Isotopic anomalies of noble gases in meteorites and their origins—VII. C3V carbonaceous chondrites

Noble gases were measured in bulk samples of the C3V chondrites Grosnaja, Vigarano, and Leoville, and in HF,HCl-insoluble residues before and after etching with HNO₃. The residues were characterized by INAA and SEM. Gas components were determined, directly or by subtraction, for the following fractions: HF,HCl-solubles (?98% of the meteorite), ‘sphase Q’, a poorly characterized trace mineral that is insoluble in HCl-HF but soluble in HNO₃, and an insoluble residue, consisting of ferrichromite, carbonaceous matter, and spinel.Bulk meteorites show some correlation of the noble-gas pattern with McSween's subclasses: two ‘oxidized’ C3V's—Allende (LEWIS et al, 1975) and Grosnaja— have lower Ar/Xe but higher Ne/Xe ratios than the ‘reduced’ C3V's—Vigarano and Leoville—which are transitional to LL3's and C3O chondrites in both respects. An HCl-soluble mineral of high Ar/Xr ratio seems to be responsible. In other respects, the 3 C3V's of this study resemble Allende, with only moderate differences. Phase Q contains most of the Ar, Kr, Xe, but only small amounts of Ne; the etched residues contain planetary Ne ($\text{Ne}{}^{20}\text{Ne}{}^{22}\text{? 8.5}$) and the controversial CCFXe component, enriched in the heavy Xe isotopes ($\text{Xe136}\text{Xe132 ? 0.4–0.5}$). The CCFXe is accompanied by an ‘L-Xe’ component that is enriched in the light Xe isotopes. The proportion of the two is virtually constant in C3V's. as in all other C-chondrites. in contrast to the ~ 2-fold variation in ordinary chondrites.C3V's have systematically higher $\text{Xe}{}^{136}\text{Xe}{}^{132}$ ratios, and hence higher ratios of CCFXe to planetary Xe, than do other chondrite classes. This may reflect some peculiarity in their formation conditions, favoring uptake of CCFXe.     

Terrestrial heat flow around the aseismic front of the Japanese Island Arc

Very few data on heat flow are available in the area around the aseismic front of the Japanese Islands. In order to remedy this situation, measurements of the terrestrial heat flow were made at three locations in the eastern part of Fukushima Prefecture, northeastern Honshu, Japan. The observed values of heat flow were 37 mW/m² (0.88 μcal/cm²·s) at Soma, 52 mW/m² (1.25 μcal/cm²·s) at Kashima and 19 mW/m² (0.46 μcal/cm²·s) at Naraha, respectively. These data partially fill the gaps in the terrestrial heat flow data on land in northeastern Honshu, Japan. These values are considerably lower than the average heat flow over the world, but agree well with the previous estimation for the area.     

Ries impact crater,southern Germany: search for meteoritic material

Twenty-three samples from the Ries crater, representing a wide range of shock metamorphism, were analyzed for seven siderophile elements (Au, Ge, Ir, Ni, Os, Pd, Re) and five volatile elements (Ag, Cd, Sb, Se, Zn). Taking Ir as an example, we found siderophile enrichments over the indigenous level of 0.015 ppb Ir occur in only eight samples. The excess is very modest; even the most enriched samples (a weakly shocked biotite gneiss and a metal-impregnated amphibolite) have Ir, Os corresponding to ~4 × 10^?4 C1 chondrite abundances. Of five flädle glasses analyzed only one shows excess Ir. Suevite matrix and vesicular glass have slight enrichment, but homogenous glass from the same rock does not. In flädle glasses, Ni and Se are strongly correlated and apparently reside in Ir, Os-poor Sulfides [pyrrhotite, chalcopyrite, pentlandite(?)]of terrestrial, probably sedimentary, origin. The Ir, Os and Ni enrichments of the metal-bearing amphibolite are compatible with chondritic ratios, but these are ill-defined because of uncertainty in Ni. In the other samples enriched in siderophiles Ir(Os), Ni and Se are mutually correlated; $\text{Ni}\text{Ir}$ and $\text{Ni}\text{Os}$ ~ 11 × C1 and are much higher than any chondritic ratios; $\text{Se}\text{Ni}\text{~ 2 × C1}$ and suggests a sulfide phase, rather than metal may be the host of the correlated elements. Lacking a plausible local source, this material is apparently meteoritic in origin. The unusual elemental ratios, coupled with the very low enrichments, tend to exclude chondrites and most irons as likely projectile material. Of the achondrites, aubrites seem slightly preferable. Ratios of excess siderophiles in Ries materiel match tolerably those of an aubrite (possibly atypical) occurring as an inclusion in the Bencubbin meteorite, Australia. The Hungaria group of Mars-crossing asteroids may be a source of aubritic projectiles.     

Strontium and hydrogen isotope geochemistry of fresh and metabasalt dredged from the Mid-Atlantic Ridge

Fresh basalt and metabasalt dredged from the Mid-Atlantic Ridge were studied for Na, K, Rb, Sr, and H₂O(+) contents, and strontium and hydrogen isotope ratios. Na, K, Rb, and Sr contents of these samples are within the range of those of oceanic tholeiite. H₂O(+) content, strontium, and hydrogen isotope ratios vary widely. The variation in water content of metabasalt is apparently related to the chlorite content. The metamorphic temperature was about 550 °C based on the estimated δD value of chlorite. There is positive linear relationship between water content and strontium isotope ratio. Based on this relationship, the variation of strontium isotope ratio of the metabasalt was interpreted as follows: complete exchange occurred between strontium in the chlorite portion of the metabasalt and strontium in sea water (⁸⁷Sr/⁸⁶Sr ratio=0.7090), while the original strontium (⁸⁷Sr/⁸⁶Sr∼0.7023) was retained in the non-altered portion of the basalts.     

S-wave velocity structures of sediments estimated from array microtremor records and site responses in the near-fault region of the 1999 Chi-Chi,Taiwan earthquake

The 1999 Chi-Chi, Taiwan earthquake, M_W = 7.6, caused severe damage in the near-fault region of the earthquake. In order to evaluate site effects in the near-field strong motions we estimate S-wave velocity structures of sediments at four sites using array records of microtremors. We also recalculated S-wave velocity structures at other four sites previously reported. To show the validity of the estimated S-wave velocity structures we separate empirical site responses from aftershock records using the generalized inversion method and show the agreement between empirical and theoretical site responses. We also show an observed fact that suggests soil nonlinearity during the Chi-Chi earthquake by comparing horizontal-to-vertical spectral ratios (HVRs) for main shock records with HVRs for aftershock records. Then we calculate one-dimensional equivalent-linear site responses using the estimated S-wave velocity structures and the main shock records observed on the surface. It is found that site amplification due to thick (about 6 km) sediments is one of the important factors for explaining the long-period velocity pulses of about 5 to 10 sec observed at sites in the footwall during the Chi-Chi earthquake. It is also found that the theoretical site responses of shallow soft sediments at sites that sustained severe damage in the hanging wall shows significant amplification around 1 sec. As the amplitude of velocity pulses with period around 1 sec is most critical in causing damage to ordinary buildings of moderate heights, our results suggest that the 1-sec period velocity pulses, amplified by the site response of shallow sediments should contribute to the severe damage during the Chi-Chi earthquake.     

The Apsidal Antialignment of the HD 82943 System

We perform numerical simulations to explore the dynamical evolution of the HD 82943 planetary system. By simulating diverse planetary configurations, we find two mechanisms of stabilizing the system: the 2:1 mean motion resonance (MMR) between the two planets can act as the first mechanism for all stable orbits. The second mechanism is a dynamical antialignment of the apsidal lines of the orbiting planets, which implies that the difference of the periastron longitudes ₃ librates about 180° in the simulations. We also use a semi-analytical model to explain the numerical results for the system under study.     

Effects of deposit feeder Stichopus japonicus on algal bloom and organic matter contents of bottom sediments of the enclosed sea

Algae growing in an enclosed sea may inhibit eutrophication because they absorb nutrients in the water. However, dead algae often cause anaerobic conditions in the water just above and on sediment after they are deposited on the bottom. We found that Stichopus japonicus inhibited the anaerobic processes coupling water sulfite production in sediment. The present study investigates whether S. japonicus inhibits algal flourish and influences sediment properties such as organic matter contents. Aquarium experiments were carried out at Komatsushima port in Tokushima Prefecture, western Japan. The aquaria used in the experiments were supplied with water directly from the adjacent sea (6 L/min), laid with sand of 10 cm depths, and lighted at 12 h intervals. Six aquaria each containing a sea cucumber from Komatsushima port and six aquaria without any were used in the experiments. Water temperature ranged between 9 and 15 degrees C during December 2000 and April 2001. Salinity ranged between 32 per thousand and 34 per thousand. Algae began to cover the bottom of the aquaria without S. japonicus after 2 weeks, whereas no growth was evident in the aquaria containing sea cucumbers. Chlorophyll a concentration in the surface sediment of the aquaria with S. japonicus (6.1+/-3.6 microg/g, mean S.D.+/-standard deviation) was significantly lower than that without it (60+/-17 microg/g, U-test, p<0.05). Phaeophytin concentration in the surface sediment of the aquaria with S. japonicus (0.9+/-0.09 microg/g) was also significantly lower than that without it (4.5+/-1.0 microg/g, U-test, p<0.05). TOC concentration in the surface sediment of the aquaria with S. japonicus (2.6+/-1.3 microg/g) was slightly lower than that without it (4.0+/-1.2 microg/g). These results showed that algal biomass and organic matter concentration of the bottom were decreased in the presence of S. japonicus. Therefore, S. japonicus inhibits algal bloom and decrease the contents of organic matter deposited on the bottom of enclosed sea areas.     

Résultats préliminaires sur la sédimentation pélagique de l'Atlantique tropical au Crétacé et au Tertiaire (plateau de Demerara,Leg ODP 207)

Five sites located on a bathymetric transect of the distal Demerara Rise were studied by ODP Leg 207. Albian sediments of essentially terrigenous nature (clay, siltstone, sandstone) are the oldest drilled stratigraphic levels and form apparently the top of the synrift sequence. They are overlain by Cenomanian to Santonian finely laminated black shales, rich in organic matter of marine origin, which accumulated on a thermally subsiding ramp. Early Campanian hiatuses are thought to be the result of final disjunction of Demerara Rise (South America) from Africa and the onset of deep water communication between the two Atlantic basins (south and central). The overlying Uppermost Cretaceous–Oligocene chalk includes rich and diversified calcareous plankton assemblages, as well as two radiolarian-rich intervals (Late Campanian and Middle Eocene). A complex erosional surface developed during the Late Oligocene–Early Miocene. Sedimentation was impeded since then on the intermediate and deep sites of Demerara Rise, possibly due to the action of deep submarine currents. To cite this article: T. Danelian et al., C. R. Geoscience 337 (2005).