The aerodynamic behaviour of volcanic aggregates

A large proportion of solid material transported within the atmosphere during volcanic eruptions consists of particles less than 500 m in diameter. The majority of these particles become incorporated into a wide range of aggregate types, the aerodynamic behaviour of which has not been determined by either direct observation or in the laboratory. In the absence of such data, theoretical models of fallout from volcanic plumes make necessarily crude assumptions about aggregate densities and fall velocities. Larger volcanic ejecta often consists of pumice of lower than bulk density. Experimental data are presented for the fall velocities of porous aggregates and single particles, determined in systems analogous to that of ejecta falling from a volcanic plume. It is demonstrated that the fall of aggregates may be modelled in identical fashion to single particles by using a reduced aggregate density dependent on the porosity, and a size corresponding to an enclosing sphere. Particles incorporated into aggregates attain a substantially higher fall velocity than single particles. This is due to the larger physical dimensions of the aggregate, which overcomes the effect of lower aggregate density. Additionally, the internal porosity of the aggregate allows some flow of fluid through the aggregate and this results in a small increase in fall velocity. The increase in fall velocity of particles incorporated into aggregates, rather than falling individually, results in the enhanced removal of fine material from volcanic plumes.     

Storage diagenesis versus sulphide authigenesis: possible implications in environmental magnetism

Experiments involving the gradual drying out of controlled mixtures of soil and organic lake sediment during storage at room temperature show that this leads to a loss of magnetic susceptibility and isothermal remanence greatly in excess of the initial values for the sediment components of the mixtures. We conclude that during storage in the moist state, soil-derived, fine-grained, ferrimagnetic iron oxides (magnetite and/or maghemite) are transformed to paramagnetic and/or imperfect antiferrimagnetic minerals. The imperfect anti-ferromagnetic component of the initial mixtures, which probably includes goethite, appears to survive and may even increase during storage. The experimental results compare well with the previously documented effects of storing wet sediment from the site, Peckforton Mere, Cheshire, U.K., over a comparable time interval. We conclude that transformation of fine grained ferrimagnets during storage diagenesis may be responsible for many of the examples of loss of magnetic susceptibility and remanence attributed by other authors solely to the oxidation of an iron sulphide such as greigite. Only where greigite is positively identified is it valid to infer a contribution from it to the magnetic properties of lake sediments: loss of susceptibility or remanence during storage is not alone a sufficient basis for such an inference. Early drying of samples will normally avoid the effects of storage diagenesis; and recent sediment samples so treated will, where greigite formation, bacterial magnetite and magnetite dissolution are insignificant, provide a valid basis for source identification on the basis of magnetic properties.     

Formation of pyrite in freshwater sediments: Implications for C/S ratios

The vertical distribution of pyrite, acid volatile sulphide (AVS), carbon, and total S (St) were determined directly in the sediments of three lakes of different trophic status. The results showed that freshwater pyrite formation reflects the redox status of the sediment or overlying waters. It appears to form chiefly in reducing sediments which are subject to oxidizing influences, by either a low turnover of organic carbon or periodic incursions of oxygen. Although there are high concentrations of AVS in the near-surface sediments of productive lakes, very little is diagenetically converted to pyrite.The feasibility of using sulphur ratios to diagnose whether rocks were formed in marine or freshwater environments is assessed. New values for FeS₂/FeS of 0.5-5 show that this ratio does not provide a reliable test. Values of C/Sp, where Sp represents pyrite sulphur, lie within the range of 160–700 and are much higher than previously measured ratios of C/S_t of 1–50. These new determinations show that, if pyrite sulphur is unequivocally measured, C/S ratios may be a more sensitive indicator of salinity than had been previously thought.     

Seasonal variations of the clear-sky greenhouse effect: the role of changes in atmospheric temperatures and humidities

We present an analysis of the factors which control the seasonal variations of the clear-sky greenhouse effect, based on satellite observations and radiative transfer simulations. The satellite observations include the radiation budget at the top of the atmosphere from the Earth Radiation Budget Experiment and the total column moisture content derived from the Special Sensor Microwave/Imager. The simulations were performed with the SAMSON system described in an earlier paper, using atmospheric temperatures and humidities from operational analyses produced by the European Centre for Medium Range Weather Forecasts. At low latitudes, the magnitude of the clear-sky greenhouse effect is dominated by the strong thermodynamic link between the total column moisture content of the atmosphere and sea surface temperatures, with minimal seasonal variations. In contrast, at middle to high latitudes there are strong seasonal variations, the clear-sky greenhouse effect being largest in winter and smallest in summer. These variations cannot be explained by the seasonal cycle in the total column moisture content, as this is largest in summer and smallest in winter. The variations are controlled instead by the seasonal changes in atmospheric temperatures. The colder atmosphere in winter enhances the temperature differential between the atmosphere and the sea surface, leading to a larger greenhouse effect despite the lower moisture contents. The magnitude of the clear-sky greenhouse effect is thus controlled by atmospheric humidity at low latitudes, but by atmospheric temperature at middle and high latitudes. These controls are illustrated by results from sensitivity experiments with SAMSON and are interpreted in terms of a simple model.     

Similarities in the behaviour of Chernobyl derived Ru-103, Ru-106 and Cs-137 in two freshwater lakes

Measurements of the concentrations of Ru-103 and Ru-106 in the water column and sediments of two productive temperate lakes were made during an eight month period following the Chernobyl accident. Ru-103 accumulation in the sediments began simultaneously with that of Cs-134 and a constant ratio (approx. 2.0 on a decay corrected basis) of Ru-103/Cs-137 was observed in surface waters and sediments throughout the measurement period. The ratio is not statistically different from that reported for atmospheric input and for epilimnetic water. The results suggest that the processes of removal of radioactive ruthenium and caesium from the mixed water column to the sediments are the same.Enhancement of Cs, compared with Ru, in the isolated bottom waters of one of the lakes in the summer months provided evidence for Cs release from the sediments during a period of hypolimnetic anoxia.     

Petrology,geochemistry, and geochronology of Paleoproterozoic volcanic and granitic rocks (1.89–1.88 Ga) of the Pitinga Province,Amazonian Craton,Brazil

This paper presents geochemical, petrographic, and geochronological data on the Uatumã magmatism in the Pitinga Province, where it is represented by volcanic rocks from the Iricoumé Group and granitic rocks from the Mapuera Suite. The Iricoumé Group (1.89–1.88 Ga) is constituted of the Divisor Formation (intermediate volcanic rocks), Ouro Preto Formation (acid effusive rocks), and Paraiso Formation (acid crystal-rich ignimbrites, surge deposits, and basic rocks). The volcanic sequence is intruded by granitoids from the Mapuera Suite (1.88 Ga), mainly represented by monzogranites and syenogranites. Structural and field relations suggest that caldera complex collapse controlled the emplacement of volcanics and granitoids of the Mapuera Suite. Subsequent structure reactivations allowed the younger Madeira Suite (1.82–1.81 Ga) to be emplaced in the central portion of the caldera complex. The felsic Iricoumé magmatism is mainly composed of rhyolites, trachydacites and latites, with SiO₂ contents between 64 wt% and 80 wt%. The plutonic rocks from the Mapuera Suite present SiO₂ between 65 wt% and 77 wt%. Volcanic and granitic rocks present identical geochemical characteristics and that is attributed to their co-magmatic character. The felsic volcanic rocks and granites are metaluminous to slightly peraluminous and show affinity with silica-saturated alkaline series or with A-type magmas. They have Na₂O + K₂O between 6.6% and 10.4%, FeO^t/(FeO^t + MgO) varying between 0.76 and 0.99, Ga/Al ratios between 1.5 and 4.9, like typical A-type rocks; and plot in the within-plate or post-collisional fields in the (Nb + Y) vs. Rb diagram. The Nb/Y ratios indicate that these rocks are comparable to A2-type granites. This magmatism can be related to the (i) potassic alkaline series, with low Sr content in the felsic rocks explained by plagioclase fractionation at low pressure and high temperature or, alternatively, (ii) a bimodal association where magma had high crustal influence. The similarity of the Iricoumé felsic magmatism with A2-type granitoids and their high ETRL/Nb ratios suggest its relation with mantle sources previously modified by subduction, probably in a post-collision environment. Alternatively, this can be interpreted as bimodal within-plate magmatism with contamination by crustal melts. In this context, the extreme F, Nb and Zr enrichment of Madeira Suite could be explained by the presence of a thin crust which favored the presence and continuity of convective systems in the upper mantle.     

A commentary on coastal research in New Zealand universities

Abstract:    University research in coastal geomorphology, processes and management has made a major contribution to the fundamental understanding of coastal systems in New Zealand over the past 43 years. This article examines the growth in university-based coastal research since 1964 and discusses the geographical pattern and themes of this research. Data indicate a significant geographical concentration of research effort and focus on a narrow range of research themes. Underlying reasons for these characteristics of New Zealand coastal research are explored and challenges facing university based research are discussed. Such challenges can be overcome through a more coordinated research effort to realize the huge potential to undertake coastal science of national relevance and international significance.     

Major and trace element and Sr–Nd isotope signatures of lavas from the Central Lau Basin: Implications for the nature and influence of subduction components in the back-arc mantle

New major and trace element and Sr–Nd isotope data are presented for basaltic glasses from active spreading centers (Central Lau Spreading Center (CLSC), Relay Zone (RZ) and Eastern Lau Spreading Center (ELSC)) in the Central Lau Basin, SW Pacific. Basaltic lavas from the Central Lau Basin are mainly tholeiitic and are broadly similar in composition to mid-ocean ridge basalts (MORB). Their generally high ⁸⁷Sr/⁸⁶Sr ratios, combined with relatively low ¹⁴³Nd/¹⁴⁴Nd ratios are more akin to MORB from the Indian rather than Pacific Ocean. In detail, the CLSC, RZ and ELSC lavas are generally more enriched in large ion lithophile elements (Rb, Ba, Sr, and K) than average normal-MORB, which suggests that the mantle beneath the Central Lau Basin was modified by subducted slab-derived components. Fluid mobile/immobile trace element and Sr – Nd isotope ratios suggest that the subduction components were essentially transferred into the mantle via hydrous fluids derived from the subducted oceanic crust; contributions coming from the subducted sediments are minor. Compared to CLSC lavas, ELSC and RZ lavas show greater enrichment in fluid mobile elements and depletion in high field strength elements, especially Nb. Thus, with increasing distance away from the arc, the influence of subduction components in the mantle source of Lau Basin lavas diminishes. The amount of hydrous fluids also influences the degree of partial melting of the mantle beneath the Central Lau Basin, and hence the degree of melting also decreases with increasing distance from the arc.     

Recapturing quality field experiences and strengthening teaching–research links

Because of unwieldy numbers, and in an attempt to strengthen teaching–research links, the teaching team of 'Field Research Methods' discarded a class fieldtrip in favour of more flexible fieldwork. The new approach continues to use inquiry-based learning but has research problems more closely linked to staff interests. Students are responsible for most aspects of the research process including some logistical planning of fieldwork. Although often anxious at first, students welcomed this approach and appreciated the host of transferable and research skills they developed. Tutors benefited from the enhanced learning outcomes for students and a strengthening of teaching–research links.