Iodine (and Other Halogens) in Twenty Six Geological Reference Materials by ICP-MS and Ion Chromatography

Analytical results for iodine in twenty six geological reference materials (RM) are presented. Bromine, fluorine and chlorine were also determined in some samples. Pyrohydrolysis in a heated quartz tube under a wet oxygen flow was used for the separation of the halogens from the matrix and the evolved gas was absorbed in a trap solution. The halogens were measured by ICP-MS and ion chromatography (IC). All four halogens can be collected in the trap solution from one combustion procedure. The analysed samples range in type from igneous rocks to terrestrial and marine sediments. Precision, detection limits, and accuracy are also presented.     

Changes in extended boreal summer tropical cyclogenesis associated with large-scale flow patterns over the western North Pacific in response to the global warming hiatus

Climate Dynamics - This study examines extended boreal summer (May–October) tropical cyclogenesis events (TCGEs) associated with large-scale flow patterns (LFPs) over the western North...     

Necessary condition for the existence of algebraic first integrals

Existence of algebraic first integrals for a class of dynamical systems is discussed in connection with the nature of the singularities of solutions. It is shown that under some conditions, the existence of algebraic first integrals controls a quantity characterising a singularity (Kowalevski's exponent) which can be calculated in a finite procedure. Two simple examples are given, which illustrate how main theorems work.     

The behavior of a two-dimensional dual forced plume

The behavior of two plumes ejected into a thin water tank is investigated experimentally. As the time elapses, the plume axes deflect towards each other. Time evolution of this two-dimensional, dual forced plume is found to be similar to that of a two-dimensional, single plume ejected near a vertical wall. The symmetric plane of the two plumes in the former case plays the role of the vertical wall. The time required for the dual plume to attain a quasi-steady state is shorter than that for the single plume. The deflection angles of the plume axes are smaller for the dual plume, and the plume water remains near the free water surface in a quasi-steady state. Water circulation in a triangular region surrounded by the free water surface, the side of the plume and the symmetric plane (or the vertical wall for the single plume case) may account for this difference; the circulation is much more pronounced in the single plume case.     

A numerical simulation of the distribution of water temperature and salinity in the Seto Inland Sea

Constant flows, as well as oscillatory tidal flow, play an important role in the long-term dispersion of water in the Seto Inland Sea. Two kinds of numerical model (1-line and 2-line models) of the Seto Inland Sea have been developed to determine the role of density-induced currents, one type of the constant flow, in water dispersion in the Inland Sea. The seasonal variations of temperature, salinity and density fields are simulated and the density-induced current field is predicted at the same time. It is found that the most appropriate value of the longitudinal eddy diffusion coefficient,K _x, is 5×10⁶–7×10⁶ cm²sec^–1. The value of the overall mean dispersion coefficient is of the order of 10⁷cm²sec^–1 (Hayami and Unoki, 1970). Consequently, it is suggested that 50–70% of the total dispersion in the Seto Inland Sea can be attributed to currents other than density-induced currents,i.e., tidal currents, tide-induced currents and wind-driven currents.In winter, both density and velocity fields, calculated using the 1-line model, satisfy the conditions for the existence of a coastal front in Kii Channel and in the eastern Iyo-nada.     

Giant Megamullion in the Parece Vela Backarc Basin

We present results of high-resolution bathymetric studies of the extinct intermediate-spreading Parece Vela Basin in the northwestern Pacific, where we have identified an extremely large mullion structure, here termed a giant megamullion. We find that the giant megamullion is nearly an order of magnitude larger than the similar structures in the slow-spreading Mid-Atlantic Ridge (`megamullions'). The giant megamullion has slightly elevated mantle Bouguer anomaly, and yields serpentinized peridotites and gabbros, suggesting that they are exposing oceanic crust and upper mantle. An off-axis rugged `chaotic terrain' was also identified in the Parece Vela Basin. The terrain consists of isolated and elevated blocks capped by corrugated axis-normal lineations, and associated deeps. We thus interpret it as analogues to the Mid-Atlantic Ridge megamullions. We propose that amagmatic tectonics producing the giant megamullion and the chaotic terrain occupied a significant part in crustal construction in the Parece Vela Basin evolution.     

Recent Occurrences of Dinophysis fortii (Dinophyceae) in the Okkirai Bay, Sanriku, Northern Japan, and Related Environmental Factors

Occurrence of Dinophysis fortii, a causative organism of diarrhetic shellfish poisoning, in the Okkirai Bay, Sanriku was surveyed in 1995, 1996, 1998 and 1999. In each year, its major occurrence was detected from the late May or early June and continued until the late June or early July. Seawater temperature, salinity and nutrients measurements suggested that inflows of offshore water into the bay played key role on the first major occurrence of D. fortii. With an analysis of continuous temperature data in the Otsuchi Bay which locates north of the Okkirai Bay, this influent was considered to be intermittent inflow of the offshore water by internal tidal waves which propagated from north to south. First occurrence peak of D. fortii was synchronous with phycobilin containing microalgae, synechococcoid cyanobacteria and cryptomonad, in all years. In vivo fluorescence measurement of D. fortii cells in 1995 and 96 showed that the cells in these microalgal-rich water contained more phycobilin pigment than those in the microalgal-poor water. The result may support a hypothesis that D. fortii acquires phycobilin by an uptake of these microalgae. After the first major occurrence in the bay, D. fortii sometimes occurred in rather inshore waters where showed elevated ammonium level possibly due to increased heterotrophic activity. Together with another finding that D. fortii is mixotrophic, it could be assumed that the environment being suited to heterotrophic nutrition also stimulates D. fortii growth in the bay.