Wakefieldite‐(Nd), a New Neodymium Vanadate Mineral in the Arase Stratiform Ferromanganese Deposit,Kochi Prefecture,Japan

Wakefieldite‐(Nd), NdVO₄, is a new mineral found from the Arase stratiform ferromanganese deposit in Kochi Prefecture, Shikoku Island, Japan. It is the Nd‐dominant analogue of wakefieldite‐(Y) and wakefieldite‐(Ce). The ferromanganese ore specimen mainly consists of hematite and caryopilite, and wakefieldite‐(Nd) is typically enclosed in caryopilite. Wakefieldite‐(Nd) is tetragonal, I4₁/amd, a = 7.338(16) Å, c = 6.509(19) Å, V = 350.5(18) ų, Z = 4. The four strongest lines in the X‐ray diffraction pattern [d(Å), I/I₀, hkl] using a Gandolfi camera are (3.67, 100, 200); (2.74, 51, 112); (4.84, 27, 101) and (1.89, 25, 312). Chemical composition of wakefieldite‐(Nd) are V₂O₃ 35.25, As₂O₃ 0.93, SiO₂ 0.14, MnO 1.45, Fe₂O₃ 0.41, Y₂O₃ 2.87, La₂O₃ 7.61, Ce₂O₃ 7.37, Pr₂O₃ 6.04, Nd₂O₃ 26.79, Sm₂O₃ 4.41, Eu₂O₃ 1.36, Gd₂O₃ 3.41, Tb₂O₃ 0.22, Dy₂O₃ 1.41, Er₂O₃ 0.10, total 99.77 wt.%. The empirical formula is (Nd_0.403La_0.118Ce_0.114Pr_0.093Y_0.064Sm_0.064Mn_0.052Gd_0.048Eu_0.020Dy_0.019Fe_0.013Tb_0.003Er_0.001)_1.012(V_0.981As_0.020Si_0.006)_1.007O₄ on the basis of O = 4. The calculated density is 4.782 g/cm³. Microtexture and co‐existing relationship between wakefieldite‐(Nd) and caryopilite suggest that recrystallization and dehydration of Fe‐ and Mn‐oxyhydroxide led to the generation of hematite, caryopilite, rhodochrosite and wakefieldite‐(Nd) by the metamorphism during the accretion of the host unit of the Arase deposit. Chondrite‐normalized REE pattern of the host ferromanganese ore, which is regarded as oceanic metalliferous sediment in origin, shows negative Ce anomaly. Chemical composition of wakefieldite‐(Nd) reflects Ce‐depleted bulk composition of REE‐enriched ferromanganese ore.     

The S pole distribution on magnetic grains in pyroxenite determined by magnetotactic bacteria

North-seeking bacteria (NSB) with 1 μm diameters migrate to the S pole only. They were applied to identify the S pole determination on a polished surface of magnetite-rich pyroxenite whose natural remanent magnetization (NRM) intensity was 5.64 × 10⁻³ Am² kg⁻¹. The microscopic observations were performed under dark-field illumination in a controlled magnetic field to 10 μT. The NSB formed clusters on limited areas of magnetite grains and scattered over the whole magnetite grains.

The NRM decreased to 1.02 × 10⁻⁵ Am² kg⁻¹ by alternating field (AF) demagnetization to 60 mT but no clusters appeared, while small populations of the NSB scattered on each grain. These scattered bacteria may gather toward the S pole resulting from magnetic domain walls.

When the sample acquired saturation isothermal remanent magnetization (SIRM) to 1 T, the NSB formed dense clusters at the opposite side to the applied field direction on the many grains as expected. This evidence indicated that the NSB can be useful micro-organisms for the determination of fine magnetic structures. Some grains also had NSB clusters at the edge of the grains toward the field direction or did not exhibit any clusters. The complicated distribution of the clusters (the S poles) may be explained by shape anisotropy of the magnetic grains.     

Dynamic compaction properties of bentonite-based materials

Dynamic compaction tests of bentonite-based materials (BBMs) with 100, 70 and 50% bentonite contents have been performed using five powdery bentonites with different physicochemical properties to establish the simplified evaluation method for dynamic compaction properties of BBMs. For a given bentonite content and a total compaction energy condition, the maximum dry density, ρ_dmax, and the optimum water content, w_opt, which are well-known indexes of compaction properties, for BBMs were determined according to the type of bentonite used for BBMs. For evaluation of those values of BBMs derived in this study, the plastic limit of BBM, w_pbbm, was defined as the plastic limit that was measured using the sample pulverized to a maximum grain size of less than 425 μm in the case of BBM with sand having a maximum grain size of more than 425 μm and was measured using the powdery bentonite itself in the case of BBM without sand. This study proposed equations for evaluating ρ_dmax and w_opt of BBMs with more than 50% bentonite content under the total compaction energy conditions of 551–2755 kN-m/m³ using w_pbbm. Finally, we related the equations derived in this study to the equation for evaluating hydraulic properties of compacted BBMs proposed in previous work and proposed the preparation method of BBMs with more than 50% bentonite content for constructing BBM buffer by in-situ compaction method.     

Deep Flows on the Slope Inshore of the Kuril-Kamchatka Trench Southeast off Cape Erimo, Hokkaido

Deep flows on the slope inshore of the Kuril-Kamchatka Trench southeast off Cape Erimo, Hokkaido were observed for about five years from June 1989 to March 1995, using a mooring system with two current meters. In 1991 and 1993 directionally stable southwestward flows were observed at the upper layer (1000 m). These appear to be typical of the Oyashio because the characteristics of the flows were high mean kinetic energy, low eddy energy and high stability. However, the magnitudes of other mean flows at the upper layer, except for 1991 and 1993, were less than their standard deviations. This suggests that the Oyashio was observed for only a limited period of time. On the other hand, at the lower layer (3000 m) the magnitudes of the mean flows for 10–11 months were 1–3 cm s^-1 and ellipses of their eddy kinetic energy were extremely flattened in the direction of the local isobath. The directions of the mean flows in 1990, 1991 and 1993 were southwestward along the local isobath. The relationships between the upper and the lower flows are discussed in terms of monthly change of kinetic energy, since the low-frequency fluctuations longer than 30-day are predominant from the eddy kinetic energy spectra. The results show that there are cases when the kinetic energy of the monthly mean flows at the lower layers are larger than those at the upper layers. This suggests the possibility that the lower flows are in part a southward deep western boundary current.     

Simple two-dimensional model of propagation of magma-filled cracks

The direction of propagation of magma-filled cracks was theoretically examined for a two-dimensional model. The analytical result indicates that magma-filled cracks, which have magmatic pressures larger than a critical value, propagate in parallel with the maximum principal direction of far-field stress. This may give one of theoretical grounds to the dike method by which the regional stress field is estimated.     

A spectroscopic study of Epsilon Aurigae

Epsilon Aurigae has been observed during ingress and totality between 1982 and 1983 at Okayama. Analyses of profiles of H line and of radial velocities of neutral hydrogen and metals show that the secondary component consists of at least three parts in structure.Paper presented at the Lembang-Bamberg IAU Colloquium No. 80 on Double Stars: Physical Properties and Generic Relations, held at Bandung, Indonesia, 3–7 June, 1983.     

Numerical study of Ashiyahama residential building damage in the Kobe Earthquake

Studies are made on the structural damage at the Ashiyahama residential high‐rise steel building complex due to the Hyogo‐ken Nanbu Earthquake (Kobe Earthquake), which occurred on 17 January 1995. The axial breakage of very thick‐plated steel columns of the mega‐structure is unprecedented and has been attracting the special attention of structural engineers. The cause of the damage is first investigated from numerical computation with recourse to an explicit method of dynamic analysis based on a continuous medium. The numerical result is compared with that obtained from a conventional multi‐mass lumped stiffness model combined with an equivalent lateral‐force procedure. By comparing both the numerical results, the latter conventional method is shown to be inadequate for achieving earthquake‐resistant capability. The destructive power of the ground motion is found to have exceeded the horizontal earthquake‐resistant capacity that is prescribed in the structural design criteria. Great axial stresses are produced in columns by combined action of bending moment and axial force due to overturning moment. The fracture of heavy steel columns is caused from only the horizontal component of seismic ground motion. Actual locations of significant damage are closely related to the occurrence of plastic hinges in the analysis. It is emphasized as a warning to avoid yielding concentration in particular storeys. Lastly, recommendations to enhance earthquake‐resistant design are proposed from a practical point of view. Copyright © 2001 John Wiley & Sons, Ltd.     

Orbital signals found in physical and chemical properties of bottom sediments from Lake Baikal

Physical and chemical properties of two 100 m sediment cores (BDP-93-1, 93-2) obtained from the Buguldeika saddle of Lake Baikal in the eastern Siberia and a ¹⁴C-based age scale for the core show that the core bottom is about 400000 years ago and that the changes in the sedimentological environment of the area during the interval were that comparatively coarse and high C/N ratio sediments accumulated in the lake during interglacial periods, and fine material and low C/N ratio during glacial periods. The tentative age scale suggests that the first excursion in the earth's magnetic field at about 26 m (BDP-93-1 and 93-2) from the sediment surface corresponds to the Blake event. Statistical analyses of the data-sets for the some properties show that the fluctuations have distinct periods; 20000 years, 40000 years and 100000 years, that are related to the Milankovitch parameters and support that the tentative age scale is approximately acceptable.