Persistent organic pollutants in marine biota of São Pedro and São Paulo Archipelago,Brazil

Remote islands, such as the São Pedro and São Paulo Archipelago (SPSPA), Brazil, are pristine areas. However, these locations are not exempt from the arrival of anthropogenic agents, such as persistent organic pollutants (POPs). The present study aimed to determine the occurrence and distribution of POPs in the marine biota of the SPSPA. Sample extractions were performed using a microwave-assisted method. The predominant compounds were PCBs and DDTs, which respectively had mean wet weight concentrations of 62.23 and 9.23 ng g⁻¹ in the tropical two-wing flying fish (Exocoetus volitans), 78.66 and 6.81 ng g⁻¹ in the brown booby (Sula leucogaster) and 43.40 and 3.03 ng g⁻¹ in the red rock crab (Grapsus grapsus). Low levels of contaminants suggest a relative degree of isolation. Occurrence and distribution profiles of PCBs support long-range atmospheric transport as the main source of contamination and demonstrate the ubiquity of these pollutants in the marine environment.     

Decline in heavy metal contamination in marine sediments in Jakarta Bay,Indonesia due to increasing environmental regulations

The ²¹⁰Pb geochronology, heavy metal concentrations (Zn, Cu, and Pb), and stable Pb isotope ratios (²⁰⁶Pb/²⁰⁷Pb) of three sediment cores collected from Jakarta Bay were analyzed to decipher the history of heavy metal contamination in the period 1900–2006. The chemical and isotopic analyses clearly suggest that anthropogenic metal accumulation in the sediments began in the 1920s and increased greatly from the 1970s until the end of the 1990s. From the end of the 1990s to 2006, accumulation rates were constant or decreased for Zn and Pb near the coastal industrialized area. Comparison of economic data and sociological information suggests that the decline in the concentrations of heavy metals could be attributed to the stricter environmental regulations which were enforced at the end of 1990s. However, metal contamination is currently still an important cause of concern in dealing with environmental preservation and protection in Jakarta Bay.     

Nuclear obscuration in the high-ionization Seyfert 2 galaxy Tol 0109–383

We report on the BeppoSAX detection of a hard X-ray excess in the X-ray spectrum of the classical high-ionization Seyfert 2 galaxy Tol 0109–383. The X-ray emission of this source observed below 7 keV is dominated by reflection from both cold and ionized gas, as seen in the ASCA data. The excess hard X-ray emission is presumably caused by the central source absorbed by an optically thick obscuring torus with N _H∼2×10²⁴ cm⁻² . The strong cold X-ray reflection, if it is produced at the inner surface of the torus, is consistent with the picture where much of the inner nucleus of Tol 0109–383 is exposed to direct view, as indicated by optical and infrared properties. However, the X-ray absorption must occur at small radii in order to hide the central X-ray source but leave the optical high-ionization emission-line region unobscured. This may also be the case for objects such as the Seyfert 1 galaxy Mrk231.     

On measuring settlement by magnetic method at any depth

Abstract

When artificial islands are constructed, they are subject to surface subsidence, which is the resultant sum of the consolidation strata, many of which seem differ in character. When these strata are soft and thick, or heavily loaded, it becomes very difficult to estimate how much settlement will eventually take place, and over how long a period. For the estimate to be accurate, the settlement characteristics of each layer must first be determined.

For this purpose, the authors have investigated a new method of measuring settlement, based on two unique principles. One principle is the application of a permanent magnet as an indicator of settlement, and the other is the exploitation of semiconductor, magneto‐resistance elements for detecting the magnetic fields. In advance of the observation, the magnets are forced into the earth, being pushed out through the bore‐hole casing by the oil jack at suitable depths and intervals. The small‐sized magneto‐resistance element is essential to the practicality and efficiency of this method.

In this study, the principles of this method, measuring procedure, the special characteristics and potential of this system, and the results of field trials are described.     

Degradation of common pharmaceuticals and personal care products in mixed solutions by advanced oxidation techniques

Widespread detection of pharmaceutical compounds in water environment has been a serious concern recently, while conventional sewage treatments are ineffective for their elimination. But, advanced oxidation techniques are very promising to remove varieties of organic contaminants in water. This research aims to elucidate oxidation potentials of sixteen commonly used pharmaceutical compounds in mixed solutions by seven advanced oxidation techniques in laboratory batch experiments. The removal profiles exhibited four distinct patterns: a) easily degradable by all seven techniques, b) not easily degradable by all seven techniques, c) easily degradable by ozone-based techniques, but not by ultraviolet radiation-based techniques and d) easily degradable by ultraviolet radiation-based techniques, but not by ozone-based techniques. Ozone-based techniques rather than ultraviolet radiation-based techniques were very powerful for simultaneous removal of the compounds efficiently. Moreover, ozonation combined with ultraviolet radiation was the most appropriate technique for simultaneous removal of the tested compounds efficiently. Increased ozone dissolution and decomposition with ozone-based techniques did not always enhance the compounds’ removal. Physicochemical properties of the compounds and solution pH also presumably played an important role on the removal which merits further attention.     

Effect of the variation in the lower tropospheric temperature on the wind onset of the Indian summer monsoon

There is a large thermal contrast between the Arabian Peninsula and India (Δθ _AI) at the mature stage of the Indian summer monsoon (ISM). The forming process of Δθ _AI is investigated analyzing various datasets. It forms earlier in the lower troposphere than in the middle and upper layers. The potential temperature in the lower troposphere over the west coast of India (θ _IW) abruptly decreases in advance of the rapid enhancement of the westerly wind over the Arabian Sea corresponding to the ISM onset. Such a process was observed for all the target years and the rapid decrease in θ _IW could trigger the ISM onset. The decrease in θ _IW had two patterns. In one case, cooler air is brought by the strong winds around a cyclone over the Arabian Sea. In another case, θ _IW decreases gradually by a synergy of a southwesterly wind over the Arabian Sea and the enlargement of Δθ _AI.     

Use of temperature profiles and stable isotopes to trace flow lines: Nagaoka area, Japan

In this study, we use borehole temperature data and stable isotopes to delineate the flow system and estimate the effect of urbanization in the Nagaoka area of Japan. Temperature profiles were measured four times in observation wells during the period 2000-2001 and compared with those measured in the same wells during the period 1977-1983 (Taniguchi 1986). Water was sampled in both observation and pumping wells during the same period. The temporal and spatial variability in temperature indicate clearly the effect of urban warming and heavy pumping on the ground water system. Urban warming caused higher temperatures recently as compared to the older values, and pumping caused induced recharge from the river to the ground water. The stable isotope data show the ground water flow system is divided into shallow, intermediate, and deep systems, and that land use and infiltration rate are affecting the shallow flow system.     

Statistical analysis for thermal data in the Japanese Islands

We calculated statistical average of thermal data to speculate regional thermal structure of the forearc area of the Japanese Islands. The three thermal statistical averages show a difference of a high thermal regime in the western part of forearc inner zone and a low in the Kanto forearc outer zone. The Kanto zone marks 18 K km⁻¹ for mean geothermal gradient, 44 mW m⁻² for mean heat flow, while the western inner zone shows 27 K km⁻¹ for mean geothermal gradient, 63 mW m⁻² for mean heat flow. The geothermal gradients of the Nobi Plain and the Osaka Plain in the western inner zone are 29 and 36 K km⁻¹, respectively, while the value of the Kanto Plain in the Kanto zone is 21 K km⁻¹. Taking account of the effect of accumulation of sediments, we see the difference in the thermal regime between the plains and conclude that the difference is significant. Heat flux in the crust depends on the volume of granite rich in radioactive elements. There are few granitic rocks in the Kanto zone, while granitic rocks are dominant in the western inner zone. The heat flow of 20 mW m⁻² is attributed to the granitic rocks of about 8 km in thickness. There are two oceanic plate subductions of the Pacific plate and the Philippine Sea plate under the Kanto zone, while only the Philippine Sea plate has been subducting under the western inner zone. The model simulation based on thermal and subduction model shows a heat flow ranging 50-60 mW m⁻² in the southwest Japan forarc area and a low value of about 20 mW m⁻² in the northeast Japan forearc area. The heat flux from the cooling oceanic lithosphere depends on the age of plate. The Shikoku Basin, a part of the Philippine Sea plate, off the western inner zone is 15-30 Ma, while the Pacific plate off the Kanto zone is 122-132 Ma. Theoretically, heat flux values of 15 and 50 Ma oceanic plates range 60-120 mW m⁻² and those of 122-132 Ma could be about 10 mW m⁻². If the heat flux contribution from the Philippine Sea plate under the Kanto zone is smaller than the plate under the western inner zone, there could be a thermal regime difference in order of several tens of mW m⁻². Conclusively, the cause of the difference of heat flux could be the uneven granitic rocks distribution and/or the difference of heat flux between the two subducting plate.