low and Ctenocalanus vanus dominated (nearly 37%) in the intermediate belt zone, indicating that C. vanus has a relatively high tolerance to adverse environments for calanoid copepods. As the Kuroshio Current left the Boso Peninsula, the coastal assemblage expanded in the same direction, and the intermediate belt assemblage off the northeastern Izu Islands disappeared. The largest population of Calanus sinicus was found along the two western transects off the northeastern Izu Islands (>1000 m depth), which was assumed to be transported from Sagami Bay and advanced southwestward while growing from copepodite stages CIII to CV. Larvae of C. sinicus would be an important food for fish larvae in addition to Paracalanus parvus s.l., the numerically dominant species in the coastal assemblage, and C. vanus under the adverse conditions for coastal copepods.     

Geology of the Gorny Altai subduction–accretion complex, southern Siberia: Tectonic evolution of an Ediacaran–Cambrian intra-oceanic arc-trench system

The Gorny Altai region in southern Siberia is one of the key areas in reconstructing the tectonic evolution of the western segment of the Central Asian Orogenic Belt (CAOB). This region features various orogenic elements of Late Neoproterozoic–Early Paleozoic age, such as an accretionary complex (AC), high-P/T metamorphic (HP) rocks, and ophiolite (OP), all formed by ancient subduction–accretion processes. This study investigated the detailed geology of the Upper Neoproterozoic to Lower Paleozoic rocks in a traverse between Gorno-Altaisk city and Lake Teletskoy in the northern part of the region, and in the Kurai to Chagan-Uzun area in the southern part. The tectonic units of the studied areas consist of (1) the Ediacaran (=Vendian)–Early Cambrian AC, (2) ca. 630 Ma HP complex, (3) the Ediacaran–Early Cambrian OP complex, (4) the Cryogenian–Cambrian island arc complex, and (5) the Middle Paleozoic fore-arc sedimentary rocks. The AC consists mostly of paleo-atoll limestone and underlying oceanic island basalt with minor amount of chert and serpentinite. The basaltic lavas show petrochemistry similar to modern oceanic plateau basalt. The 630 Ma HP complex records a maximum peak metamorphism at 660 °C and 2.0 GPa that corresponds to 60 km-deep burial in a subduction zone, and exhumation at ca. 570 Ma. The Cryogenian island arc complex includes boninitic rocks that suggest an incipient stage of arc development. The Upper Neoproterozoic–Lower Paleozoic complexes in the Gorno-Altaisk city to Lake Teletskoy and the Kurai to Chagan-Uzun areas are totally involved in a subhorizontal piled-nappe structure, and overprinted by Late Paleozoic strike-slip faulting. The HP complex occurs as a nappe tectonically sandwiched between the non- to weakly metamorphosed AC and the OP complex. These lithologic assemblages and geologic structure newly documented in the Gorny Altai region are essentially similar to those of the circum-Pacific (Miyashiro-type) orogenic belts, such as the Japan Islands in East Asia and the Cordillera in western North America. The Cryogenian boninite-bearing arc volcanism indicates that the initial stage of arc development occurred in a transient setting from a transform zone to an incipient subduction zone. The less abundant of terrigenous clastics from mature continental crust and thick deep-sea chert in the Ediacaran–Early Cambrian AC may suggest that the southern Gorny Altai region evolved in an intra-oceanic arc-trench setting like the modern Mariana arc, rather than along the continental arc of a major continental margin. Based on geological, petrochemical, and geochronological data, we synthesize the Late Neoproterozoic to Early Paleozoic tectonic history of the Gorny Altai region in the western CAOB.