Information content of snow hydrological signatures based on streamflow,precipitation and air temperature

Hydrological signatures that represent snow processes are valuable to gain insights into snow accumulation and snow melt dynamics. We investigated five snow signatures. Considering inter-annual average of each calendar day, two slopes derived from the relation between streamflow and air temperature for different periods and streamflow peak maxima are used as signatures. In addition, two different approaches are used to compute inter-annual average and yearly snow storage estimates. We evaluated the ability of these signatures to characterize average (a) snow melt dynamics and (b) snow storage. They were applied in 10 Critical Zone Observatory catchments of the Southern Sierra mountains (USA) characterized by a Mediterranean climate. The relevance and information content of the signatures are evaluated using snow depth and snow water equivalent measurements as well as inter-catchment differences in elevation. The slopes quantifying the relations between streamflow and air temperature and the date of streamflow peak were found to characterize snow melt dynamics in terms of snow melt rates and snow melt affected areas. Streamflow peak dates were linked to the period of highest snow melt rates. Snow storage could be estimated both on average, considering all years, and for each year. Snow accumulation dynamics could not be characterized due to the lack of streamflow response during the snow accumulation period. The signatures were found potentially valuable to gain insights into catchment scale snow processes. In particular, when comparing catchments or observed and simulated data, they could provide insights into differences in terms of (a) snow melt rate and/or snow melt affected area over the snow melt season and (b) average or yearly snow storage. Requiring only widely available data, these hydrological signatures can be valuable for snow processes characterization, catchment comparison/classification or model development, calibration or evaluation.     

Obituary – Lalchand Govindram Gwalani (1945–2018)

Mineralogy and Petrology -     

Linking hydrologic signatures to hydrologic processes: A review

Hydrologic signatures are metrics that quantify aspects of streamflow response. Linking signatures to underlying processes enables multiple applications, such as selecting hydrologic model structure, analysing hydrologic change, making predictions in ungauged basins, and classifying watershed function. However, many lists of hydrologic signatures are not process-based, and knowledge about signature-process links has been scattered among studies from experimental watersheds and model selection experiments. This review brings together those studies to catalogue more than 50 signatures representing evapotranspiration, snow storage and melt, permafrost, infiltration excess, saturation excess, groundwater, baseflow, connectivity, channel processes, partitioning, and human alteration. The review shows substantial variability in the number, type, and timescale of signatures available to represent each process. Many signatures provide information about groundwater storage, partitioning, and connectivity, whereas snow processes and human alteration are underrepresented. More signatures are related to the seasonal scale than the event timescale, and land surface processes (ET, snow, and overland flow) have no signatures at the event scale. There are limitations in some signatures that test for occurrence but cannot quantify processes, or are related to multiple processes, making automated analysis more difficult. This review will be valuable as a reference for hydrologists seeking to use streamflow records to investigate a particular hydrologic process or to conduct large-sample analyses of patterns in hydrologic processes.     

A first look at oxygen isotope records from modern and Holocene-aged gastropod (Stenomelania) shells from Lake Kutubu,Papua New Guinea

The oxygen isotopic composition of Stenomelania gastropod shells was investigated to reconstruct Holocene palaeoclimate change at Lake Kutubu in the southern highlands of Papua New Guinea. Oxygen isotope (δ¹⁸O) values recorded in aquatic gastropod shells change according to ambient water δ¹⁸O values and temperature. The gastropod shells appear to form in oxygen isotopic equilibrium with the surrounding water and record a shift in average shell oxygen isotopic composition through time, probably as a result of warmer/wetter conditions at ca. 600–900 and 5900–6200 cal a bp. Shorter term fluctuations in oxygen isotope values were also identified and may relate to changes in the intensity or source of rainfall. Further δ¹⁸O analyses of gastropod shells or other carbonate proxies found in the Lake Kutubu sediments are warranted. © 2020 John Wiley & Sons, Ltd.     

Isotopic composition of carbon and nitrogen in ureilitic fragments of the Almahata Sitta meteorite

This study characterizes carbon and nitrogen abundances and isotopic compositions in ureilitic fragments of Almahata Sitta. Ureilites are carbon‐rich (containing up to 7 wt% C) and were formed early in solar system history, thus the origin of carbon in ureilites has significance for the origin of solar system carbon. These samples were collected soon after they fell, so they are among the freshest ureilite samples available and were analyzed using stepped combustion mass spectrometry. They contained 1.2–2.3 wt% carbon; most showed the major carbon release at temperatures of 600–700 °C with peak values of δ¹³C from ?7.3 to +0.4‰, similar to literature values for unbrecciated (“monomict”) ureilites. They also contained a minor low temperature (≤500 °C) component (δ¹³C = ca ?25‰). Bulk nitrogen contents (9.4–27 ppm) resemble those of unbrecciated ureilites, with major releases mostly occurring at 600–750 °C. A significant lower temperature release of nitrogen occurred in all samples. Main release δ¹⁵N values of ?53 to ?94‰ fall within the range reported for diamond separates and acid residues from ureilites, and identify an isotopically primordial nitrogen component. However, they differ from common polymict ureilites which are more nitrogen‐rich and isotopically heavier. Thus, although the parent asteroid 2008TC₃ was undoubtedly a polymict ureilite breccia, this cannot be deduced from an isotopic study of individual ureilite fragments. The combined main release δ¹³C and δ¹⁵N values do not overlap the fields for carbonaceous or enstatite chondrites, suggesting that carbon in ureilites was not derived from these sources.     

Geochemistry and tectonic development of Cenozoic magmatism in the Carpathian–Pannonian region

This review considers the magmatic processes in the Carpathian–Pannonian Region (CPR) from Early Miocene to Recent times, as well as the contemporaneous magmatism at its southern boundary in the Dinaride and Balkans regions. This geodynamic system was controlled by the Cretaceous to Neogene subduction and collision of Africa with Eurasia, especially by Adria that generated the Alps to the north, the Dinaride–Hellenide belt to the east and caused extrusion, collision and inversion tectonics in the CPR. This long-lived subduction system supplied the mantle lithosphere with various subduction components. The CPR contains magmatic rocks of highly diverse compositions (calc-alkaline, K-alkalic, ultrapotassic and Na-alkalic), all generated in response to complex post-collisional tectonic processes. These processes formed extensional basins in response to an interplay of compression and extension within two microplates: ALCAPA and Tisza–Dacia. Competition between the different tectonic processes at both local and regional scales caused variations in the associated magmatism, mainly as a result of extension and differences in the rheological properties and composition of the lithosphere. Extension led to disintegration of the microplates that finally developed into two basin systems: the Pannonian and Transylvanian basins. The southern border of the CPR is edged by the Adria microplate via Sava and Vardar zones that acted as regional transcurrent tectonic areas during Miocene–Recent times.Major, trace element and isotopic data of post-Early Miocene magmatic rocks from the CPR suggest that subduction components were preserved in the lithospheric mantle after the Cretaceous–Miocene subduction and were reactivated especially by extensional tectonic processes that allowed uprise of the asthenosphere. Changes in the composition of the mantle through time support geodynamic scenarios of post-collision and extension processes linked to the evolution of the main blocks and their boundary relations. Weak lithospheric blocks (i.e. ALCAPA and western Tisza) generated the Pannonian basin and the adjacent Styrian, Transdanubian and Z?rand basins which show high rates of vertical movement accompanied by a range of magmatic compositions. Strong lithospheric blocks (i.e. Dacia) were only marginally deformed, where strike–slip faulting was associated with magmatism and extension. At the boundary of Adria and Tisza–Dacia strike–slip tectonics and core complex extension were associated with small volume Miocene magmatism in narrow extensional sedimentary basins or granitoids in core-complex detachment systems along older suture zones (Sava and Vardar) accommodating the extension in the Pannonian basin and afterward Pliocene–Quaternary inversion. Magmas of various compositions appear to have acted as lubricants in a range of tectonic processes.     

Hydrological field data from a modeller's perspective: Part 2: process‐based evaluation of model hypotheses

The current generation of hydrological models has been widely criticized for their inability to adequately simulate hydrological processes. In this study, we evaluate competing model representations of hydrological processes with respect to their capability to simulate observed processes in the Mahurangi River basin in Northland, New Zealand. In the first part of this two‐part series, the precipitation, soil moisture, and flow data in the Mahurangi were used to estimate the dominant hydrological processes and explore several options for their suitable mathematical representation. In this paper, diagnostic tests are applied to gain several insights for model selection. The analysis highlights dominant hydrological processes (e.g. the importance of vertical drainage and baseflow compared to sub‐surface stormflow), provides guidance for the choice of modelling approaches (e.g. implicitly representing sub‐grid heterogeneity in soils), and helps infer appropriate values for model parameters. The approach used in this paper demonstrates the benefits of flexible model structures in the context of hypothesis testing, in particular, supporting a more systematic exploration of current ambiguities in hydrological process representation. The challenge for the hydrological community is to make better use of the available data, not only to estimate parameter values but also to diagnostically identify more scientifically defensible model structures. Copyright © 2010 John Wiley & Sons, Ltd.     

Late-glacial and early-Holocene Trichoptera (Insecta) from Kråkenes Lake, western Norway

Fossil Trichoptera (caddisfly) remains have been identified and quantitatively recorded in the late-glacial and early-Holocene sediments from Kråkenes Lake, western Norway. The sediment sequence was deposited between 12,300 and 8850 ¹⁴C BP, covering the Allerød, Younger Dryas, and early-Holocene periods. The first Trichoptera were recorded at 12,000 ¹⁴C BP, and during the Allerod a diverse assemblage of Limnephilidae taxa developed in the lake. By about 11,400 ¹⁴C BP the relatively thermophilous Polycentropus flavomaculatus and Limnephilus rhombicus were present, suggesting that the summer water temperature was at least 17 °C. This temperature fell by 5-8 °C at the start of the Younger Dryas, and the thermophilous taxa were replaced within 20-40 ¹⁴C yrs by Apatania spp., including the arctic-alpine A. zonella, suggesting a maximum summer water temperature of 10-12 °C. The Trichoptera assemblage was impoverished in numbers and in diversity over the next 200 yrs as the severe conditions of the Younger Dryas developed. As soon as temperatures rose and glacial meltwater and silt input ended about 700 ¹⁴C yrs later, the resident Apatania assemblage expanded immediately, within 10 yrs. About 130 yrs later, thermophilous taxa replaced Apatania, and a much more diverse assemblage than in the Allerod occupied the varied habitats made available by the development of the Holocene lake ecosystem. The 130 yr delay may have been caused by a gradual temperature increase crossing a critical threshold, or by the time taken for thermophilous taxa to migrate from their Younger Dryas refugia.