Evidence for recycled plate material in Pacific upper mantle unrelated to plumes

We report Sr, Nd, and Pb isotopic data of young alkaline basalt lava from a new type of volcano (petit-spot) on the northwestern Pacific Plate. Petit-spot lavas show Dupal, or extremely EM-1-like, Sr-Nd-Pb isotopic compositions. The data cannot be explained by contamination of pelagic sediment, in spite of the prediction on the basis of geological observation. We thus consider that the geochemistry of petit-spot lava indicates the existence of recycled fertile plate materials, not only the Dupal isotopic signature, in the northern hemisphere Pacific upper mantle unrelated to one or more active plumes. In consideration of published experimental results for fertile plate materials, selective melting of recycled material is a process critical in generating petit-spot lava. Moreover, the small volume of the volcano and low degree of melting in the mantle source needed to form strongly alkalic lavas suggest that petit-spot volcanism is originated from small-scale heterogeneities of recycled material. This idea consistently explains the geochemistry and noble gas isotopic composition of petit-spot lava, and also suggests small-scale heterogeneity widespread in the upper mantle of the Pacific Ocean. Together with a revised view of upper mantle heterogeneity, we propose that gross upper mantle composition is controlled by abundances and scales of regions of recycled material that correspond to differences in the relative position to the Pangea supercontinent, suggesting the link to the tectonic origin of the global scale heterogeneity.     

Kalman filtering in groundwater flow modelling: problems and prospects

The popularity of applying filtering theory in the environmental and hydrological sciences passed its first climax in the 1970s. Like so many other new mathematical methods it was simply the fashion at the time. The study of groundwater systems was not immune to this fashion, but neither was it by any means a prominent area of application. The spatial-temporal characteristics of groundwater flow are customarily described by analytical or, more frequently, numerical, physics-based models. Consequently, the state-space representations associated with filtering must be of a high order, with an immediately apparent computational over-burden. And therein lies part of the reason for the but modest interest there has been in applying Kalman filtering to groundwater systems, as reviewed critically in this paper. Filtering theory may be used to address a variety of problems, such as: state estimation and reconstruction, parameter estimation (including the study of uncertainty and its propagation), combined state-parameter estimation, input estimation, estimation of the variance-covariance properties of stochastic disturbances, the design of observation networks, and the analysis of parameter identifiability. A large proportion of previous studies has dealt with the problem of parameter estimation in one form or another. This may well not remain the focus of attention in the future. Instead, filtering theory may find wider application in the context of data assimilation, that is, in reconstructing fields of flow and the migration of sub-surface contaminant plumes from relatively sparse observations. Received: October 27, 1997     

Distribution of fault rocks in the fracture zone of the Nojima Fault at a depth of 1140 m: Observations from the Hirabayashi NIED drill core

Abstract Characteristics of deformation and alteration of the 1140 m deep fracture zone of the Nojima Fault are described based on mesoscopic (to the naked eye) and microscopic (by both optical and scanning electron microscopes) observations of the Hirabayashi National Research Institute for Earth Science and Disaster Prevention (NIED) drill core. Three types of fault rocks; that is, fault breccia, fault gouge and cataclasite, appear in the central part of the fault zone and two types of weakly deformed and/or altered rocks; that is, weakly deformed and altered granodiorite and altered granodiorite, are located in the outside of the central part of the fault zone (damaged zone). Cataclasite appears occasionally in the damaged zone. Six distinct, thin foliated fault gouge zones, which dip to the south-east, appear clearly in the very central part of the fracture zone. Slickenlines plunging to the north-east are observed on the surface of the newest gouge. Based on the observations of XZ thin sections, these slickenlines and the newest gouge have the same kinematics as the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake), which was dextral-reverse slip. Scanning electron microscopy observations of the freeze-dried fault gouge show that a large amount of void space is maintained locally, which might play an important role as a path for fluid migration and the existence of either heterogeneity of pore fluid pressure or strain localization.     

A study on the chemical forms of radionuclides in seawater—II chloride and sulfate complexes of60Co

The apparent stability constants for chloride and sulfate ions with Co (II) at ionic strength of 0.67 were determined by the cation exchange method. The value of the stability constant ₁ for chloride ion with Co (II) ion was 0.79±0.055. The stability constants ₁, ₂ and ₃ for sulfate ion with Co (II) ion were 12.0±0.27, 91.5±11.4 and l,110±250, respectively. The chemical species of Co (II) in seawater was estimated at the pH of 8.0 to be present as Co²⁺ (63%), CoCl⁺ (27%) and CoSO₄ ⁰ (8.6%) using the known value of dissociation constant of Co (II), and under the assumption that only major inorganic anions are responsible for the chemical equilibrium of Co (II).     

Urban climate simulation by incorporating satellite-derived vegetation cover distribution into a mesoscale meteorological model

Summary We simulated urban climate with surface boundary conditions based on satellite remote sensing (RS) data. Most previous mesoscale meteorological modeling studies use land-use data instead as the surface boundary conditions. However, small patches of vegetation-cover, such as roadside trees and garden trees, are excluded from the land-use data. Therefore, we made a fractional vegetation cover (FVC) dataset with these small patches of vegetation-cover from RS data, and then simulated the urban heat island in Tokyo with FVC data as new surface boundary conditions. In addition, we compared the above simulation results with results from a simulation that used only land-use data. The comparison shows that the air temperature with the new boundary condition is up to 1.5°C lower than that with the old boundary condition. Furthermore, the new boundary condition led to predicted air temperatures closer to the measured temperatures than those with the old boundary condition. Therefore, it is important for urban climate simulations to include small vegetation cover.     

Multi-approach characterization of shallow-water carbonates off Minamitorishima and their depositional settings/history

Sedimentological, geochemical, and chronological analyses were carried out on 18 carbonate rock samples collected at depths of 938, 1085, and 3354 m on the western slope of Minamitorishima (Marcus Island), which is located near the western margin of the Pacific Plate. Four groups of carbonate rocks were distinguished: a mollusk-rich limestone, a coral-rich dolomite, a foraminiferal-nannofossil packstone, and a phosphatized mudstone/wackestone. The mollusk-rich limestone is characterized by the dominance of bivalves (including rudists) and gastropod shells. Strontium isotope ratios (⁸⁷Sr/⁸⁶Sr) and Mesorbitolina ex gr. texana (a large benthic foraminifer) indicate that the shallow-water carbonates were deposited during the late Aptian–early Albian (ca. 123–111 Ma). The coral-rich dolomite is characterized by abundant scleractinian corals and nongeniculate coralline algae associated with encrusting acervulinid foraminifers. The biotic composition is similar to that of the Oligocene–Pleistocene carbonates reported from other seamounts in the northwestern Pacific. Geochemical data show that the coral-rich carbonates were dolomitized at 9.5–6.8 Ma (Tortonian–Messinian) and that normal seawater was the most likely parent fluid. The foraminiferal-nannofossil packstone is a semi-consolidated foraminiferal-nannofossil ooze and was deposited during the Pleistocene (0.99–0.45 Ma). The phosphatized mudstone/wackestone is marked by the absence of macrofossils and the presence of traces of planktic foraminifers. Although its depositional age is not constrained, the Sr isotope ratios indicate that the phosphatization occurred at 33.2–28.9 Ma. After the deposition of the Cretaceous shallow-water carbonates, including the mollusk-rich limestone, Minamitorishima was drowned and its top was covered with a pelagic cap, represented by the mudstone/wackestone. The late Eocene–early Oligocene volcanism (40.2–33.2 Ma) caused episodic uplift and returned the top of Minamitorishima to a shallow-water environment. After the early Oligocene phosphatization of the pelagic cap, coral reefs flourished on the top of this island. The reef limestone was dolomitized during the Tortonian–Messinian.     

Characteristics of observed turbulent mixing across the Antarctic Slope Front at 140°E, East Antarctica

The strength of mixing due to turbulence in the Antarctic Slope Front (ASF) region was investigated using CTD (conductivity-temperature-depth profilers) observations and direct measurements of turbulence conducted off Adélie Land, East Antarctica along 140°E from the 12th–14th February, 2005. The strongest horizontal gradient of the ASF was located below 300 m depth near the 1000 m isobath. The turbulent measurements revealed that the energy dissipation rate frequently exceeded 10^?8 Wkg^?1 on the continental shelf and upper slope regions. Turbulent diffusivities near the shelf break were higher than 10^?3 m²s^?1. Near the ASF the average turbulent heat flux was 5.7 Wm^?2 and 1.1 Wm^?2 across the temperature minimum layer to 250 m and from 300 to 600 m, respectively. The distribution of the high dissipation rate was consistently explained by the characteristic curve of the M2 internal wave emanating from the shelf break and continental slope. The water mass observed in the ASF below 300 m in the continental slope comprised Modified Circumpolar Deep Water and low salinity Shelf Water originating from either the upper layer of the Adélie Depression or the Adélie Bank, and produced by boundary mixing near the shelf break.     

Particle associated polycyclic aromatic hydrocarbons in the atmospheric environment of urban and suburban residential area

Ten polycyclic aromatic hydrocarbons associated with suspended particulate matter in the ambient air were collected at two sampling sites: urban and suburban residential areas of Yokohama, Japan from 1999 to 2005. The concentrations of target compounds were determined using gas chromatography-mass spectrometry. The total concentrations were higher in urban residential area than suburban residential area. They ranged from 0.31 to 6.16 ng/m3 withameanof2.07ng/m3 and 0.33 to2.87ng/m3 with a mean of 1.02 ng/m3 in the urban and suburban residential areas, respectively. The predominant compounds determined both in the urban and suburban residential areas were benzo[b]fluoranthene, benzo[ghi]perylene, indeno[1,2,3-cd]pyrene and benzo[e]pyrene. The concentrations of 5- and 6-ring polycyclic aromatic hydrocarbons were higher in the urban than the suburban residential area, accounting for 77.3 % and 72.1 % of total polycyclic aromatic hydrocarbons, respectively. Source identification was performed by principal component analysis. Two principal components were identified for each study area and these accounted for 95.9 % and 83.3 % of total variance, respectively. The results revealed that stationary source and vehicle emissions were the major pollution sources in the studied areas. The impact of emission regulations for automobiles in large Japanese cities, which were enacted during 2002 and 2003, was also studied. Based on the average total concentration, emission reduction was 47.8 % and 18.6 % in urban residential and suburban residential areas, respectively.     

Upwelling of oxygen-depleted water (Sumishio) in Omura Bay,Japan

Wind-induced circulation and the distribution of hypoxia corresponding to the upwelling of oxygen-depleted water (called “Aoshio” in Japan and “Sumishio” locally in Omura Bay) in Omura Bay, Japan, was examined field observations and by three-dimensional modeling. During the calm weather in summer, well-mixed strait water, in rich oxygen at the mouth of the bay intruded into the middle layer of the bay, southward and northward along the west and east coast, respectively, forming basin-scale cyclonic circulation. A stagnant water mass was formed below the center of this cyclonic circulation, and it became hypoxic water. As a result of the prevailing strong southeast (northeast) wind, the bottom hypoxia moved in a southeasterly (northeasterly) direction. This induces the upwelling of hypoxic water, accompanied by mass mortality of marine organisms.     

Laplace method to investigate subsurface geologic structures and its application

The ages of layered strata show a particular spatial distribution, and the bedding plane is isopotential surface of a scalar T(x, y, z) correlative to the age of a given stratigraphic horizon. The scalar T is obtained as the solution of boundary value problem of Laplace equation in power series, and the solution describes the three-dimensional geologic structures within an analytical space bounded by faults or unconformities on which the value of T jumps. The solution is termed the horizon function and consists of the datum succession and the structural part. The datum succession defines the relationship between the relative age (time-scale; T) and the thickness of strata (spatial scale; z) for undeformed horizontal strata. Geologic structures are described by the structural part of the solution composed by Fourier series, and the coefficients included there are determined by the least-square method using the dip and strike defined by particular combinations of the derivatives of T or the horizon data obtained in the area. The undersampled nature of geologic data is overcome by the selection of solution type, Eigenvalues, and boundary condition. Geological map and cross-sections are composed quantitatively and automatically by combining the spatial distribution of investigated T with the digital map defining the landform of the area. Test results were examined from this point of view. Improvement of the structural part to have the result fit completely the measured data is possible by introduction of the multiplying polynomials, although this concerns mathematical nature of the potential T.